Whether the forces which connect two hydrogen atoms to an oxygen atom in a water molecule are intramolecular or intermolecular should be explained and whether the forces which hold water molecules close together in an ice cube are intermolecular or intramolecular should be explained. Concept Introduction: Intermolecular forces are stronger. The forces which are present between two molecules is known as intermolecular forces whereas forces that are present within the molecule is known as intramolecular forces.

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B 1 of 2 Additional problems in preparation to Midterm #1: 1.) How can the following compounds be prepared using Diels-Alder reaction: CH3 O CN (a) (b) CN CH3 2.) What is the missing reagent in the shown reaction? H3C + ? H3C H3C CN H3C ''CN (၁) H 3.) Write the products 1,2-addition and 1,4-addition of DBr to 1,3-cyclohexadiene. Remember, D is deuterium, a heavy isotope of hydrogen. It reacts exactly like hydrogen. 4.) In the shown reaction, which will be the kinetic product and which will be the thermodynamic product? H3C CI H3C HCI H3C + 5.) Which of the following molecules is aromatic? (a) (b) (c) H 6.) Which of the following molecules is aromatic? (a) (b) (c) 7.) Write the mechanism for the shown reaction. + Ха AICI 3 CI 8.) Suggest reagents that would convert benzene into the shown compounds. CI NO2 -8-6-6-8-a (a) (b) (c) (d) (e) (a) SO3H Br

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Chapter 14, Problem 10QAP

Interpretation Introduction

Interpretation:

Whether the forces which connect two hydrogen atoms to an oxygen atom in a water molecule are intramolecular or intermolecular should be explained and whether the forces which hold water molecules close together in an ice cube are intermolecular or intramolecular should be explained.

Concept Introduction:

Intermolecular forces are stronger. The forces which are present between two molecules is known as intermolecular forces whereas forces that are present within the molecule is known as intramolecular forces.

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