GENERAL,ORGANIC, & BIOLOGICAL CHEM-ACCES
4th Edition
ISBN: 9781265982959
Author: SMITH
Publisher: MCG
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Textbook Question
Chapter 1.4, Problem 1.9P
Using the prefixes in Table 1.2, determine which quantity in each pair is larger.
- 3mL or 3cL
- 1ng or
- 5 km or 5 cm
- 2 mL or
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Complete the following table. The only density needed is already given. Show your
calculations in a neat and easy-to-follow manner in the space below the table. All units
should be included and significant figures should be given close attention. Be sure to notice
that the amount of material should be in millimoles rather than moles, and the theoretical
mass of the product should in milligrams rather than grams.
LOCH 3
+
H2SO4
HNO 3
O=C-OCH 3
NO2
x
H₂O
F.W.
4.0 mL 1.3 M
amount
0.50 mL
in H2SO4
mg Theoretical
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mmoles
density
1.09
Kumada Coupling:
1. m-Diisobutylbenzene below could hypothetically be synthesized by Friedel-Crafts reaction. Write out the reaction with a
mechanism and give two reasons why you would NOT get the desired product.
Draw the reaction (NOT a mechanism) for a Kumada coupling to produce the molecule above from m-dichlorobenzene.
Calculate the theoretical yield for the reaction in question 2 using 1.5 g of p-dichlorobenzene and 3.0 mL isobutyl bromide.
What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Wintergreen from Aspirin:
1. In isolating the salicylic acid, why is it important to press out as much of the water as possible?
2. Write the mechanism of the esterification reaction you did.
3.
What characteristic absorption band changes would you expect in the IR spectrum on going from aspirin to salicyclic acid and
then to methyl salicylate as you did in the experiment today? Give approximate wavenumbers associated with each functional
group change.
What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Chapter 1 Solutions
GENERAL,ORGANIC, & BIOLOGICAL CHEM-ACCES
Ch. 1.1 - Prob. 1.1PCh. 1.2 - Characterize each process as a physical change or...Ch. 1.2 - Does the molecular art represent a chemical change...Ch. 1.3 - Classify each example of molecular art as a pure...Ch. 1.3 - (a) Which representation(s) of molecular art...Ch. 1.3 - Classify each item as a pure substance or a...Ch. 1.3 - Classify each item as an element or a compound:...Ch. 1.4 - What term is used for each of the following units:...Ch. 1.4 - If a nanometer is one-billionth of a meter...Ch. 1.4 - Prob. 1.8P
Ch. 1.4 - Using the prefixes in Table 1.2, determine which...Ch. 1.5 - How many significant figures does each number...Ch. 1.5 - Indicate whether each zero in the following...Ch. 1.5 - Round off each number in Sample Problem 1.4 to two...Ch. 1.5 - Carry out each caluction and give the answer using...Ch. 1.5 - Carry out each calculation and give the answer...Ch. 1.6 - Write each number in scientific notation. 93,200...Ch. 1.6 - Lab results for a routine check-up showed an...Ch. 1.6 - Convert each number to its standard form. 6.5103...Ch. 1.7 - Write two conversion factors for each pair of...Ch. 1.7 - Carry out each of the following conversions. 25 L...Ch. 1.7 - On a flight from Bangkok, Thailand, to Taipei,...Ch. 1.7 - What is the volume of liquid contained in the...Ch. 1.7 - Carry out each of the following conversions. 6,250...Ch. 1.8 - A patient is prescribed 0.100 mg of a drug that is...Ch. 1.8 - Prob. 1.13PPCh. 1.8 - Prob. 1.14PCh. 1.9 - Prob. 1.14PPCh. 1.9 - Prob. 1.15PCh. 1.10 - How does the mass of liquid A in cylinder [1]...Ch. 1.10 - Calculate the mass in grams of 10.0 mL of diethyl...Ch. 1.10 - If a 120-lb woman uses five 2.0lb lead weights in...Ch. 1.10 - If a household recycles 10.5 kg of plastic bottles...Ch. 1.10 - If the density of a liquid is 0.80 g/mL, what is...Ch. 1 - Classify each example of molecular art as a pure...Ch. 1 - (a) Which representation(s) in Problem 1.19...Ch. 1 - Label each component in the molecular art as an...Ch. 1 - Label each component in the molecular art as an...Ch. 1 - (a) Which representation(s) illustrate a mixture...Ch. 1 - Label each of the following conversions as a...Ch. 1 - Classify each process as a chemical or physical...Ch. 1 - Classify each process as a chemical or physical...Ch. 1 - When a chunk of dry ice (solid carbon dioxide) is...Ch. 1 - The inexpensive preparation of nitrogen-containing...Ch. 1 - What is the temperature on the given Fahrenheit...Ch. 1 - a. What is the length of the given crayon in...Ch. 1 - Label each quantity as an exact or inexact number....Ch. 1 - Label each quantity as an exact or inexact number....Ch. 1 - Which quantity in each pair is larger? 5 mL or 5...Ch. 1 - Which quantity in each pair is larger? 10 km or 10...Ch. 1 - How many significant figures does each number...Ch. 1 - Prob. 36PCh. 1 - Prob. 37PCh. 1 - Prob. 38PCh. 1 - Prob. 39PCh. 1 - Prob. 40PCh. 1 - Prob. 41PCh. 1 - Prob. 42PCh. 1 - Prob. 43PCh. 1 - Prob. 44PCh. 1 - Prob. 45PCh. 1 - Rank the numbers in each group from smallest to...Ch. 1 - Prob. 47PCh. 1 - Prob. 48PCh. 1 - Prob. 49PCh. 1 - What is the volume of liquid contained in the...Ch. 1 - Prob. 51PCh. 1 - (a) If there are 15 mL in one tablespoon, how many...Ch. 1 - The concentration of mercury, a toxi pollutant, in...Ch. 1 - Prob. 54PCh. 1 - Prob. 55PCh. 1 - Prob. 56PCh. 1 - Prob. 57PCh. 1 - Prob. 58PCh. 1 - Prob. 59PCh. 1 - Prob. 60PCh. 1 - Which temperature in each pair is higher? a....Ch. 1 - Prob. 62PCh. 1 - Prob. 63PCh. 1 - Draw a graduated cylinder similar to Problem 1.63...Ch. 1 - The given beaker contains 100 mL of water. Draw an...Ch. 1 - Prob. 66PCh. 1 - Prob. 67PCh. 1 - Prob. 68PCh. 1 - If milk has a density of 1.03 g/mL, what is the...Ch. 1 - Prob. 70PCh. 1 - Prob. 71PCh. 1 - Prob. 72PCh. 1 - A lab test showed an individual’s chloesterol leve...Ch. 1 - Hemoglobin is a protein that transports oxygen...Ch. 1 - Prob. 75PCh. 1 - A soccer weighed 70.7 kg before a match, drank 1.8...Ch. 1 - Liposuction is a cosmetic procedure used to remove...Ch. 1 - A single 1-oz serving of tortilla chips contains...Ch. 1 - Prob. 79PCh. 1 - Prob. 80PCh. 1 - Prob. 81PCh. 1 - Prob. 82PCh. 1 - Prob. 83PCh. 1 - Prob. 84PCh. 1 - Often the specific amount of a drug to be...Ch. 1 - Prob. 86CPCh. 1 - Prob. 87CPCh. 1 - Prob. 88CPCh. 1 - Prob. 89CPCh. 1 - Prob. 90CPCh. 1 - Prob. 91CPCh. 1 - If the proper dosage of a medication is 10g/kg of...
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