Introductory Chemistry: Foundation - Text (Looseleaf)
9th Edition
ISBN: 9781337399623
Author: ZUMDAHL
Publisher: Cengage
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Chapter 14, Problem 61AP
Given the densities and conditions of ice, liquid water, and steam listed in Table 14.1, calculate the volume of
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(11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the
molecule depicted below.
Bond B
Bond A
Bond C
a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in
appropriate boxes.
Weakest
Bond
Strongest
Bond
b. (4pts) Consider the relative stability of all cleavage products that form when bonds A,
B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B,
and C are all carbon radicals.
i. Which ONE cleavage product is the most stable? A condensed or bond line
representation is fine.
ii. Which ONE cleavage product is the least stable? A condensed or bond line
representation is fine.
c. (5pts) Use principles discussed in lecture, supported by relevant structures, to
succinctly explain the why your part b (i) radical is more stable than your part b(ii)
radical. Written explanation can be no more than one-two succinct sentence(s)!
.
3°C
with
TH
12. (10pts total) Provide the major product for each reaction depicted below. If no reaction
occurs write NR. Assume heat dissipation is carefully controlled in the fluorine reaction.
3H
24 total (30)
24
21
2h
• 6H total
● 8H total
34
래
Br2
hv
major product
will be most
Substituted
12
hv
Br
NR
I too weak of a
participate in P-1
F₂
hv
Statistically
most favored
product will be
major
=
most subst =
thermo favored
hydrogen atom abstractor to
LL
F
Five chemistry project topic that does not involve practical
Chapter 14 Solutions
Introductory Chemistry: Foundation - Text (Looseleaf)
Ch. 14.2 - trong>Exercise 14.1 Calculate the total energy...Ch. 14.3 - Prob. 1CTCh. 14.6 - trong>Exercise 14.2 Name the type of crystalline...Ch. 14 - ou seal a container half-filled with water. Which...Ch. 14 - xplain the following: You add 100mLof water to a...Ch. 14 - Prob. 3ALQCh. 14 - Prob. 4ALQCh. 14 - Prob. 5ALQCh. 14 - Prob. 6ALQCh. 14 - Prob. 7ALQ
Ch. 14 - ow do the following physical properties depend on...Ch. 14 - ook at Fig. 14.2. Why doesn't temperature increase...Ch. 14 - Prob. 10ALQCh. 14 - Prob. 11ALQCh. 14 - Prob. 12ALQCh. 14 - Prob. 13ALQCh. 14 - Prob. 14ALQCh. 14 - Prob. 15ALQCh. 14 - True or false? Methane (CH4) is more likely In...Ch. 14 - Prob. 17ALQCh. 14 - Prob. 18ALQCh. 14 - Prob. 19ALQCh. 14 - Which would you predict should be larger for a...Ch. 14 - Prob. 21ALQCh. 14 - Prob. 22ALQCh. 14 - Prob. 23ALQCh. 14 - ases have (higher/lower) densities than liquids or...Ch. 14 - Prob. 2QAPCh. 14 - Prob. 3QAPCh. 14 - he enthalpy (H)of vaporization of water is about...Ch. 14 - Prob. 5QAPCh. 14 - Prob. 6QAPCh. 14 - Prob. 7QAPCh. 14 - Prob. 8QAPCh. 14 - Prob. 9QAPCh. 14 - Prob. 10QAPCh. 14 - Prob. 11QAPCh. 14 - The energy required to melt 1 mole of a solid is...Ch. 14 - The following data have ban collected for...Ch. 14 - The molar heat of fusion of aluminum metal is...Ch. 14 - Prob. 15QAPCh. 14 - Prob. 16QAPCh. 14 - The molar heats of fusion and vaporization for...Ch. 14 - It requires 113Jto melt 1.00gof sodium metal at...Ch. 14 - Consider the iodine monochloride molecule, ICI....Ch. 14 - Prob. 20QAPCh. 14 - Prob. 21QAPCh. 14 - Prob. 22QAPCh. 14 - Prob. 23QAPCh. 14 - Prob. 24QAPCh. 14 - What type of intermolecular forces is active in...Ch. 14 - Prob. 26QAPCh. 14 - Prob. 27QAPCh. 14 - The heats of fusion of three substances are listed...Ch. 14 - When dry ammonia gas (NH3)is bubbled into a...Ch. 14 - Prob. 30QAPCh. 14 - Prob. 31QAPCh. 14 - If you've ever opened a bottle of rubbing alcohol...Ch. 14 - Prob. 33QAPCh. 14 - Prob. 34QAPCh. 14 - Which substance in each pair would be expected to...Ch. 14 - Which substance in each pair would be expected to...Ch. 14 - Prob. 37QAPCh. 14 - Two molecules that contain the same number of each...Ch. 14 - Prob. 39QAPCh. 14 - Prob. 40QAPCh. 14 - How do ionic solids differ in structure from...Ch. 14 - A common prank on college campuses is to switch...Ch. 14 - Prob. 43QAPCh. 14 - What types of forces exist between the individual...Ch. 14 - Prob. 45QAPCh. 14 - Prob. 46QAPCh. 14 - Prob. 47QAPCh. 14 - Prob. 48QAPCh. 14 - Prob. 49QAPCh. 14 - Prob. 50QAPCh. 14 - Prob. 51APCh. 14 - Prob. 52APCh. 14 - Prob. 53APCh. 14 - Prob. 54APCh. 14 - Prob. 55APCh. 14 - Prob. 56APCh. 14 - Prob. 57APCh. 14 - Prob. 58APCh. 14 - Prob. 59APCh. 14 - Prob. 60APCh. 14 - Given the densities and conditions of ice, liquid...Ch. 14 - Prob. 62APCh. 14 - Which of the substances in each of the following...Ch. 14 - Prob. 64APCh. 14 - Prob. 65APCh. 14 - Prob. 66APCh. 14 - Prob. 67APCh. 14 - Prob. 68APCh. 14 - Describe, on both a microscopic and a macroscopic...Ch. 14 - Cake mixes and other packaged foods that require...Ch. 14 - Prob. 71APCh. 14 - Prob. 72APCh. 14 - The molar heat of vaporization of carbon...Ch. 14 - Prob. 74APCh. 14 - Prob. 75APCh. 14 - Prob. 76APCh. 14 - Prob. 77APCh. 14 - Prob. 78APCh. 14 - Prob. 79APCh. 14 - Prob. 80APCh. 14 - Prob. 81APCh. 14 - Prob. 82APCh. 14 - Prob. 83APCh. 14 - Prob. 84APCh. 14 - Describe in detail the microscopic processes that...Ch. 14 - Prob. 86APCh. 14 - Formaldehyde has the formula CH2O, where C is the...Ch. 14 - Prob. 88APCh. 14 - Prob. 89APCh. 14 - Describe, on a microscopic basis, the processes of...Ch. 14 - Prob. 91APCh. 14 - Prob. 92APCh. 14 - Which of the following compound(s) exhibit only...Ch. 14 - Which of the following statements about...Ch. 14 - Prob. 95CPCh. 14 - Prob. 96CPCh. 14 - Prob. 97CPCh. 14 - Which of the following statements is(are) true?...
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- Please correct answer and don't used hand raitingarrow_forwardQ2. Consider the hydrogenation of ethylene C2H4 + H2 = C2H6 The heats of combustion and molar entropies for the three gases at 298 K are given by: C2H4 C2H6 H2 AH comb/kJ mol¹ -1395 -1550 -243 Sº / J K¹ mol-1 220.7 230.4 131.1 The average heat capacity change, ACP, for the reaction over the temperature range 298-1000 K is 10.9 J K¹ mol¹. Using these data, determine: (a) the standard enthalpy change at 800 K (b) the standard entropy change at 800 K (c) the equilibrium constant at 800 K.arrow_forward13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the molecule depicted below. Bond B Bond A Bond C a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in appropriate boxes. Weakest Bond Strongest Bond b. (4pts) Consider the relative stability of all cleavage products that form when bonds A, B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B, and C are all carbon radicals. i. Which ONE cleavage product is the most stable? A condensed or bond line representation is fine. ii. Which ONE cleavage product is the least stable? A condensed or bond line representation is fine. c. (5pts) Use principles discussed in lecture, supported by relevant structures, to succinctly explain the why your part b (i) radical is more stable than your part b(ii) radical. Written explanation can be no more than one-two succinct sentence(s)! Googlearrow_forward
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