(a) Interpretation: The hydroxyl groups, halogens, sulfhydryl groups and ether oxygen of each compound, chondrocohole A, 3-methyl-3-sulfanyl-1-hexanol, and salmeterol should be labeled. Concept introduction: A functional group is defined as a specific group of atoms or bonds within a compound and functional group is decided the chemical characteristic of the compound. The same functional groups have same chemical properties, and undergoing same reactions. In organic chemistry , the most common functional groups are carbonyls (C=O), carboxylic acids (CO 2 H), alcohols (-OH), esters (CO 2 R), and amines (NH 2 ).

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Answer 1

Question

Chapter 14.1, Problem 14.1P

Interpretation Introduction

(a)

Interpretation:

The hydroxyl groups, halogens, sulfhydryl groups and ether oxygen of each compound, chondrocohole A, 3-methyl-3-sulfanyl-1-hexanol, and salmeterol should be labeled.

Concept introduction:

A functional group is defined as a specific group of atoms or bonds within a compound and functional group is decided the chemical characteristic of the compound. The same functional groups have same chemical properties, and undergoing same reactions. In organic chemistry, the most common functional groups are carbonyls (C=O), carboxylic acids (CO₂H), alcohols (-OH), esters (CO₂R), and amines (NH₂).

Interpretation Introduction

(b)

Interpretation:

The −OH that is not a part of alcohol should be labeled and need to explain the choice.

Concept introduction:

A functional group is defined as a specific group of atoms or bonds within a compound and functional group is decided the chemical characteristic of the compound. The same functional groups have same chemical properties, and undergoing same reactions. In organic chemistry, the most common functional groups are carbonyls (C=O), carboxylic acids (CO₂H), alcohols (-OH), esters (CO₂R), and amines (NH₂).

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What spectral features allow you to differentiate the product from the starting material? Use four separate paragraphs for each set of comparisons. You should have one paragraph each devoted to MS, HNMR, CNMR and IR. 2) For MS, the differing masses of molecular ions are a popular starting point. Including a unique fragmentation is important, too. 3) For HNMR, CNMR and IR state the peaks that are different and what makes them different (usually the presence or absence of certain groups). See if you can find two differences (in each set of IR, HNMR and CNMR spectra) due to the presence or absence of a functional group. Include peak locations. Alternatively, you can state a shift of a peak due to a change near a given functional group. Including peak locations for shifted peaks, as well as what these peaks are due to. Ideally, your focus should be on not just identifying the differences but explaining them in terms of functional group changes.

Answer 2

Question

Chapter 14.1, Problem 14.1P

Interpretation Introduction

(a)

Interpretation:

The hydroxyl groups, halogens, sulfhydryl groups and ether oxygen of each compound, chondrocohole A, 3-methyl-3-sulfanyl-1-hexanol, and salmeterol should be labeled.

Concept introduction:

A functional group is defined as a specific group of atoms or bonds within a compound and functional group is decided the chemical characteristic of the compound. The same functional groups have same chemical properties, and undergoing same reactions. In organic chemistry, the most common functional groups are carbonyls (C=O), carboxylic acids (CO₂H), alcohols (-OH), esters (CO₂R), and amines (NH₂).

Interpretation Introduction

(b)

Interpretation:

The −OH that is not a part of alcohol should be labeled and need to explain the choice.

Concept introduction:

A functional group is defined as a specific group of atoms or bonds within a compound and functional group is decided the chemical characteristic of the compound. The same functional groups have same chemical properties, and undergoing same reactions. In organic chemistry, the most common functional groups are carbonyls (C=O), carboxylic acids (CO₂H), alcohols (-OH), esters (CO₂R), and amines (NH₂).

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Answer 3

Question

Chapter 14.1, Problem 14.1P

Interpretation Introduction

(a)

Interpretation:

The hydroxyl groups, halogens, sulfhydryl groups and ether oxygen of each compound, chondrocohole A, 3-methyl-3-sulfanyl-1-hexanol, and salmeterol should be labeled.

Concept introduction:

A functional group is defined as a specific group of atoms or bonds within a compound and functional group is decided the chemical characteristic of the compound. The same functional groups have same chemical properties, and undergoing same reactions. In organic chemistry, the most common functional groups are carbonyls (C=O), carboxylic acids (CO₂H), alcohols (-OH), esters (CO₂R), and amines (NH₂).

Interpretation Introduction

(b)

Interpretation:

The −OH that is not a part of alcohol should be labeled and need to explain the choice.

Concept introduction:

A functional group is defined as a specific group of atoms or bonds within a compound and functional group is decided the chemical characteristic of the compound. The same functional groups have same chemical properties, and undergoing same reactions. In organic chemistry, the most common functional groups are carbonyls (C=O), carboxylic acids (CO₂H), alcohols (-OH), esters (CO₂R), and amines (NH₂).

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Answer 4

Question

Chapter 14.1, Problem 14.1P

Interpretation Introduction

(a)

Interpretation:

The hydroxyl groups, halogens, sulfhydryl groups and ether oxygen of each compound, chondrocohole A, 3-methyl-3-sulfanyl-1-hexanol, and salmeterol should be labeled.

Concept introduction:

A functional group is defined as a specific group of atoms or bonds within a compound and functional group is decided the chemical characteristic of the compound. The same functional groups have same chemical properties, and undergoing same reactions. In organic chemistry, the most common functional groups are carbonyls (C=O), carboxylic acids (CO₂H), alcohols (-OH), esters (CO₂R), and amines (NH₂).

Interpretation Introduction

(b)

Interpretation:

The −OH that is not a part of alcohol should be labeled and need to explain the choice.

Concept introduction:

A functional group is defined as a specific group of atoms or bonds within a compound and functional group is decided the chemical characteristic of the compound. The same functional groups have same chemical properties, and undergoing same reactions. In organic chemistry, the most common functional groups are carbonyls (C=O), carboxylic acids (CO₂H), alcohols (-OH), esters (CO₂R), and amines (NH₂).

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Answer 5

Chapter 14.1, Problem 14.1P

Interpretation Introduction

(a)

Interpretation:

The hydroxyl groups, halogens, sulfhydryl groups and ether oxygen of each compound, chondrocohole A, 3-methyl-3-sulfanyl-1-hexanol, and salmeterol should be labeled.

Concept introduction:

A functional group is defined as a specific group of atoms or bonds within a compound and functional group is decided the chemical characteristic of the compound. The same functional groups have same chemical properties, and undergoing same reactions. In organic chemistry, the most common functional groups are carbonyls (C=O), carboxylic acids (CO₂H), alcohols (-OH), esters (CO₂R), and amines (NH₂).

Interpretation Introduction

(b)

Interpretation:

The −OH that is not a part of alcohol should be labeled and need to explain the choice.

Concept introduction:

A functional group is defined as a specific group of atoms or bonds within a compound and functional group is decided the chemical characteristic of the compound. The same functional groups have same chemical properties, and undergoing same reactions. In organic chemistry, the most common functional groups are carbonyls (C=O), carboxylic acids (CO₂H), alcohols (-OH), esters (CO₂R), and amines (NH₂).

Answer 6

Chapter 14.1, Problem 14.1P

Interpretation Introduction

(a)

Interpretation:

The hydroxyl groups, halogens, sulfhydryl groups and ether oxygen of each compound, chondrocohole A, 3-methyl-3-sulfanyl-1-hexanol, and salmeterol should be labeled.

Concept introduction:

A functional group is defined as a specific group of atoms or bonds within a compound and functional group is decided the chemical characteristic of the compound. The same functional groups have same chemical properties, and undergoing same reactions. In organic chemistry, the most common functional groups are carbonyls (C=O), carboxylic acids (CO₂H), alcohols (-OH), esters (CO₂R), and amines (NH₂).

Answer 7

Chapter 14.1, Problem 14.1P

Interpretation Introduction

(a)

Interpretation:

The hydroxyl groups, halogens, sulfhydryl groups and ether oxygen of each compound, chondrocohole A, 3-methyl-3-sulfanyl-1-hexanol, and salmeterol should be labeled.

Concept introduction:

A functional group is defined as a specific group of atoms or bonds within a compound and functional group is decided the chemical characteristic of the compound. The same functional groups have same chemical properties, and undergoing same reactions. In organic chemistry, the most common functional groups are carbonyls (C=O), carboxylic acids (CO₂H), alcohols (-OH), esters (CO₂R), and amines (NH₂).

Answer 8

Interpretation Introduction

(b)

Interpretation:

The −OH that is not a part of alcohol should be labeled and need to explain the choice.

Concept introduction:

A functional group is defined as a specific group of atoms or bonds within a compound and functional group is decided the chemical characteristic of the compound. The same functional groups have same chemical properties, and undergoing same reactions. In organic chemistry, the most common functional groups are carbonyls (C=O), carboxylic acids (CO₂H), alcohols (-OH), esters (CO₂R), and amines (NH₂).

Answer 9

Interpretation Introduction

(b)

Interpretation:

The −OH that is not a part of alcohol should be labeled and need to explain the choice.

Concept introduction:

A functional group is defined as a specific group of atoms or bonds within a compound and functional group is decided the chemical characteristic of the compound. The same functional groups have same chemical properties, and undergoing same reactions. In organic chemistry, the most common functional groups are carbonyls (C=O), carboxylic acids (CO₂H), alcohols (-OH), esters (CO₂R), and amines (NH₂).

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 14.1 - Prob. 14.1P Ch. 14.2 - Prob. 14.1PP Ch. 14.2 - Classify each hydroxyl group in sorbitol as 1°,...Ch. 14.2 - Prob. 14.3P Ch. 14.2 - Prob. 14.4P Ch. 14.3 - Prob. 14.2PP Ch. 14.3 - Give the structure corresponding to each name a....Ch. 14.5 - Draw the products formed when each alcohol is...Ch. 14.5 - Prob. 14.6P Ch. 14.5 - Prob. 14.7P

Solution Summary: The author explains that the hydroxyl groups, halogens, and sulfhydryls of each compound should be labeled.

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