(a) Interpretation: The structure of products formed from dehydration of 3-hexanol needs to be determined. Concept Introduction: According to Zaitsev's rule, in elimination reaction the alkene formed in major amount is the one which is formed due to the removal of hydrogen from the beta carbon atom with a smaller number of hydrogen atoms. Also, the alkene formed as major product is more substituted. Dehydration reaction is defined as removal of water molecule from a compound. An alcohol reacts with acid to from alkene as a dehydration product.

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Answer 1

Question

Chapter 14, Problem 59P

Interpretation Introduction

(a)

Interpretation:

The structure of products formed from dehydration of 3-hexanol needs to be determined.

Concept Introduction:

According to Zaitsev's rule, in elimination reaction the alkene formed in major amount is the one which is formed due to the removal of hydrogen from the beta carbon atom with a smaller number of hydrogen atoms. Also, the alkene formed as major product is more substituted.

Dehydration reaction is defined as removal of water molecule from a compound. An alcohol reacts with acid to from alkene as a dehydration product.

Interpretation Introduction

(b)

Interpretation:

The reason for the formation of both the products in same amount needs to be explained.

Concept Introduction:

According to Zaitsev's rule, in elimination reaction the alkene formed in major amount is the one which is formed due to the removal of hydrogen from the beta carbon atom with a smaller number of hydrogen atoms. Also, the alkene formed as major product is more substituted.

Dehydration reaction is defined as removal of water molecule from a compound. An alcohol reacts with acid to from alkene as a dehydration product.

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Name these aldehydes:

IV. Compounds A and B are isomers of the molecular formula C9H19Br. Both yield the same alkene Cin an elimination reaction. Hydrogenation of C yields the product 2,3,3,4 tetramethyl pentane. What are the structures of A, B, and C?

Draw the structures of (a) 6-methyl-3-heptanol and (b) trans-2-methylcyclohexanol

Answer 2

Question

Chapter 14, Problem 59P

Interpretation Introduction

(a)

Interpretation:

The structure of products formed from dehydration of 3-hexanol needs to be determined.

Concept Introduction:

According to Zaitsev's rule, in elimination reaction the alkene formed in major amount is the one which is formed due to the removal of hydrogen from the beta carbon atom with a smaller number of hydrogen atoms. Also, the alkene formed as major product is more substituted.

Dehydration reaction is defined as removal of water molecule from a compound. An alcohol reacts with acid to from alkene as a dehydration product.

Interpretation Introduction

(b)

Interpretation:

The reason for the formation of both the products in same amount needs to be explained.

Concept Introduction:

According to Zaitsev's rule, in elimination reaction the alkene formed in major amount is the one which is formed due to the removal of hydrogen from the beta carbon atom with a smaller number of hydrogen atoms. Also, the alkene formed as major product is more substituted.

Dehydration reaction is defined as removal of water molecule from a compound. An alcohol reacts with acid to from alkene as a dehydration product.

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Answer 3

Question

Chapter 14, Problem 59P

Interpretation Introduction

(a)

Interpretation:

The structure of products formed from dehydration of 3-hexanol needs to be determined.

Concept Introduction:

According to Zaitsev's rule, in elimination reaction the alkene formed in major amount is the one which is formed due to the removal of hydrogen from the beta carbon atom with a smaller number of hydrogen atoms. Also, the alkene formed as major product is more substituted.

Dehydration reaction is defined as removal of water molecule from a compound. An alcohol reacts with acid to from alkene as a dehydration product.

Interpretation Introduction

(b)

Interpretation:

The reason for the formation of both the products in same amount needs to be explained.

Concept Introduction:

According to Zaitsev's rule, in elimination reaction the alkene formed in major amount is the one which is formed due to the removal of hydrogen from the beta carbon atom with a smaller number of hydrogen atoms. Also, the alkene formed as major product is more substituted.

Dehydration reaction is defined as removal of water molecule from a compound. An alcohol reacts with acid to from alkene as a dehydration product.

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Answer 4

Question

Chapter 14, Problem 59P

Interpretation Introduction

(a)

Interpretation:

The structure of products formed from dehydration of 3-hexanol needs to be determined.

Concept Introduction:

According to Zaitsev's rule, in elimination reaction the alkene formed in major amount is the one which is formed due to the removal of hydrogen from the beta carbon atom with a smaller number of hydrogen atoms. Also, the alkene formed as major product is more substituted.

Dehydration reaction is defined as removal of water molecule from a compound. An alcohol reacts with acid to from alkene as a dehydration product.

Interpretation Introduction

(b)

Interpretation:

The reason for the formation of both the products in same amount needs to be explained.

Concept Introduction:

According to Zaitsev's rule, in elimination reaction the alkene formed in major amount is the one which is formed due to the removal of hydrogen from the beta carbon atom with a smaller number of hydrogen atoms. Also, the alkene formed as major product is more substituted.

Dehydration reaction is defined as removal of water molecule from a compound. An alcohol reacts with acid to from alkene as a dehydration product.

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Answer 5

Chapter 14, Problem 59P

Interpretation Introduction

(a)

Interpretation:

The structure of products formed from dehydration of 3-hexanol needs to be determined.

Concept Introduction:

According to Zaitsev's rule, in elimination reaction the alkene formed in major amount is the one which is formed due to the removal of hydrogen from the beta carbon atom with a smaller number of hydrogen atoms. Also, the alkene formed as major product is more substituted.

Dehydration reaction is defined as removal of water molecule from a compound. An alcohol reacts with acid to from alkene as a dehydration product.

Interpretation Introduction

(b)

Interpretation:

The reason for the formation of both the products in same amount needs to be explained.

Concept Introduction:

According to Zaitsev's rule, in elimination reaction the alkene formed in major amount is the one which is formed due to the removal of hydrogen from the beta carbon atom with a smaller number of hydrogen atoms. Also, the alkene formed as major product is more substituted.

Dehydration reaction is defined as removal of water molecule from a compound. An alcohol reacts with acid to from alkene as a dehydration product.

Answer 6

Chapter 14, Problem 59P

Interpretation Introduction

(a)

Interpretation:

The structure of products formed from dehydration of 3-hexanol needs to be determined.

Concept Introduction:

According to Zaitsev's rule, in elimination reaction the alkene formed in major amount is the one which is formed due to the removal of hydrogen from the beta carbon atom with a smaller number of hydrogen atoms. Also, the alkene formed as major product is more substituted.

Dehydration reaction is defined as removal of water molecule from a compound. An alcohol reacts with acid to from alkene as a dehydration product.

Answer 7

Chapter 14, Problem 59P

Interpretation Introduction

(a)

Interpretation:

The structure of products formed from dehydration of 3-hexanol needs to be determined.

Concept Introduction:

According to Zaitsev's rule, in elimination reaction the alkene formed in major amount is the one which is formed due to the removal of hydrogen from the beta carbon atom with a smaller number of hydrogen atoms. Also, the alkene formed as major product is more substituted.

Dehydration reaction is defined as removal of water molecule from a compound. An alcohol reacts with acid to from alkene as a dehydration product.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The reason for the formation of both the products in same amount needs to be explained.

Concept Introduction:

According to Zaitsev's rule, in elimination reaction the alkene formed in major amount is the one which is formed due to the removal of hydrogen from the beta carbon atom with a smaller number of hydrogen atoms. Also, the alkene formed as major product is more substituted.

Dehydration reaction is defined as removal of water molecule from a compound. An alcohol reacts with acid to from alkene as a dehydration product.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The reason for the formation of both the products in same amount needs to be explained.

Concept Introduction:

According to Zaitsev's rule, in elimination reaction the alkene formed in major amount is the one which is formed due to the removal of hydrogen from the beta carbon atom with a smaller number of hydrogen atoms. Also, the alkene formed as major product is more substituted.

Dehydration reaction is defined as removal of water molecule from a compound. An alcohol reacts with acid to from alkene as a dehydration product.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 14.1 - Prob. 14.1P Ch. 14.2 - Prob. 14.1PP Ch. 14.2 - Classify each hydroxyl group in sorbitol as 1°,...Ch. 14.2 - Prob. 14.3P Ch. 14.2 - Prob. 14.4P Ch. 14.3 - Prob. 14.2PP Ch. 14.3 - Give the structure corresponding to each name a....Ch. 14.5 - Draw the products formed when each alcohol is...Ch. 14.5 - Prob. 14.6P Ch. 14.5 - Prob. 14.7P

Solution Summary: The author explains that the structure of products formed from dehydration of 3-hexanol needs to be determined.

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Chapter 14 Solutions