EBK CHEMICAL PRINCIPLES
8th Edition
ISBN: 9781305856745
Author: DECOSTE
Publisher: CENGAGE LEARNING - CONSIGNMENT
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Textbook Question
Chapter 14, Problem 44E
In which of the following diatomic molecules would the bond strength be expected to weaken as an electron is removed?
a.
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In one electrode: Pt, H2(1 atm) | H+(a=1), the interchange current density at 298K is 0.79 mA·cm-2. If the voltage difference of the interface is +5 mV. What will be the correct intensity at pH = 2?. Maximum transfer voltage and beta = 0.5.
In a Pt electrode, H2(1 atm) | H+(a=1), the interchange current density of an electrode is 0.79 mA cm-2. ¿Qué corriente flow across the electrode of área 5 cm2 when the difference in potential of the interface is +5 mV?.
If the current voltage is n = 0.14 V, indicate which of the 2 voltage
formulas of the ley of Tafel must be applied
i
a
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xp[(1 - ß³):
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Fn
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b) == exp B
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Chapter 14 Solutions
EBK CHEMICAL PRINCIPLES
Ch. 14 - Prob. 1DQCh. 14 - Prob. 2DQCh. 14 - Prob. 3DQCh. 14 - Prob. 4DQCh. 14 - Prob. 5DQCh. 14 - Prob. 6DQCh. 14 - Compare and contrast the MO model with the LE...Ch. 14 - Prob. 8DQCh. 14 - Prob. 9ECh. 14 - Prob. 10E
Ch. 14 - Prob. 11ECh. 14 - Prob. 12ECh. 14 - Prob. 13ECh. 14 - Use the localized electron model to describe the...Ch. 14 - Prob. 15ECh. 14 - Use the LE model to describe the bonding in H2CO...Ch. 14 - Prob. 17ECh. 14 - The space-filling models of hydrogen cyanide and...Ch. 14 - Prob. 19ECh. 14 - Prob. 20ECh. 14 - Prob. 21ECh. 14 - Indigo is the dye used in coloring blue jeans. The...Ch. 14 - Prob. 23ECh. 14 - Prob. 24ECh. 14 - Why must all six atoms in C2H4 be in the same...Ch. 14 - The allene molecule has the following Lewis...Ch. 14 - Biacetyl and acetoin are added to margarine to...Ch. 14 - Many important compounds in the chemical industry...Ch. 14 - Prob. 29ECh. 14 - Hot and spicy foods contain molecules that...Ch. 14 - Two molecules used in the polymer industry are...Ch. 14 - Prob. 32ECh. 14 - The three most stable oxides of carbon are carbon...Ch. 14 - Prob. 34ECh. 14 - Prob. 35ECh. 14 - What are the relationships among bond order, bond...Ch. 14 - Prob. 37ECh. 14 - A Lewis structure obeying the octet rule can be...Ch. 14 - Prob. 39ECh. 14 - Why does the molecular orbital model do a better...Ch. 14 - Prob. 41ECh. 14 - Prob. 42ECh. 14 - Prob. 43ECh. 14 - In which of the following diatomic molecules would...Ch. 14 - Prob. 45ECh. 14 - Using the molecular orbital model to describe the...Ch. 14 - The transport of O2 in the blood is carried out by...Ch. 14 - Prob. 48ECh. 14 - Prob. 49ECh. 14 - Consider the following electron configuration:...Ch. 14 - Prob. 51ECh. 14 - Using an MO energy-level diagram, would you expect...Ch. 14 - Use Figs.14.45 and 14.46 to answer the following...Ch. 14 - The diatomic molecule OH exists in the gas phase....Ch. 14 - Prob. 55ECh. 14 - Describe the bonding in the O3 molecule and the...Ch. 14 - Prob. 57ECh. 14 - The space-filling model for benzoic acid is shown...Ch. 14 - Prob. 59ECh. 14 - Prob. 60ECh. 14 - The microwave spectrum of 12C16O shows that the...Ch. 14 - Prob. 62ECh. 14 - Prob. 63ECh. 14 - Prob. 64ECh. 14 - Draw the Lewis structures, predict the molecular...Ch. 14 - Prob. 66AECh. 14 - Prob. 67AECh. 14 - Prob. 68AECh. 14 - Prob. 69AECh. 14 - Prob. 70AECh. 14 - Prob. 71AECh. 14 - Prob. 72AECh. 14 - Prob. 73AECh. 14 - Vitamin B6 is an organic compound whose deficiency...Ch. 14 - Prob. 75AECh. 14 - Prob. 76AECh. 14 - Prob. 77AECh. 14 - Prob. 78AECh. 14 - Prob. 79AECh. 14 - Draw the Lewis structures for TeCl4 , ICl5 , PCl5...Ch. 14 - Prob. 81AECh. 14 - Pelargondin is the molecule responsible for the...Ch. 14 - Prob. 83AECh. 14 - Prob. 84AECh. 14 - Prob. 85AECh. 14 - Prob. 86AECh. 14 - Given that the ionization energy of F2 is...Ch. 14 - Bond energy has been defined in the text as the...Ch. 14 - a.A flask containing gaseous N2 is irradiated with...Ch. 14 - Use the MO model to determine which of the...Ch. 14 - Cholesterol (C27H46O) has the following structure:...Ch. 14 - Arrange the following from lowest to highest...Ch. 14 - Carbon monoxide (CO) forms bonds to a variety of...Ch. 14 - Prob. 94CPCh. 14 - In Exercise71 in Chapter13 , the Lewis structures...Ch. 14 - Prob. 96CPCh. 14 - Prob. 97CPCh. 14 - Prob. 98MP
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- If the current voltage is n = 0.14 V. Indicate which of the 2 formulas must be applied a) = a T = i exp[(1 - p) F Fn Fn b) i==exp B RTarrow_forwardTopic: Photochemistry and Photophysics of Supramoleculesarrow_forwardTwo cations that exchange an electron in an interface, the exchange density is worth 1.39 mA/cm2 and the current density is worth 15 mA/cm2 at 25°C. If the overvoltage is 0.14 V, calculate the reaction rate and symmetry factor. Data: R = 8,314 J mol-1 k-1: F = 96500 Carrow_forward
- With the help of the Tafel line, it is estimated that the interchange density of the VO2+/VO2+ system on the carbon paper has a value of 3 mA cm-2. Calculate a) the current density if the voltage has a value of 1.6 mV and the temperature is 25°C. b) the beta value of the anódico process if the Tafel pendulum is 0.6 V at 25°C. Data: R = 8.314 JK-1mol-1, y F = 96485 C mol-1.arrow_forwardApply the NANSTE law to the MnO4- + 8H+ + 5e- ⇄ Mn2+ + 4H2Oarrow_forwardIn the Nernst Law, how much is RT / F?arrow_forward
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