(a) Interpretation: The structures of the four given molecules must be drawn indicating whether those are polar or non polar. Concept Introduction: Lewis structure is the representation of molecules showing the electron dots present in each atom. A polar molecule has non zero bond moments whereas a non polar molecule has zero bond moments.

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Answer 1

Question

Chapter 14, Problem 80AP

Interpretation Introduction

(a)

Interpretation:

The structures of the four given molecules must be drawn indicating whether those are polar or non polar.

Concept Introduction:

Lewis structure is the representation of molecules showing the electron dots present in each atom.

A polar molecule has non zero bond moments whereas a non polar molecule has zero bond moments.

Interpretation Introduction

(b)

Interpretation:

Which two molecules are liquid and which two are gases as room temperature must be predicted along with proper explanation.

Concept Introduction:

For liquids intermolecular forces are stronger as compared to gases.

Interpretation Introduction

(c)

Interpretation:

The given compounds must be ranked from lowest to highest boiling point with proper justification.

Concept Introduction:

Molecules having stronger intermolecular forces show higher boiling points.

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. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the molecule depicted below. Bond B 2°C. +2°C. < cleavage Bond A • CH3 + 26. t cleavage 2°C• +3°C• Bond C Cleavage CH3 ZC '2°C. 26. E Strongest 3°C. 2C. Gund Largest BDE weakest bond In that molecule a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in appropriate boxes. Weakest C bond Produces A Weakest Bond Most Strongest Bond Stable radical Strongest Gund produces least stable radicals b. (4pts) Consider the relative stability of all cleavage products that form when bonds A, B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B, and C are all carbon radicals. i. Which ONE cleavage product is the most stable? A condensed or bond line representation is fine. 人 8°C. formed in bound C cleavage ii. Which ONE cleavage product is the least stable? A condensed or bond line representation is fine. methyl radical •CH3 formed in bund A Cleavage

Which carbocation is more stable?

Are the products of the given reaction correct? Why or why not?

Answer 2

Question

Chapter 14, Problem 80AP

Interpretation Introduction

(a)

Interpretation:

The structures of the four given molecules must be drawn indicating whether those are polar or non polar.

Concept Introduction:

Lewis structure is the representation of molecules showing the electron dots present in each atom.

A polar molecule has non zero bond moments whereas a non polar molecule has zero bond moments.

Interpretation Introduction

(b)

Interpretation:

Which two molecules are liquid and which two are gases as room temperature must be predicted along with proper explanation.

Concept Introduction:

For liquids intermolecular forces are stronger as compared to gases.

Interpretation Introduction

(c)

Interpretation:

The given compounds must be ranked from lowest to highest boiling point with proper justification.

Concept Introduction:

Molecules having stronger intermolecular forces show higher boiling points.

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Answer 3

Question

Chapter 14, Problem 80AP

Interpretation Introduction

(a)

Interpretation:

The structures of the four given molecules must be drawn indicating whether those are polar or non polar.

Concept Introduction:

Lewis structure is the representation of molecules showing the electron dots present in each atom.

A polar molecule has non zero bond moments whereas a non polar molecule has zero bond moments.

Interpretation Introduction

(b)

Interpretation:

Which two molecules are liquid and which two are gases as room temperature must be predicted along with proper explanation.

Concept Introduction:

For liquids intermolecular forces are stronger as compared to gases.

Interpretation Introduction

(c)

Interpretation:

The given compounds must be ranked from lowest to highest boiling point with proper justification.

Concept Introduction:

Molecules having stronger intermolecular forces show higher boiling points.

Expert Solution & Answer

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Answer 4

Question

Chapter 14, Problem 80AP

Interpretation Introduction

(a)

Interpretation:

The structures of the four given molecules must be drawn indicating whether those are polar or non polar.

Concept Introduction:

Lewis structure is the representation of molecules showing the electron dots present in each atom.

A polar molecule has non zero bond moments whereas a non polar molecule has zero bond moments.

Interpretation Introduction

(b)

Interpretation:

Which two molecules are liquid and which two are gases as room temperature must be predicted along with proper explanation.

Concept Introduction:

For liquids intermolecular forces are stronger as compared to gases.

Interpretation Introduction

(c)

Interpretation:

The given compounds must be ranked from lowest to highest boiling point with proper justification.

Concept Introduction:

Molecules having stronger intermolecular forces show higher boiling points.

Expert Solution & Answer

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Answer 5

Chapter 14, Problem 80AP

Interpretation Introduction

(a)

Interpretation:

The structures of the four given molecules must be drawn indicating whether those are polar or non polar.

Concept Introduction:

Lewis structure is the representation of molecules showing the electron dots present in each atom.

A polar molecule has non zero bond moments whereas a non polar molecule has zero bond moments.

Interpretation Introduction

(b)

Interpretation:

Which two molecules are liquid and which two are gases as room temperature must be predicted along with proper explanation.

Concept Introduction:

For liquids intermolecular forces are stronger as compared to gases.

Interpretation Introduction

(c)

Interpretation:

The given compounds must be ranked from lowest to highest boiling point with proper justification.

Concept Introduction:

Molecules having stronger intermolecular forces show higher boiling points.

Answer 6

Chapter 14, Problem 80AP

Interpretation Introduction

(a)

Interpretation:

The structures of the four given molecules must be drawn indicating whether those are polar or non polar.

Concept Introduction:

Lewis structure is the representation of molecules showing the electron dots present in each atom.

A polar molecule has non zero bond moments whereas a non polar molecule has zero bond moments.

Answer 7

Chapter 14, Problem 80AP

Interpretation Introduction

(a)

Interpretation:

The structures of the four given molecules must be drawn indicating whether those are polar or non polar.

Concept Introduction:

Lewis structure is the representation of molecules showing the electron dots present in each atom.

A polar molecule has non zero bond moments whereas a non polar molecule has zero bond moments.

Answer 8

Interpretation Introduction

(b)

Interpretation:

Which two molecules are liquid and which two are gases as room temperature must be predicted along with proper explanation.

Concept Introduction:

For liquids intermolecular forces are stronger as compared to gases.

Answer 9

Interpretation Introduction

(b)

Interpretation:

Which two molecules are liquid and which two are gases as room temperature must be predicted along with proper explanation.

Concept Introduction:

For liquids intermolecular forces are stronger as compared to gases.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The given compounds must be ranked from lowest to highest boiling point with proper justification.

Concept Introduction:

Molecules having stronger intermolecular forces show higher boiling points.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The given compounds must be ranked from lowest to highest boiling point with proper justification.

Concept Introduction:

Molecules having stronger intermolecular forces show higher boiling points.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 14.2 - trong>Exercise 14.1 Calculate the total energy...Ch. 14.3 - Prob. 1CT Ch. 14.6 - trong>Exercise 14.2 Name the type of crystalline...Ch. 14 - ou seal a container half-filled with water. Which...Ch. 14 - xplain the following: You add 100mLof water to a...Ch. 14 - Prob. 3ALQ Ch. 14 - Prob. 4ALQ Ch. 14 - Prob. 5ALQ Ch. 14 - Prob. 6ALQ Ch. 14 - Prob. 7ALQ

(b) Interpretation: Which two molecules are liquid and which two are gases as room temperature must be predicted along with proper explanation. Concept Introduction: For liquids intermolecular forces are stronger as compared to gases.

(c) Interpretation: The given compounds must be ranked from lowest to highest boiling point with proper justification. Concept Introduction: Molecules having stronger intermolecular forces show higher boiling points.

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Chapter 14 Solutions

(b)

Interpretation:

Which two molecules are liquid and which two are gases as room temperature must be predicted along with proper explanation.

Concept Introduction:

For liquids intermolecular forces are stronger as compared to gases.

(c)

Interpretation:

The given compounds must be ranked from lowest to highest boiling point with proper justification.

Concept Introduction:

Molecules having stronger intermolecular forces show higher boiling points.