(a) Interpretation: Thiols should be identified after reduction of C H 3 S − S C H 2 C H 2 C H 3 . Concept Introduction: Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon. Reaction of disulfides with reducing agentwill form thiolsand the reaction is known as a reduction reaction.

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Answer 1

Question

Chapter 14, Problem 77P

Interpretation Introduction

(a)

Interpretation:

Thiols should be identified after reduction of CH3S−SCH2CH2CH3.

Concept Introduction:

Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon.

Reaction of disulfides with reducing agentwill form thiolsand the reaction is known as a reduction reaction.

Interpretation Introduction

(b)

Interpretation:

Thiols should be identified after reduction of CH2=CHCH2S−SCH2CH2CH3.

Concept Introduction:

Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon.

Reaction of disulfides with reducing agent will form thiols and the reaction is known as a reduction reaction.

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Students have asked these similar questions

The representation of a one-dimensional velocity distribution function for a gas, as the temperature increases:a) it becomes more flattenedb) the maximum occurs for vi = 0 m/sExplain it.

The velocity distribution function of gas moleculesa) is used to measure their velocity, since the small size of gas molecules means that it cannot be measured in any other wayb) is only used to describe the velocity of particles if their density is very high.c) describes the probability that a gas particle has a velocity in a given interval of velocities

Explain why in the representation of a one-dimensional velocity distribution function for a particular gas, the maximum occurs for vi = 0 m/s.

Answer 2

Question

Chapter 14, Problem 77P

Interpretation Introduction

(a)

Interpretation:

Thiols should be identified after reduction of CH3S−SCH2CH2CH3.

Concept Introduction:

Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon.

Reaction of disulfides with reducing agentwill form thiolsand the reaction is known as a reduction reaction.

Interpretation Introduction

(b)

Interpretation:

Thiols should be identified after reduction of CH2=CHCH2S−SCH2CH2CH3.

Concept Introduction:

Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon.

Reaction of disulfides with reducing agent will form thiols and the reaction is known as a reduction reaction.

Expert Solution & Answer

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Answer 3

Question

Chapter 14, Problem 77P

Interpretation Introduction

(a)

Interpretation:

Thiols should be identified after reduction of CH3S−SCH2CH2CH3.

Concept Introduction:

Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon.

Reaction of disulfides with reducing agentwill form thiolsand the reaction is known as a reduction reaction.

Interpretation Introduction

(b)

Interpretation:

Thiols should be identified after reduction of CH2=CHCH2S−SCH2CH2CH3.

Concept Introduction:

Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon.

Reaction of disulfides with reducing agent will form thiols and the reaction is known as a reduction reaction.

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Answer 4

Question

Chapter 14, Problem 77P

Interpretation Introduction

(a)

Interpretation:

Thiols should be identified after reduction of CH3S−SCH2CH2CH3.

Concept Introduction:

Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon.

Reaction of disulfides with reducing agentwill form thiolsand the reaction is known as a reduction reaction.

Interpretation Introduction

(b)

Interpretation:

Thiols should be identified after reduction of CH2=CHCH2S−SCH2CH2CH3.

Concept Introduction:

Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon.

Reaction of disulfides with reducing agent will form thiols and the reaction is known as a reduction reaction.

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Answer 5

Chapter 14, Problem 77P

Interpretation Introduction

(a)

Interpretation:

Thiols should be identified after reduction of CH3S−SCH2CH2CH3.

Concept Introduction:

Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon.

Reaction of disulfides with reducing agentwill form thiolsand the reaction is known as a reduction reaction.

Interpretation Introduction

(b)

Interpretation:

Thiols should be identified after reduction of CH2=CHCH2S−SCH2CH2CH3.

Concept Introduction:

Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon.

Reaction of disulfides with reducing agent will form thiols and the reaction is known as a reduction reaction.

Answer 6

Chapter 14, Problem 77P

Interpretation Introduction

(a)

Interpretation:

Thiols should be identified after reduction of CH3S−SCH2CH2CH3.

Concept Introduction:

Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon.

Reaction of disulfides with reducing agentwill form thiolsand the reaction is known as a reduction reaction.

Answer 7

Chapter 14, Problem 77P

Interpretation Introduction

(a)

Interpretation:

Thiols should be identified after reduction of CH3S−SCH2CH2CH3.

Concept Introduction:

Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon.

Reaction of disulfides with reducing agentwill form thiolsand the reaction is known as a reduction reaction.

Answer 8

Interpretation Introduction

(b)

Interpretation:

Thiols should be identified after reduction of CH2=CHCH2S−SCH2CH2CH3.

Concept Introduction:

Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon.

Reaction of disulfides with reducing agent will form thiols and the reaction is known as a reduction reaction.

Answer 9

Interpretation Introduction

(b)

Interpretation:

Thiols should be identified after reduction of CH2=CHCH2S−SCH2CH2CH3.

Concept Introduction:

Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon.

Reaction of disulfides with reducing agent will form thiols and the reaction is known as a reduction reaction.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 14.1 - Prob. 14.1P Ch. 14.2 - Prob. 14.1PP Ch. 14.2 - Classify each hydroxyl group in sorbitol as 1°,...Ch. 14.2 - Prob. 14.3P Ch. 14.2 - Prob. 14.4P Ch. 14.3 - Prob. 14.2PP Ch. 14.3 - Give the structure corresponding to each name a....Ch. 14.5 - Draw the products formed when each alcohol is...Ch. 14.5 - Prob. 14.6P Ch. 14.5 - Prob. 14.7P

Solution Summary: The author explains that thiols are considered as sulfur analogs of alcohols since S is placed directly below to the oxygen in the periodic table and disulfides undergo reduction reactions.

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Chapter 14 Solutions