EBK CHEMICAL PRINCIPLES
8th Edition
ISBN: 9781305856745
Author: DECOSTE
Publisher: CENGAGE LEARNING - CONSIGNMENT
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Chapter 14, Problem 7DQ
Compare and contrast the
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Antibonding MOs always have at least one node. Can a bonding MO have a node? If so, draw an example.
For the molecule H-He, please complete the following:
Draw the MO energy diagram. Sketch the MOs that result and fill in the electrons.
Determine bond order. Would this molecule be favored over the separated atoms
Chapter 14 Solutions
EBK CHEMICAL PRINCIPLES
Ch. 14 - Prob. 1DQCh. 14 - Prob. 2DQCh. 14 - Prob. 3DQCh. 14 - Prob. 4DQCh. 14 - Prob. 5DQCh. 14 - Prob. 6DQCh. 14 - Compare and contrast the MO model with the LE...Ch. 14 - Prob. 8DQCh. 14 - Prob. 9ECh. 14 - Prob. 10E
Ch. 14 - Prob. 11ECh. 14 - Prob. 12ECh. 14 - Prob. 13ECh. 14 - Use the localized electron model to describe the...Ch. 14 - Prob. 15ECh. 14 - Use the LE model to describe the bonding in H2CO...Ch. 14 - Prob. 17ECh. 14 - The space-filling models of hydrogen cyanide and...Ch. 14 - Prob. 19ECh. 14 - Prob. 20ECh. 14 - Prob. 21ECh. 14 - Indigo is the dye used in coloring blue jeans. The...Ch. 14 - Prob. 23ECh. 14 - Prob. 24ECh. 14 - Why must all six atoms in C2H4 be in the same...Ch. 14 - The allene molecule has the following Lewis...Ch. 14 - Biacetyl and acetoin are added to margarine to...Ch. 14 - Many important compounds in the chemical industry...Ch. 14 - Prob. 29ECh. 14 - Hot and spicy foods contain molecules that...Ch. 14 - Two molecules used in the polymer industry are...Ch. 14 - Prob. 32ECh. 14 - The three most stable oxides of carbon are carbon...Ch. 14 - Prob. 34ECh. 14 - Prob. 35ECh. 14 - What are the relationships among bond order, bond...Ch. 14 - Prob. 37ECh. 14 - A Lewis structure obeying the octet rule can be...Ch. 14 - Prob. 39ECh. 14 - Why does the molecular orbital model do a better...Ch. 14 - Prob. 41ECh. 14 - Prob. 42ECh. 14 - Prob. 43ECh. 14 - In which of the following diatomic molecules would...Ch. 14 - Prob. 45ECh. 14 - Using the molecular orbital model to describe the...Ch. 14 - The transport of O2 in the blood is carried out by...Ch. 14 - Prob. 48ECh. 14 - Prob. 49ECh. 14 - Consider the following electron configuration:...Ch. 14 - Prob. 51ECh. 14 - Using an MO energy-level diagram, would you expect...Ch. 14 - Use Figs.14.45 and 14.46 to answer the following...Ch. 14 - The diatomic molecule OH exists in the gas phase....Ch. 14 - Prob. 55ECh. 14 - Describe the bonding in the O3 molecule and the...Ch. 14 - Prob. 57ECh. 14 - The space-filling model for benzoic acid is shown...Ch. 14 - Prob. 59ECh. 14 - Prob. 60ECh. 14 - The microwave spectrum of 12C16O shows that the...Ch. 14 - Prob. 62ECh. 14 - Prob. 63ECh. 14 - Prob. 64ECh. 14 - Draw the Lewis structures, predict the molecular...Ch. 14 - Prob. 66AECh. 14 - Prob. 67AECh. 14 - Prob. 68AECh. 14 - Prob. 69AECh. 14 - Prob. 70AECh. 14 - Prob. 71AECh. 14 - Prob. 72AECh. 14 - Prob. 73AECh. 14 - Vitamin B6 is an organic compound whose deficiency...Ch. 14 - Prob. 75AECh. 14 - Prob. 76AECh. 14 - Prob. 77AECh. 14 - Prob. 78AECh. 14 - Prob. 79AECh. 14 - Draw the Lewis structures for TeCl4 , ICl5 , PCl5...Ch. 14 - Prob. 81AECh. 14 - Pelargondin is the molecule responsible for the...Ch. 14 - Prob. 83AECh. 14 - Prob. 84AECh. 14 - Prob. 85AECh. 14 - Prob. 86AECh. 14 - Given that the ionization energy of F2 is...Ch. 14 - Bond energy has been defined in the text as the...Ch. 14 - a.A flask containing gaseous N2 is irradiated with...Ch. 14 - Use the MO model to determine which of the...Ch. 14 - Cholesterol (C27H46O) has the following structure:...Ch. 14 - Arrange the following from lowest to highest...Ch. 14 - Carbon monoxide (CO) forms bonds to a variety of...Ch. 14 - Prob. 94CPCh. 14 - In Exercise71 in Chapter13 , the Lewis structures...Ch. 14 - Prob. 96CPCh. 14 - Prob. 97CPCh. 14 - Prob. 98MP
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- When is it desirable to use MO theory rather than valence bond theory?arrow_forwardThe MO energy diagram for BO is shown below. Redraw the diagram in your answer sheet a. Fully label the diagram b. Indicate which orbitals are B and which are O C. Fill in the electrons for B0 on your MO diagram d. Determine the bond order for BO, BO* and BO? e. Comment on the bond orders and the magnetic properties of the two ions.arrow_forward1. Sketch the MO diagram of the following species and fill the molecular orbitals with electrons. You can sketch the MO diagrams with a paper and a pencil and then take a picture of your sketches. Paste together all the pictures to the same word document. You will upload the word document to Canvas when you take the online quiz. Liz Nez N* (Note, N* is cation with one less electron than N2, but has the same MO structure as N2.) B (Note, B is cation with one less electron than B2, but has the same MO structure as B2.)arrow_forward
- Study the following sketch of a molecular orbital (MO) in a homonuclear diatomic molecule. This MO was formed by combining one 3s atomic orbital from each atom. The dark dots in this sketch are the nuclei. Now use the sketch to complete the table below. Write the symbol for this MO. JT Is this a bonding or antibonding MO? bonding antibonding higher ? What is the energy of this MO, compared to the energy of a 3s orbital on one of the separate atoms? lower the same not enough information to decide Subm Tems 2019 McGraw Hil Education Al Rights Reserved Continue MacBook Pro DII F8 F9 F7 O OOarrow_forwardHow MO bond order predicts the stability of molecular speciesarrow_forwardStudy the following sketch of a molecular orbital (MO) in a homonuclear diatomic molecule. This MO was formed by combining one 3p atomic orbital from each atom. The dark dots in this sketch are the nuclei. Now use the sketch to complete the table below. Write the symbol for this MO. Is this a bonding or antibonding MO? What is the energy of this MO, compared to the energy of a 3p orbital on one of the separate. atoms? 0 O bonding O antibonding O higher O lower O the same not enough information to decide O 2 00 X 2 뮤 0 Śarrow_forward
- Use the MO model to explain the bonding in BeH2. When constructing the MO energy-level diagram, assume that the Be 1s electrons are not involved in bond formation. Please provide me a full details answer. Thank Youarrow_forwardStudy the following sketch of a molecular orbital (MO) in a homonuclear diatomic molecule. This MO was formed by combining one 2p atomic orbital from atom. The dark dots in this sketch are the nuclei. Now use the sketch to complete the table below. Write the symbol for this MO. Is this a bonding or antibonding MO? What is the energy of this MO, compared to the energy of a 2p orbital on one of the separate 0 Obonding antibonding O higher Olower the same not enough information to decide D 8 70 % 9arrow_forwardTwo p orbitals from one atom and two p orbitals from another atom are combined to form molecular orbitals for the joined atoms. How many MOs will result from this combination? Explain.arrow_forward
- a MO energy diagram with two electrons in sigma 2s two electrons in sigma 2s* and four electrons in pi 2p orbitals matches which homonuclear diatomic molecule? C2 F2 B2 O2 Ne2 or N2arrow_forwardStudy the following sketch of a molecular orbital (MO) in a homonuclear diatomic molecule. This MO was formed by combining one 3s atomic orbital from each atom. The dark dots in this sketch are the nuclei. Now use the sketch to complete the table below. Write the symbol for this MO. Is this a bonding or antibonding MO? bonding What is the energy of this MO, compared to the energy of a 3s orbital on one of the separate atoms? antibonding higher lower the same not enough information to decide σ Π х Garrow_forwardPart 4: Drawing Molecular Orbital (MO) Energy Diagrams These species will be explored: OF 16. Draw MO energy diagrams (including the A0 portions for individual atoms or ions), using the correct energy order of MOs for each species.arrow_forward
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