(a) Interpretation: The type of intermolecular forces present in liquid state of xenon molecule must be explained. Concept Introduction: Various intermolecular forces are dipole-dipole interaction, ion-dipole interaction, induced dipole −induced dipole interaction. Dipole-dipole interaction is present in molecules with permanent dipole moment. Positive pole of one dipole interacts with negative pole of another dipole. In ion dipole interaction one dipole interact with another ion. Out of the two different poles one with opposite charge with respect to the ion interacts. In non polar molecule induced dipole-induced dipole interaction is present. In this case one dipole is created which induces dipole in nearby non polar molecules.

Question

B 1 of 2 Additional problems in preparation to Midterm #1: 1.) How can the following compounds be prepared using Diels-Alder reaction: CH3 O CN (a) (b) CN CH3 2.) What is the missing reagent in the shown reaction? H3C + ? H3C H3C CN H3C ''CN (၁) H 3.) Write the products 1,2-addition and 1,4-addition of DBr to 1,3-cyclohexadiene. Remember, D is deuterium, a heavy isotope of hydrogen. It reacts exactly like hydrogen. 4.) In the shown reaction, which will be the kinetic product and which will be the thermodynamic product? H3C CI H3C HCI H3C + 5.) Which of the following molecules is aromatic? (a) (b) (c) H 6.) Which of the following molecules is aromatic? (a) (b) (c) 7.) Write the mechanism for the shown reaction. + Ха AICI 3 CI 8.) Suggest reagents that would convert benzene into the shown compounds. CI NO2 -8-6-6-8-a (a) (b) (c) (d) (e) (a) SO3H Br

Answer 1

Question

Chapter 14, Problem 26QAP

Interpretation Introduction

(a)

Interpretation:

The type of intermolecular forces present in liquid state of xenon molecule must be explained.

Concept Introduction:

Various intermolecular forces are dipole-dipole interaction, ion-dipole interaction, induced dipole −induced dipole interaction.

Dipole-dipole interaction is present in molecules with permanent dipole moment. Positive pole of one dipole interacts with negative pole of another dipole.

In ion dipole interaction one dipole interact with another ion. Out of the two different poles one with opposite charge with respect to the ion interacts.

In non polar molecule induced dipole-induced dipole interaction is present. In this case one dipole is created which induces dipole in nearby non polar molecules.

Interpretation Introduction

(b)

Interpretation:

The type of intermolecular forces present in liquid state of ammonia molecule must be explained.

Concept Introduction:

Various intermolecular forces are dipole-dipole interaction, ion-dipole interaction, induced dipole −induced dipole interaction.

Dipole-dipole interaction is present in molecules with permanent dipole moment. Positive pole of one dipole interacts with negative pole of another dipole.

In ion dipole interaction one dipole interact with another ion. Out of the two different poles one with opposite charge with respect to the ion interacts.

In non-polar molecule induced dipole-induced dipole interaction is present. In this case one dipole is created which induces dipole in nearby non-polar molecules.

Interpretation Introduction

(c)

Interpretation:

The type of intermolecular forces are present in liquid state of fluorine molecule must be explained.

Concept Introduction:

Various intermolecular forces are dipole-dipole interaction, ion-dipole interaction, induced dipole −induced dipole interaction.

Dipole-dipole interaction is present in molecules with permanent dipole moment. Positive pole of one dipole interacts with negative pole of another dipole.

In ion dipole interaction one dipole interact with another ion. Out of the two different poles one with opposite charge with respect to the ion interacts.

In non-polar molecule induced dipole-induced dipole interaction is present. In this case one dipole is created which induces dipole in nearby non-polar molecules.

(d)

Interpretation Introduction

Interpretation:

The type of intermolecular forces are present in liquid state of Iodine monochloride molecule must be explained.

Concept Introduction:

Various intermolecular forces are dipole-dipole interaction, ion-dipole interaction, induced dipole −induced dipole interaction.

Dipole-dipole interaction is present in molecules with permanent dipole moment. Positive pole of one dipole interacts with negative pole of another dipole.

In ion dipole interaction one dipole interact with another ion. Out of the two different poles one with opposite charge with respect to the ion interacts.

In non-polar molecule induced dipole-induced dipole interaction is present. In this case one dipole is created which induces dipole in nearby non-polar molecules.

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B 1 of 2 Additional problems in preparation to Midterm #1: 1.) How can the following compounds be prepared using Diels-Alder reaction: CH3 O CN (a) (b) CN CH3 2.) What is the missing reagent in the shown reaction? H3C + ? H3C H3C CN H3C ''CN (၁) H 3.) Write the products 1,2-addition and 1,4-addition of DBr to 1,3-cyclohexadiene. Remember, D is deuterium, a heavy isotope of hydrogen. It reacts exactly like hydrogen. 4.) In the shown reaction, which will be the kinetic product and which will be the thermodynamic product? H3C CI H3C HCI H3C + 5.) Which of the following molecules is aromatic? (a) (b) (c) H 6.) Which of the following molecules is aromatic? (a) (b) (c) 7.) Write the mechanism for the shown reaction. + Ха AICI 3 CI 8.) Suggest reagents that would convert benzene into the shown compounds. CI NO2 -8-6-6-8-a (a) (b) (c) (d) (e) (a) SO3H Br

The number of 2sp^2 hybridized atoms in is: A. 8; B. 6; C.4; D.2; E.0;

The highest boiling compound from among the following isA. 2-methylheptane; B. 3-methylheptane; C. 2,2-dimethylhexane;D. octane; E. 2,2,3-trimethylpentane

Answer 2

Question

Chapter 14, Problem 26QAP

Interpretation Introduction

(a)

Interpretation:

The type of intermolecular forces present in liquid state of xenon molecule must be explained.

Concept Introduction:

Various intermolecular forces are dipole-dipole interaction, ion-dipole interaction, induced dipole −induced dipole interaction.

Dipole-dipole interaction is present in molecules with permanent dipole moment. Positive pole of one dipole interacts with negative pole of another dipole.

In ion dipole interaction one dipole interact with another ion. Out of the two different poles one with opposite charge with respect to the ion interacts.

In non polar molecule induced dipole-induced dipole interaction is present. In this case one dipole is created which induces dipole in nearby non polar molecules.

Interpretation Introduction

(b)

Interpretation:

The type of intermolecular forces present in liquid state of ammonia molecule must be explained.

Concept Introduction:

Various intermolecular forces are dipole-dipole interaction, ion-dipole interaction, induced dipole −induced dipole interaction.

Dipole-dipole interaction is present in molecules with permanent dipole moment. Positive pole of one dipole interacts with negative pole of another dipole.

In ion dipole interaction one dipole interact with another ion. Out of the two different poles one with opposite charge with respect to the ion interacts.

In non-polar molecule induced dipole-induced dipole interaction is present. In this case one dipole is created which induces dipole in nearby non-polar molecules.

Interpretation Introduction

(c)

Interpretation:

The type of intermolecular forces are present in liquid state of fluorine molecule must be explained.

Concept Introduction:

Various intermolecular forces are dipole-dipole interaction, ion-dipole interaction, induced dipole −induced dipole interaction.

Dipole-dipole interaction is present in molecules with permanent dipole moment. Positive pole of one dipole interacts with negative pole of another dipole.

In ion dipole interaction one dipole interact with another ion. Out of the two different poles one with opposite charge with respect to the ion interacts.

In non-polar molecule induced dipole-induced dipole interaction is present. In this case one dipole is created which induces dipole in nearby non-polar molecules.

(d)

Interpretation Introduction

Interpretation:

The type of intermolecular forces are present in liquid state of Iodine monochloride molecule must be explained.

Concept Introduction:

Various intermolecular forces are dipole-dipole interaction, ion-dipole interaction, induced dipole −induced dipole interaction.

Dipole-dipole interaction is present in molecules with permanent dipole moment. Positive pole of one dipole interacts with negative pole of another dipole.

In ion dipole interaction one dipole interact with another ion. Out of the two different poles one with opposite charge with respect to the ion interacts.

In non-polar molecule induced dipole-induced dipole interaction is present. In this case one dipole is created which induces dipole in nearby non-polar molecules.

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Answer 3

Question

Chapter 14, Problem 26QAP

Interpretation Introduction

(a)

Interpretation:

The type of intermolecular forces present in liquid state of xenon molecule must be explained.

Concept Introduction:

Various intermolecular forces are dipole-dipole interaction, ion-dipole interaction, induced dipole −induced dipole interaction.

Dipole-dipole interaction is present in molecules with permanent dipole moment. Positive pole of one dipole interacts with negative pole of another dipole.

In ion dipole interaction one dipole interact with another ion. Out of the two different poles one with opposite charge with respect to the ion interacts.

In non polar molecule induced dipole-induced dipole interaction is present. In this case one dipole is created which induces dipole in nearby non polar molecules.

Interpretation Introduction

(b)

Interpretation:

The type of intermolecular forces present in liquid state of ammonia molecule must be explained.

Concept Introduction:

Various intermolecular forces are dipole-dipole interaction, ion-dipole interaction, induced dipole −induced dipole interaction.

Dipole-dipole interaction is present in molecules with permanent dipole moment. Positive pole of one dipole interacts with negative pole of another dipole.

In ion dipole interaction one dipole interact with another ion. Out of the two different poles one with opposite charge with respect to the ion interacts.

In non-polar molecule induced dipole-induced dipole interaction is present. In this case one dipole is created which induces dipole in nearby non-polar molecules.

Interpretation Introduction

(c)

Interpretation:

The type of intermolecular forces are present in liquid state of fluorine molecule must be explained.

Concept Introduction:

Various intermolecular forces are dipole-dipole interaction, ion-dipole interaction, induced dipole −induced dipole interaction.

Dipole-dipole interaction is present in molecules with permanent dipole moment. Positive pole of one dipole interacts with negative pole of another dipole.

In ion dipole interaction one dipole interact with another ion. Out of the two different poles one with opposite charge with respect to the ion interacts.

In non-polar molecule induced dipole-induced dipole interaction is present. In this case one dipole is created which induces dipole in nearby non-polar molecules.

(d)

Interpretation Introduction

Interpretation:

The type of intermolecular forces are present in liquid state of Iodine monochloride molecule must be explained.

Concept Introduction:

Various intermolecular forces are dipole-dipole interaction, ion-dipole interaction, induced dipole −induced dipole interaction.

Dipole-dipole interaction is present in molecules with permanent dipole moment. Positive pole of one dipole interacts with negative pole of another dipole.

In ion dipole interaction one dipole interact with another ion. Out of the two different poles one with opposite charge with respect to the ion interacts.

In non-polar molecule induced dipole-induced dipole interaction is present. In this case one dipole is created which induces dipole in nearby non-polar molecules.

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Answer 4

Question

Chapter 14, Problem 26QAP

Interpretation Introduction

(a)

Interpretation:

The type of intermolecular forces present in liquid state of xenon molecule must be explained.

Concept Introduction:

Various intermolecular forces are dipole-dipole interaction, ion-dipole interaction, induced dipole −induced dipole interaction.

Dipole-dipole interaction is present in molecules with permanent dipole moment. Positive pole of one dipole interacts with negative pole of another dipole.

In ion dipole interaction one dipole interact with another ion. Out of the two different poles one with opposite charge with respect to the ion interacts.

In non polar molecule induced dipole-induced dipole interaction is present. In this case one dipole is created which induces dipole in nearby non polar molecules.

Interpretation Introduction

(b)

Interpretation:

The type of intermolecular forces present in liquid state of ammonia molecule must be explained.

Concept Introduction:

Various intermolecular forces are dipole-dipole interaction, ion-dipole interaction, induced dipole −induced dipole interaction.

Dipole-dipole interaction is present in molecules with permanent dipole moment. Positive pole of one dipole interacts with negative pole of another dipole.

In ion dipole interaction one dipole interact with another ion. Out of the two different poles one with opposite charge with respect to the ion interacts.

In non-polar molecule induced dipole-induced dipole interaction is present. In this case one dipole is created which induces dipole in nearby non-polar molecules.

Interpretation Introduction

(c)

Interpretation:

The type of intermolecular forces are present in liquid state of fluorine molecule must be explained.

Concept Introduction:

Various intermolecular forces are dipole-dipole interaction, ion-dipole interaction, induced dipole −induced dipole interaction.

Dipole-dipole interaction is present in molecules with permanent dipole moment. Positive pole of one dipole interacts with negative pole of another dipole.

In ion dipole interaction one dipole interact with another ion. Out of the two different poles one with opposite charge with respect to the ion interacts.

In non-polar molecule induced dipole-induced dipole interaction is present. In this case one dipole is created which induces dipole in nearby non-polar molecules.

(d)

Interpretation Introduction

Interpretation:

The type of intermolecular forces are present in liquid state of Iodine monochloride molecule must be explained.

Concept Introduction:

Various intermolecular forces are dipole-dipole interaction, ion-dipole interaction, induced dipole −induced dipole interaction.

Dipole-dipole interaction is present in molecules with permanent dipole moment. Positive pole of one dipole interacts with negative pole of another dipole.

In ion dipole interaction one dipole interact with another ion. Out of the two different poles one with opposite charge with respect to the ion interacts.

In non-polar molecule induced dipole-induced dipole interaction is present. In this case one dipole is created which induces dipole in nearby non-polar molecules.

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Answer 5

Chapter 14, Problem 26QAP

Interpretation Introduction

(a)

Interpretation:

The type of intermolecular forces present in liquid state of xenon molecule must be explained.

Concept Introduction:

Various intermolecular forces are dipole-dipole interaction, ion-dipole interaction, induced dipole −induced dipole interaction.

Dipole-dipole interaction is present in molecules with permanent dipole moment. Positive pole of one dipole interacts with negative pole of another dipole.

In ion dipole interaction one dipole interact with another ion. Out of the two different poles one with opposite charge with respect to the ion interacts.

In non polar molecule induced dipole-induced dipole interaction is present. In this case one dipole is created which induces dipole in nearby non polar molecules.

Interpretation Introduction

(b)

Interpretation:

The type of intermolecular forces present in liquid state of ammonia molecule must be explained.

Concept Introduction:

Various intermolecular forces are dipole-dipole interaction, ion-dipole interaction, induced dipole −induced dipole interaction.

Dipole-dipole interaction is present in molecules with permanent dipole moment. Positive pole of one dipole interacts with negative pole of another dipole.

In ion dipole interaction one dipole interact with another ion. Out of the two different poles one with opposite charge with respect to the ion interacts.

In non-polar molecule induced dipole-induced dipole interaction is present. In this case one dipole is created which induces dipole in nearby non-polar molecules.

Interpretation Introduction

(c)

Interpretation:

The type of intermolecular forces are present in liquid state of fluorine molecule must be explained.

Concept Introduction:

Various intermolecular forces are dipole-dipole interaction, ion-dipole interaction, induced dipole −induced dipole interaction.

Dipole-dipole interaction is present in molecules with permanent dipole moment. Positive pole of one dipole interacts with negative pole of another dipole.

In ion dipole interaction one dipole interact with another ion. Out of the two different poles one with opposite charge with respect to the ion interacts.

In non-polar molecule induced dipole-induced dipole interaction is present. In this case one dipole is created which induces dipole in nearby non-polar molecules.

(d)

Interpretation Introduction

Interpretation:

The type of intermolecular forces are present in liquid state of Iodine monochloride molecule must be explained.

Concept Introduction:

Various intermolecular forces are dipole-dipole interaction, ion-dipole interaction, induced dipole −induced dipole interaction.

Dipole-dipole interaction is present in molecules with permanent dipole moment. Positive pole of one dipole interacts with negative pole of another dipole.

In ion dipole interaction one dipole interact with another ion. Out of the two different poles one with opposite charge with respect to the ion interacts.

In non-polar molecule induced dipole-induced dipole interaction is present. In this case one dipole is created which induces dipole in nearby non-polar molecules.

Answer 6

Chapter 14, Problem 26QAP

Interpretation Introduction

(a)

Interpretation:

The type of intermolecular forces present in liquid state of xenon molecule must be explained.

Concept Introduction:

Various intermolecular forces are dipole-dipole interaction, ion-dipole interaction, induced dipole −induced dipole interaction.

Dipole-dipole interaction is present in molecules with permanent dipole moment. Positive pole of one dipole interacts with negative pole of another dipole.

In ion dipole interaction one dipole interact with another ion. Out of the two different poles one with opposite charge with respect to the ion interacts.

In non polar molecule induced dipole-induced dipole interaction is present. In this case one dipole is created which induces dipole in nearby non polar molecules.

Answer 7

Chapter 14, Problem 26QAP

Interpretation Introduction

(a)

Interpretation:

The type of intermolecular forces present in liquid state of xenon molecule must be explained.

Concept Introduction:

Various intermolecular forces are dipole-dipole interaction, ion-dipole interaction, induced dipole −induced dipole interaction.

Dipole-dipole interaction is present in molecules with permanent dipole moment. Positive pole of one dipole interacts with negative pole of another dipole.

In ion dipole interaction one dipole interact with another ion. Out of the two different poles one with opposite charge with respect to the ion interacts.

In non polar molecule induced dipole-induced dipole interaction is present. In this case one dipole is created which induces dipole in nearby non polar molecules.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The type of intermolecular forces present in liquid state of ammonia molecule must be explained.

Concept Introduction:

Various intermolecular forces are dipole-dipole interaction, ion-dipole interaction, induced dipole −induced dipole interaction.

Dipole-dipole interaction is present in molecules with permanent dipole moment. Positive pole of one dipole interacts with negative pole of another dipole.

In ion dipole interaction one dipole interact with another ion. Out of the two different poles one with opposite charge with respect to the ion interacts.

In non-polar molecule induced dipole-induced dipole interaction is present. In this case one dipole is created which induces dipole in nearby non-polar molecules.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The type of intermolecular forces present in liquid state of ammonia molecule must be explained.

Concept Introduction:

Various intermolecular forces are dipole-dipole interaction, ion-dipole interaction, induced dipole −induced dipole interaction.

Dipole-dipole interaction is present in molecules with permanent dipole moment. Positive pole of one dipole interacts with negative pole of another dipole.

In ion dipole interaction one dipole interact with another ion. Out of the two different poles one with opposite charge with respect to the ion interacts.

In non-polar molecule induced dipole-induced dipole interaction is present. In this case one dipole is created which induces dipole in nearby non-polar molecules.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The type of intermolecular forces are present in liquid state of fluorine molecule must be explained.

Concept Introduction:

Various intermolecular forces are dipole-dipole interaction, ion-dipole interaction, induced dipole −induced dipole interaction.

Dipole-dipole interaction is present in molecules with permanent dipole moment. Positive pole of one dipole interacts with negative pole of another dipole.

In ion dipole interaction one dipole interact with another ion. Out of the two different poles one with opposite charge with respect to the ion interacts.

In non-polar molecule induced dipole-induced dipole interaction is present. In this case one dipole is created which induces dipole in nearby non-polar molecules.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The type of intermolecular forces are present in liquid state of fluorine molecule must be explained.

Concept Introduction:

Various intermolecular forces are dipole-dipole interaction, ion-dipole interaction, induced dipole −induced dipole interaction.

Dipole-dipole interaction is present in molecules with permanent dipole moment. Positive pole of one dipole interacts with negative pole of another dipole.

In ion dipole interaction one dipole interact with another ion. Out of the two different poles one with opposite charge with respect to the ion interacts.

In non-polar molecule induced dipole-induced dipole interaction is present. In this case one dipole is created which induces dipole in nearby non-polar molecules.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The type of intermolecular forces are present in liquid state of Iodine monochloride molecule must be explained.

Concept Introduction:

Various intermolecular forces are dipole-dipole interaction, ion-dipole interaction, induced dipole −induced dipole interaction.

Dipole-dipole interaction is present in molecules with permanent dipole moment. Positive pole of one dipole interacts with negative pole of another dipole.

In ion dipole interaction one dipole interact with another ion. Out of the two different poles one with opposite charge with respect to the ion interacts.

In non-polar molecule induced dipole-induced dipole interaction is present. In this case one dipole is created which induces dipole in nearby non-polar molecules.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The type of intermolecular forces are present in liquid state of Iodine monochloride molecule must be explained.

Concept Introduction:

Various intermolecular forces are dipole-dipole interaction, ion-dipole interaction, induced dipole −induced dipole interaction.

Dipole-dipole interaction is present in molecules with permanent dipole moment. Positive pole of one dipole interacts with negative pole of another dipole.

In ion dipole interaction one dipole interact with another ion. Out of the two different poles one with opposite charge with respect to the ion interacts.

In non-polar molecule induced dipole-induced dipole interaction is present. In this case one dipole is created which induces dipole in nearby non-polar molecules.

Answer 14

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Answer 25

Ch. 14.2 - trong>Exercise 14.1 Calculate the total energy...Ch. 14.3 - Prob. 1CT Ch. 14.6 - trong>Exercise 14.2 Name the type of crystalline...Ch. 14 - ou seal a container half-filled with water. Which...Ch. 14 - xplain the following: You add 100mLof water to a...Ch. 14 - Prob. 3ALQ Ch. 14 - Prob. 4ALQ Ch. 14 - Prob. 5ALQ Ch. 14 - Prob. 6ALQ Ch. 14 - Prob. 7ALQ

Solution Summary: The author explains the type of intermolecular forces present in liquid state of xenon molecule.

Chapter 14 Solutions