CONNECT IA GENERAL ORGANIC&BIO CHEMISTRY
4th Edition
ISBN: 9781260562620
Author: SMITH
Publisher: MCG
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Chapter 14, Problem 91P
Interpretation Introduction
Interpretation:
The reason for two ether molecules do not form hydrogen bonds with each other but can form a hydrogen bond with water molecule needs to be explained
Concept Introduction:
The covalent bond formed between the hydrogen atom and electronegative elements like fluorine, nitrogen, and oxygen in a given molecule is termed as a hydrogen bond.
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Explain why these compounds (1-propanol, ethylene glycol, and ethanethiol) experience different intermolecular forces based on their molecular structure.
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Chapter 14 Solutions
CONNECT IA GENERAL ORGANIC&BIO CHEMISTRY
Ch. 14.1 - Prob. 14.1PCh. 14.2 - Prob. 14.1PPCh. 14.2 - Classify each hydroxyl group in sorbitol as 1°,...Ch. 14.2 - Prob. 14.3PCh. 14.2 - Prob. 14.4PCh. 14.3 - Prob. 14.2PPCh. 14.3 - Give the structure corresponding to each name a....Ch. 14.5 - Draw the products formed when each alcohol is...Ch. 14.5 - Prob. 14.6PCh. 14.5 - Prob. 14.7P
Ch. 14.5 - Prob. 14.4PPCh. 14.6 - Prob. 14.8PCh. 14.7 - Prob. 14.9PCh. 14.7 - Prob. 14.5PPCh. 14.7 - Prob. 14.10PCh. 14.7 - Name each ether. CH3OCH2CH2CH2CH3Ch. 14.7 - Prob. 14.11PCh. 14.8 - (a) Translate the hall and stick model of...Ch. 14.8 - Prob. 14.13PCh. 14.9 - Prob. 14.14PCh. 14.9 - Prob. 14.15PCh. 14.9 - Prob. 14.16PCh. 14.9 - Prob. 14.17PCh. 14.9 - Prob. 14.18PCh. 14.9 - Prob. 14.19PCh. 14.9 - Prob. 14.20PCh. 14.10 - Give the IUPAC name for each thiol.Ch. 14.10 - Prob. 14.21PCh. 14.10 - Prob. 14.22PCh. 14 - Classify each alcohol as 1°, 2°, or 3o a....Ch. 14 - Prob. 24PCh. 14 - Prob. 25PCh. 14 - Classify each halide hi A as 1°, 2°, or 3°. A is a...Ch. 14 - Prob. 27PCh. 14 - Draw the structure of a molecule that fits each...Ch. 14 - Draw the structure of the six constitutional...Ch. 14 - Draw the structure of the four constitutional...Ch. 14 - Draw the structure of l-propanethiol, a compound...Ch. 14 - Prob. 32PCh. 14 - Prob. 33PCh. 14 - Prob. 34PCh. 14 - Prob. 35PCh. 14 - Answer each question about alcohol B. Draw a...Ch. 14 - Prob. 37PCh. 14 - Give the IUAPC name for each alcohol.Ch. 14 - Prob. 39PCh. 14 - Prob. 40PCh. 14 - Prob. 41PCh. 14 - Prob. 42PCh. 14 - Draw the structures and give the IUPAC names for...Ch. 14 - Prob. 44PCh. 14 - Prob. 45PCh. 14 - Prob. 46PCh. 14 - Give the structure corresponding to each IUPAC...Ch. 14 - Give the structure corresponding to each IUPAC...Ch. 14 - Which compound in each pair has the higher boiling...Ch. 14 - Rank the compounds in order of increasing melting...Ch. 14 - Rank the following compounds in order of...Ch. 14 - Rank the following compounds in order of...Ch. 14 - Prob. 53PCh. 14 - Prob. 54PCh. 14 - Prob. 55PCh. 14 - Prob. 56PCh. 14 - Prob. 57PCh. 14 - Prob. 58PCh. 14 - Prob. 59PCh. 14 - Prob. 60PCh. 14 - Prob. 61PCh. 14 - Prob. 62PCh. 14 - Prob. 63PCh. 14 - Prob. 64PCh. 14 - Prob. 65PCh. 14 - Prob. 66PCh. 14 - Prob. 67PCh. 14 - Prob. 68PCh. 14 - Prob. 69PCh. 14 - Prob. 70PCh. 14 - Prob. 71PCh. 14 - Prob. 72PCh. 14 - Prob. 73PCh. 14 - Prob. 74PCh. 14 - Prob. 75PCh. 14 - Prob. 76PCh. 14 - Prob. 77PCh. 14 - Prob. 78PCh. 14 - Prob. 79PCh. 14 - Prob. 80PCh. 14 - With reference to the halogenated organic...Ch. 14 - Prob. 82PCh. 14 - Prob. 83PCh. 14 - Prob. 84PCh. 14 - Write out the chemical reaction that occurs when a...Ch. 14 - Prob. 86PCh. 14 - Prob. 87PCh. 14 - Lactic acid [CH3CH(OH)CO2H] gives sour milk its...Ch. 14 - Prob. 89PCh. 14 - Prob. 90PCh. 14 - Prob. 91PCh. 14 - Prob. 92PCh. 14 - Prob. 93PCh. 14 - Answer the following questions about alcohol B....Ch. 14 - Prob. 95CPCh. 14 - Dehydration of alcohol C forms two products of...
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- why do some ethers with the same molecular formulas as their respective alcohols have a lower boiling point?arrow_forwardA) The boiling points of aldehydes and ketones is higher than that of alkanes but lower than that of alcohols. Discuss these differences in boiling points for these compounds. B) Acetone is a ketone and a solvent used to remove nail polish. If acetone cannot hydrogen bond with each other, why is it soluble in water?arrow_forwardis this statement correct?arrow_forward
- Which is NOT a physical property of alcohols or phenols? O Phenols are generally only slightly soluble in water. O The hydroxyl group of an alcohol is nonpolar. The solubilities of normal primary alcohols in water decrease with increasing molecular weight. Boiling points of normal primary alcohols increase with increasing molecular weight.arrow_forwardExplain why alcohols have much higher boiling points than hydrocarbons and alkyl halides of similar molecular weight.arrow_forwardWhen diethyl ether is spilled on the skin, the skin takes on a dry appearance. Explain whether this effect is more likely due to a removal of water or a removal of natural skin oilsarrow_forward
- Aldehydes and Ketones have lower boiling points than corresponding alcohols. Why ?arrow_forwardexplain why the boiling points of alkenes are much lower than those of alcohols with similar molecular masses.arrow_forwardDimethyl ether and ethanol have the same molecular mass. Dimethyl ether is a gas at room temperature, and ethanol is a liquid at room temperature. Explain these observations.arrow_forward
- Methanol is fairly volatile and evaporates quickly if spilled. Methanol is also absorbed quite readily through the skin. If, in the laboratory, methanol accidentally spilled on your clothing, why would it be a serious mistake to just let it evaporate?arrow_forwardA mixture of ethanol and 1propanol is heated to 140C in the presence of sulfuric acid. Careful analysis reveals that three ethers are formed. Write formulas for these three products, name each, and explain why three form, rather than a single product.arrow_forwardWhich of the following statements are true with respect to ether? Boiling point of ether is lower than that of alcohols. They are relatively inert. They react with metallic sodium. They react with oxidizing agents. They do not react with dilute bases.arrow_forward
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