The diol needed for preparation of 2,3-butanedione by an oxidation reaction should be predicted. Concept Introduction: Oxidation means addition of oxygen or removal of hydrogen. Reduction may be defined as the process of addition of hydrogen or removal of oxygen.

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Answer 1

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 14, Problem 86P

Interpretation Introduction

Interpretation:

The diol needed for preparation of 2,3-butanedione by an oxidation reaction should be predicted.

Concept Introduction:

Oxidation means addition of oxygen or removal of hydrogen. Reduction may be defined as the process of addition of hydrogen or removal of oxygen.

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5. A solution of sucrose is fermented in a vessel until the evolution of CO2 ceases. Then, the product solution is analyzed and found to contain, 45% ethanol; 5% acetic acid; and 15% glycerin by weight. If the original charge is 500 kg, evaluate; e. The ratio of sucrose to water in the original charge (wt/wt). f. Moles of CO2 evolved. g. Maximum possible amount of ethanol that could be formed. h. Conversion efficiency. i. Per cent excess of excess reactant. Reactions: Inversion reaction: C12H22O11 + H2O →2C6H12O6 Fermentation reaction: C6H12O6 →→2C2H5OH + 2CO2 Formation of acetic acid and glycerin: C6H12O6 + C2H5OH + H₂O→ CH3COOH + 2C3H8O3

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13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the molecule depicted below. Bond B 2°C. +2°C. cleavage Bond A •CH3 + 26.← Cleavage 2°C. + Bond C +3°C• CH3 2C Cleavage E 2°C. 26. weakest bond Intact molecule Strongest 3°C 20. Gund Largest argest a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in appropriate boxes. C Weakest bond A Produces Most Bond Strongest Bond Strongest Gund produces least stable radicals Weakest Stable radical b. (4pts) Consider the relative stability of all cleavage products that form when bonds A, B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B, and C are all carbon radicals. i. Which ONE cleavage product is the most stable? A condensed or bond line representation is fine. 13°C. formed in bound C cleavage ii. Which ONE cleavage product is the least stable? A condensed or bond line representation is fine. • CH3 methyl radical Formed in Gund A Cleavage c.…

Answer 2

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 14, Problem 86P

Interpretation Introduction

Interpretation:

The diol needed for preparation of 2,3-butanedione by an oxidation reaction should be predicted.

Concept Introduction:

Oxidation means addition of oxygen or removal of hydrogen. Reduction may be defined as the process of addition of hydrogen or removal of oxygen.

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Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 14, Problem 86P

Interpretation Introduction

Interpretation:

The diol needed for preparation of 2,3-butanedione by an oxidation reaction should be predicted.

Concept Introduction:

Oxidation means addition of oxygen or removal of hydrogen. Reduction may be defined as the process of addition of hydrogen or removal of oxygen.

Expert Solution & Answer

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Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 14, Problem 86P

Interpretation Introduction

Interpretation:

The diol needed for preparation of 2,3-butanedione by an oxidation reaction should be predicted.

Concept Introduction:

Oxidation means addition of oxygen or removal of hydrogen. Reduction may be defined as the process of addition of hydrogen or removal of oxygen.

Expert Solution & Answer

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Answer 5

Chapter 14, Problem 86P

Interpretation Introduction

Interpretation:

The diol needed for preparation of 2,3-butanedione by an oxidation reaction should be predicted.

Concept Introduction:

Oxidation means addition of oxygen or removal of hydrogen. Reduction may be defined as the process of addition of hydrogen or removal of oxygen.

Answer 6

Chapter 14, Problem 86P

Interpretation Introduction

Interpretation:

The diol needed for preparation of 2,3-butanedione by an oxidation reaction should be predicted.

Concept Introduction:

Oxidation means addition of oxygen or removal of hydrogen. Reduction may be defined as the process of addition of hydrogen or removal of oxygen.

Answer 7

Chapter 14, Problem 86P

Interpretation Introduction

Interpretation:

The diol needed for preparation of 2,3-butanedione by an oxidation reaction should be predicted.

Concept Introduction:

Oxidation means addition of oxygen or removal of hydrogen. Reduction may be defined as the process of addition of hydrogen or removal of oxygen.

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 14.1 - Prob. 14.1P Ch. 14.2 - Prob. 14.1PP Ch. 14.2 - Classify each hydroxyl group in sorbitol as 1°,...Ch. 14.2 - Prob. 14.3P Ch. 14.2 - Prob. 14.4P Ch. 14.3 - Prob. 14.2PP Ch. 14.3 - Give the structure corresponding to each name a....Ch. 14.5 - Draw the products formed when each alcohol is...Ch. 14.5 - Prob. 14.6P Ch. 14.5 - Prob. 14.7P

The diol needed for preparation of 2,3-butanedione by an oxidation reaction should be predicted. Concept Introduction: Oxidation means addition of oxygen or removal of hydrogen. Reduction may be defined as the process of addition of hydrogen or removal of oxygen.

Solution Summary: The author explains the diol needed for preparation of 2,3-butanedione by an oxidation reaction should be predicted.

Concept explainers

Interpretation:

The diol needed for preparation of 2,3-butanedione by an oxidation reaction should be predicted.

Concept Introduction:

Oxidation means addition of oxygen or removal of hydrogen. Reduction may be defined as the process of addition of hydrogen or removal of oxygen.

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Chapter 14 Solutions

The diol needed for preparation of 2,3-butanedione by an oxidation reaction should be predicted. Concept Introduction: Oxidation means addition of oxygen or removal of hydrogen. Reduction may be defined as the process of addition of hydrogen or removal of oxygen.

Solution Summary: The author explains the diol needed for preparation of 2,3-butanedione by an oxidation reaction should be predicted.

Concept explainers

Interpretation: The diol needed for preparation of 2,3-butanedione by an oxidation reaction should be predicted. Concept Introduction: Oxidation means addition of oxygen or removal of hydrogen. Reduction may be defined as the process of addition of hydrogen or removal of oxygen.

Want to see the full answer?

Chapter 14 Solutions

Interpretation:

The diol needed for preparation of 2,3-butanedione by an oxidation reaction should be predicted.

Concept Introduction:

Oxidation means addition of oxygen or removal of hydrogen. Reduction may be defined as the process of addition of hydrogen or removal of oxygen.