Organic Chemistry (9th Edition)
Organic Chemistry (9th Edition)
9th Edition
ISBN: 9780321971371
Author: Leroy G. Wade, Jan W. Simek
Publisher: PEARSON
Question
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Chapter 14.6, Problem 14.10P

(a)

Interpretation Introduction

To determine: The synthesis of the given ether by alkoxymercuration-demercuration and Williamson synthesis methods.

Interpretation: The synthesis of the given ether by alkoxymercuration-demercuration and Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

In alkoxymercuration-demercuration, ether is produced when alkene reacts with an alcohol in the presence of mercury acetate.

(b)

Interpretation Introduction

To determine: The synthesis of the given ether by alkoxymercuration-demercuration and Williamson synthesis method.

Interpretation: The synthesis of the given ether by alkoxymercuration-demercuration and Williamson synthesis method is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

In alkoxymercuration-demercuration, ether is produced when alkene reacts with an alcohol in the presence of mercury acetate.

(c)

Interpretation Introduction

To determine: The synthesis of the given ether by alkoxymercuration-demercuration and Williamson synthesis method.

Interpretation: The synthesis of the given ether by alkoxymercuration-demercuration and Williamson synthesis method is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

In alkoxymercuration-demercuration, ether is produced when alkene reacts with an alcohol in the presence of mercury acetate.

(d)

Interpretation Introduction

To determine: The synthesis of the given ether by alkoxymercuration-demercuration and Williamson synthesis method.

Interpretation: The synthesis of the given ether by alkoxymercuration-demercuration and Williamson synthesis method is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

In alkoxymercuration-demercuration, ether is produced when alkene reacts with an alcohol in the presence of mercury acetate.

(e)

Interpretation Introduction

To determine: The synthesis of the given ether by alkoxymercuration-demercuration and Williamson synthesis method.

Interpretation: The synthesis of the given ether by alkoxymercuration-demercuration and Williamson synthesis method is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

In alkoxymercuration-demercuration, ether is produced when alkene reacts with an alcohol in the presence of mercury acetate.

(f)

Interpretation Introduction

To determine: The synthesis of the given ether by alkoxymercuration-demercuration and Williamson synthesis method.

Interpretation: The synthesis of the given ether by alkoxymercuration-demercuration and Williamson synthesis method is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

In alkoxymercuration-demercuration, ether is produced when alkene reacts with an alcohol in the presence of mercury acetate.

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When an unknown amine reacts with an unknown acid chloride, an amide with a molecular mass of 163 g/mol (M* = 163 m/z) is formed. In the infrared spectrum, important absorptions appear at 1661, 750 and 690 cm. The 13C NMR and DEPT spectra are provided. Draw the structure of the product as the resonance contributor lacking any formal charges. 13C NMR DEPT 90 200 160 120 80 40 0 200 160 120 80 40 0 DEPT 135 T 200 160 120 80 40 0 Draw the unknown amide. Select Dow Templates More Frage

Chapter 14 Solutions

Organic Chemistry (9th Edition)

Ch. 14.7 - Explain why bimolecular condensation is a poor...Ch. 14.7 - Prob. 14.12PCh. 14.7 - Prob. 14.13PCh. 14.8 - Prob. 14.14PCh. 14.8 - Prob. 14.15PCh. 14.8 - Prob. 14.16PCh. 14.10A - Prob. 14.17PCh. 14.10A - Prob. 14.18PCh. 14.10B - Prob. 14.19PCh. 14.11B - Show how you would accomplish the following...Ch. 14.11B - Prob. 14.21PCh. 14.12 - Prob. 14.22PCh. 14.12 - Prob. 14.23PCh. 14.12 - Prob. 14.24PCh. 14.13 - Prob. 14.25PCh. 14.13 - Prob. 14.26PCh. 14.14 - Prob. 14.27PCh. 14.15 - Give the expected products of the following...Ch. 14 - Write structural formulas for the following...Ch. 14 - Give common names for the following compounds. a....Ch. 14 - Give IUPAC names for the following compounds. a....Ch. 14 - Glycerol (propane-1,2,3-triol) is a viscous syrup...Ch. 14 - Prob. 14.33SPCh. 14 - Show how you would make the following ethers,...Ch. 14 - (A true story.) An inexperienced graduate student...Ch. 14 - Prob. 14.36SPCh. 14 - a. Show how you would synthesize the pure (R)...Ch. 14 - a. Predict the values of m/z and the structures of...Ch. 14 - The following reaction resembles the...Ch. 14 - Prob. 14.40SPCh. 14 - Prob. 14.41SPCh. 14 - Prob. 14.42SPCh. 14 - Give the structures of the intermediates...Ch. 14 - Prob. 14.44SPCh. 14 - Show how you would synthesize the following ethers...Ch. 14 - Prob. 14.46SPCh. 14 - Prob. 14.47SPCh. 14 - Prob. 14.48SPCh. 14 - An acid-catalyzed reaction was carried out using...Ch. 14 - Propylene oxide is a chiral molecule. Hydrolysis...Ch. 14 - Prob. 14.51SPCh. 14 - Prob. 14.52SPCh. 14 - Prob. 14.53SPCh. 14 - Prob. 14.54SPCh. 14 - In 2012, a group led by Professor Masayuki Satake...
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