The method of synthesis of given ether. Interpretation: The method of synthesis of given ether is to be predicted. Concept introduction: Lithium aluminum hydride ( LiAlH 4 ) is a strong reducing agent which reduces ketones to secondary alcohols and aldehydes to primary alcohols. Both LiAlH 4 and Grignard reagents react with carbonyl compounds to give alkoxide ion intermediate. These alkoxide intermediates react with primary or methyl alkyl halides or tosylates to give ethers.

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Answer 1

Question

Chapter 14, Problem 14.41SP

(a)

Interpretation Introduction

To determine: The method of synthesis of given ether.

Interpretation: The method of synthesis of given ether is to be predicted.

Concept introduction: Lithium aluminum hydride (LiAlH4) is a strong reducing agent which reduces ketones to secondary alcohols and aldehydes to primary alcohols. Both LiAlH4 and Grignard reagents react with carbonyl compounds to give alkoxide ion intermediate. These alkoxide intermediates react with primary or methyl alkyl halides or tosylates to give ethers.

(b)

Interpretation Introduction

To determine: The method of synthesis of given ether.

Interpretation: The method of synthesis of given ether is to be predicted.

Concept introduction: Lithium aluminum hydride (LiAlH4) is a strong reducing agent which reduces ketones to secondary alcohols and aldehydes to primary alcohols. Both LiAlH4 and Grignard reagents react with carbonyl compounds to give alkoxide ion intermediate. These alkoxide intermediates react with primary or methyl alkyl halides or tosylates to give ethers.

(c)

Interpretation Introduction

To determine: The method of synthesis of given ether.

Interpretation: The method of synthesis of given ether is to be predicted.

Concept introduction: Lithium aluminum hydride (LiAlH4) is a strong reducing agent which reduces ketones to secondary alcohols and aldehydes to primary alcohols. Both LiAlH4 and Grignard reagents react with carbonyl compounds to give alkoxide ion intermediate. These alkoxide intermediates react with primary or methyl alkyl halides or tosylates to give ethers.

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Answer 2

Question

Chapter 14, Problem 14.41SP

(a)

Interpretation Introduction

To determine: The method of synthesis of given ether.

Interpretation: The method of synthesis of given ether is to be predicted.

Concept introduction: Lithium aluminum hydride (LiAlH4) is a strong reducing agent which reduces ketones to secondary alcohols and aldehydes to primary alcohols. Both LiAlH4 and Grignard reagents react with carbonyl compounds to give alkoxide ion intermediate. These alkoxide intermediates react with primary or methyl alkyl halides or tosylates to give ethers.

(b)

Interpretation Introduction

To determine: The method of synthesis of given ether.

Interpretation: The method of synthesis of given ether is to be predicted.

Concept introduction: Lithium aluminum hydride (LiAlH4) is a strong reducing agent which reduces ketones to secondary alcohols and aldehydes to primary alcohols. Both LiAlH4 and Grignard reagents react with carbonyl compounds to give alkoxide ion intermediate. These alkoxide intermediates react with primary or methyl alkyl halides or tosylates to give ethers.

(c)

Interpretation Introduction

To determine: The method of synthesis of given ether.

Interpretation: The method of synthesis of given ether is to be predicted.

Concept introduction: Lithium aluminum hydride (LiAlH4) is a strong reducing agent which reduces ketones to secondary alcohols and aldehydes to primary alcohols. Both LiAlH4 and Grignard reagents react with carbonyl compounds to give alkoxide ion intermediate. These alkoxide intermediates react with primary or methyl alkyl halides or tosylates to give ethers.

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Answer 3

Question

Chapter 14, Problem 14.41SP

(a)

Interpretation Introduction

To determine: The method of synthesis of given ether.

Interpretation: The method of synthesis of given ether is to be predicted.

Concept introduction: Lithium aluminum hydride (LiAlH4) is a strong reducing agent which reduces ketones to secondary alcohols and aldehydes to primary alcohols. Both LiAlH4 and Grignard reagents react with carbonyl compounds to give alkoxide ion intermediate. These alkoxide intermediates react with primary or methyl alkyl halides or tosylates to give ethers.

(b)

Interpretation Introduction

To determine: The method of synthesis of given ether.

Interpretation: The method of synthesis of given ether is to be predicted.

Concept introduction: Lithium aluminum hydride (LiAlH4) is a strong reducing agent which reduces ketones to secondary alcohols and aldehydes to primary alcohols. Both LiAlH4 and Grignard reagents react with carbonyl compounds to give alkoxide ion intermediate. These alkoxide intermediates react with primary or methyl alkyl halides or tosylates to give ethers.

(c)

Interpretation Introduction

To determine: The method of synthesis of given ether.

Interpretation: The method of synthesis of given ether is to be predicted.

Concept introduction: Lithium aluminum hydride (LiAlH4) is a strong reducing agent which reduces ketones to secondary alcohols and aldehydes to primary alcohols. Both LiAlH4 and Grignard reagents react with carbonyl compounds to give alkoxide ion intermediate. These alkoxide intermediates react with primary or methyl alkyl halides or tosylates to give ethers.

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Answer 4

Question

Chapter 14, Problem 14.41SP

(a)

Interpretation Introduction

To determine: The method of synthesis of given ether.

Interpretation: The method of synthesis of given ether is to be predicted.

Concept introduction: Lithium aluminum hydride (LiAlH4) is a strong reducing agent which reduces ketones to secondary alcohols and aldehydes to primary alcohols. Both LiAlH4 and Grignard reagents react with carbonyl compounds to give alkoxide ion intermediate. These alkoxide intermediates react with primary or methyl alkyl halides or tosylates to give ethers.

(b)

Interpretation Introduction

To determine: The method of synthesis of given ether.

Interpretation: The method of synthesis of given ether is to be predicted.

Concept introduction: Lithium aluminum hydride (LiAlH4) is a strong reducing agent which reduces ketones to secondary alcohols and aldehydes to primary alcohols. Both LiAlH4 and Grignard reagents react with carbonyl compounds to give alkoxide ion intermediate. These alkoxide intermediates react with primary or methyl alkyl halides or tosylates to give ethers.

(c)

Interpretation Introduction

To determine: The method of synthesis of given ether.

Interpretation: The method of synthesis of given ether is to be predicted.

Concept introduction: Lithium aluminum hydride (LiAlH4) is a strong reducing agent which reduces ketones to secondary alcohols and aldehydes to primary alcohols. Both LiAlH4 and Grignard reagents react with carbonyl compounds to give alkoxide ion intermediate. These alkoxide intermediates react with primary or methyl alkyl halides or tosylates to give ethers.

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Answer 5

Chapter 14, Problem 14.41SP

(a)

Interpretation Introduction

To determine: The method of synthesis of given ether.

Interpretation: The method of synthesis of given ether is to be predicted.

Concept introduction: Lithium aluminum hydride (LiAlH4) is a strong reducing agent which reduces ketones to secondary alcohols and aldehydes to primary alcohols. Both LiAlH4 and Grignard reagents react with carbonyl compounds to give alkoxide ion intermediate. These alkoxide intermediates react with primary or methyl alkyl halides or tosylates to give ethers.

(b)

Interpretation Introduction

To determine: The method of synthesis of given ether.

Interpretation: The method of synthesis of given ether is to be predicted.

Concept introduction: Lithium aluminum hydride (LiAlH4) is a strong reducing agent which reduces ketones to secondary alcohols and aldehydes to primary alcohols. Both LiAlH4 and Grignard reagents react with carbonyl compounds to give alkoxide ion intermediate. These alkoxide intermediates react with primary or methyl alkyl halides or tosylates to give ethers.

(c)

Interpretation Introduction

To determine: The method of synthesis of given ether.

Interpretation: The method of synthesis of given ether is to be predicted.

Concept introduction: Lithium aluminum hydride (LiAlH4) is a strong reducing agent which reduces ketones to secondary alcohols and aldehydes to primary alcohols. Both LiAlH4 and Grignard reagents react with carbonyl compounds to give alkoxide ion intermediate. These alkoxide intermediates react with primary or methyl alkyl halides or tosylates to give ethers.

Answer 6

Chapter 14, Problem 14.41SP

(a)

Interpretation Introduction

To determine: The method of synthesis of given ether.

Interpretation: The method of synthesis of given ether is to be predicted.

Concept introduction: Lithium aluminum hydride (LiAlH4) is a strong reducing agent which reduces ketones to secondary alcohols and aldehydes to primary alcohols. Both LiAlH4 and Grignard reagents react with carbonyl compounds to give alkoxide ion intermediate. These alkoxide intermediates react with primary or methyl alkyl halides or tosylates to give ethers.

Answer 7

Chapter 14, Problem 14.41SP

(a)

Interpretation Introduction

To determine: The method of synthesis of given ether.

Interpretation: The method of synthesis of given ether is to be predicted.

Concept introduction: Lithium aluminum hydride (LiAlH4) is a strong reducing agent which reduces ketones to secondary alcohols and aldehydes to primary alcohols. Both LiAlH4 and Grignard reagents react with carbonyl compounds to give alkoxide ion intermediate. These alkoxide intermediates react with primary or methyl alkyl halides or tosylates to give ethers.

Answer 8

(b)

Interpretation Introduction

To determine: The method of synthesis of given ether.

Interpretation: The method of synthesis of given ether is to be predicted.

Concept introduction: Lithium aluminum hydride (LiAlH4) is a strong reducing agent which reduces ketones to secondary alcohols and aldehydes to primary alcohols. Both LiAlH4 and Grignard reagents react with carbonyl compounds to give alkoxide ion intermediate. These alkoxide intermediates react with primary or methyl alkyl halides or tosylates to give ethers.

Answer 9

(b)

Interpretation Introduction

To determine: The method of synthesis of given ether.

Interpretation: The method of synthesis of given ether is to be predicted.

Concept introduction: Lithium aluminum hydride (LiAlH4) is a strong reducing agent which reduces ketones to secondary alcohols and aldehydes to primary alcohols. Both LiAlH4 and Grignard reagents react with carbonyl compounds to give alkoxide ion intermediate. These alkoxide intermediates react with primary or methyl alkyl halides or tosylates to give ethers.

Answer 10

(c)

Interpretation Introduction

To determine: The method of synthesis of given ether.

Interpretation: The method of synthesis of given ether is to be predicted.

Concept introduction: Lithium aluminum hydride (LiAlH4) is a strong reducing agent which reduces ketones to secondary alcohols and aldehydes to primary alcohols. Both LiAlH4 and Grignard reagents react with carbonyl compounds to give alkoxide ion intermediate. These alkoxide intermediates react with primary or methyl alkyl halides or tosylates to give ethers.

Answer 11

(c)

Interpretation Introduction

To determine: The method of synthesis of given ether.

Interpretation: The method of synthesis of given ether is to be predicted.

Concept introduction: Lithium aluminum hydride (LiAlH4) is a strong reducing agent which reduces ketones to secondary alcohols and aldehydes to primary alcohols. Both LiAlH4 and Grignard reagents react with carbonyl compounds to give alkoxide ion intermediate. These alkoxide intermediates react with primary or methyl alkyl halides or tosylates to give ethers.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 14.2C - Rank the given solvents in decreasing order of...Ch. 14.2D - Prob. 14.2P Ch. 14.2D - In the presence of 18-crown-6, potassium...Ch. 14.3B - Give a common name (when possible) and a...Ch. 14.3C - Prob. 14.5P Ch. 14.3C - Name the following heterocyclic ethers.Ch. 14.4 - Propose a fragmentation to account for each...Ch. 14.5 - Prob. 14.8P Ch. 14.5 - Prob. 14.9P Ch. 14.6 - Prob. 14.10P

Solution Summary: The author explains the method of synthesis of given ether. Lithium aluminum hydride reduces ketones to secondary alcohols and aldehydes to primary alcohol.

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