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(a)
Interpretation:
The common names of the acid chloride and carboxylate anion reactants and acid anhydride products have to be written.
Concept Introduction:
Naming of Acid Chloride:
Acid chlorides are derivatives of carboxylic acids with the formula,
Acid chlorides are named by replacing the –ic acid ending of the common name with –yl chloride and –oic acid ending of the IUPAC name of the
Naming of Acid Anhydrides:
Acid anhydrides are compounds with the formula,
Acid anhydride is divided into symmetrical and unsymmetrical anhydrides.
Symmetrical anhydrides: contain same acyl groups. They are named by replacing acid ending of the carboxylic acid with the word anhydride.
Unsymmetrical anhydrides: contain different acyl groups. They are named by arranging the names of two-parent carboxylic acid followed by the word anhydride. The names of the carboxylic acid are arranged by size or in alphabetical order.
(b)
Interpretation:
The common names of the acid chloride and carboxylate anion reactants and acid anhydride products have to be written.
Concept Introduction:
Naming of Acid Chloride:
Acid chlorides are derivatives of carboxylic acids with the formula,
Acid chlorides are named by replacing the –ic acid ending of the common name with –yl chloride and –oic acid ending of the IUPAC name of the carboxylic acid with –oyl chloride.
Naming of Acid Anhydrides:
Acid anhydrides are compounds with the formula,
Acid anhydride is divided into symmetrical and unsymmetrical anhydrides.
Symmetrical anhydrides: contain same acyl groups. They are named by replacing acid ending of the carboxylic acid with the word anhydride.
Unsymmetrical anhydrides: contain different acyl groups. They are named by arranging the names of two-parent carboxylic acid followed by the word anhydride. The names of the carboxylic acid are arranged by size or in alphabetical order.
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Chapter 14 Solutions
General, Organic, and Biochemistry
- A pdf file of your hand drawn, stepwise mechanisms for the reactions. For each reaction in the assignment, you must write each mechanism three times (there are 10 reactions, so 30 mechanisms). (A) do the work on a tablet and save as a pdf., it is expected to write each mechanism out and NOT copy and paste the mechanism after writing it just once. Everything should be drawn out stepwise and every bond that is formed and broken in the process of the reaction, and is expected to see all relevant lone pair electrons and curved arrows. Aldol: NaOH HO H Δ NaOH Δarrow_forwardNonearrow_forwardDraw structures corresponding to the following names and give IUPAC names for the following compounds: (8 Point) a) b) c) CH3 CH2CH3 CH3CHCH2CH2CH CH3 C=C H3C H H2C=C=CHCH3 d) CI e) (3E,5Z)-2,6-Dimethyl-1,3,5,7-octatetraene f) (Z)-4-bromo-3-methyl-3-penten-1-yne g) cis-1-Bromo-2-ethylcyclopentane h) (5R)-4,4,5-trichloro-3,3-dimethyldecanearrow_forward
- Draw a Newman projection from carbon 3 to carbon 2 in the highest energy conformation for the following molecule. What is this conformation called? What kind of strain is present? Brarrow_forwardWhich of the following dienophiles is most reactive in a Diels-Alder reaction: Please explain why the correct answer to this question is option 5. Please provide a detailed explanation.arrow_forwardWhich of the following would you expect to be aromatic? Please provide a detailed explanation.arrow_forward
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