Essential Organic Chemistry, Global Edition
Essential Organic Chemistry, Global Edition
3rd Edition
ISBN: 9781292089034
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Chapter 14, Problem 20P
Interpretation Introduction

Interpretation:

The value for the relative east of removing a hydrogen atom from tertiary, secondary and primary hydrogen carbons by a chlorine radical has to be given.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

Chlorine radical forms a tertiary radical five times faster than a primary radical and it forms a secondary radical 3.8 times faster than a primary radical.

Relative rates of alkyl radical formation by a chlorine radical at 125 °C.

  Essential Organic Chemistry, Global Edition, Chapter 14, Problem 20P

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