LCPO CHEMISTRY W/MODIFIED MASTERING
8th Edition
ISBN: 9780135214756
Author: Robinson
Publisher: PEARSON
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Chapter 14, Problem 14.81SP
Interpretation Introduction
Interpretation:
Thegraphs needs to be interpreted to determine the order of reaction and the value of rate constant for the consumption of
Concept introduction:
The order of any chemical reaction is an experimental value that can be determined with the help of exponents of active masses of reactants in the given rate law. On the basis of different orders,
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42. Which of the following halogenated compounds can be used successfully to prepare a Grignard reagent for
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H3C CH3
a.
Br
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b.
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C.
I H
H
d. Cl
e.
H
OCH3
Br
H
For each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check
the appropriate box.
Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below.
Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions
- just focus on the first stable product you expect to form in solution.
?
Will the first
MgBr
product that forms in this reaction
create a new CC bond?
olo
?
OH
جمله
O Yes
Ⓒ No
MgCl
?
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create a new CC bond?
Click and drag to start drawing a
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Yes
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Chapter 14 Solutions
LCPO CHEMISTRY W/MODIFIED MASTERING
Ch. 14 - Prob. 14.1PCh. 14 - Prob. 14.2ACh. 14 - The rate law for the reaction...Ch. 14 - Prob. 14.4ACh. 14 - The initial rates listed in the following...Ch. 14 - Prob. 14.6ACh. 14 - Prob. 14.7PCh. 14 - Prob. 14.8ACh. 14 - Prob. 14.9PCh. 14 - Prob. 14.10A
Ch. 14 - Prob. 14.11PCh. 14 - Prob. 14.12ACh. 14 - Prob. 14.13PCh. 14 - Prob. 14.14ACh. 14 - Consider the first-order decomposition of H2O2...Ch. 14 - Prob. 14.16ACh. 14 - Hydrogen iodide gas decomposes at 410 °C:...Ch. 14 - Prob. 14.18ACh. 14 - Thereaction NO2(g)+CO(g)NO(g)+CO2(g) occurs in one...Ch. 14 - Prob. 14.20ACh. 14 - Prob. 14.21PCh. 14 - Apply 13.22 The rate of the reaction...Ch. 14 - Prob. 14.23PCh. 14 - Prob. 14.24ACh. 14 - Prob. 14.25PCh. 14 - Prob. 14.26ACh. 14 - Prob. 14.27PCh. 14 - Prob. 14.28ACh. 14 - The following mechanism has been proposed for the...Ch. 14 - Prob. 14.30ACh. 14 - Prob. 14.31PCh. 14 - Draw a potential energy diagram for the mechanism...Ch. 14 - Prob. 14.33PCh. 14 - Given the mechanism for an enzyme-catalyzed...Ch. 14 - Prob. 14.35PCh. 14 - Prob. 14.36PCh. 14 - At high substrate concentrations, the rate...Ch. 14 - Chymotrypsin is a digestive enzyme component of...Ch. 14 - Prob. 14.39CPCh. 14 - Prob. 14.40CPCh. 14 - Prob. 14.41CPCh. 14 - Prob. 14.42CPCh. 14 - Prob. 14.43CPCh. 14 - Prob. 14.44CPCh. 14 - Prob. 14.45CPCh. 14 - Prob. 14.46CPCh. 14 - Prob. 14.47CPCh. 14 - Prob. 14.48CPCh. 14 - Prob. 14.49CPCh. 14 - Use the data in Table 13.1 to calculate the...Ch. 14 - 13.50 Use the data in Table 13.1 to calculate the...Ch. 14 - Prob. 14.52SPCh. 14 - Prob. 14.53SPCh. 14 - From the plot of concentrationtime data in Figure...Ch. 14 - Prob. 14.55SPCh. 14 - Prob. 14.56SPCh. 14 - Prob. 14.57SPCh. 14 - Prob. 14.58SPCh. 14 - Prob. 14.59SPCh. 14 - Prob. 14.60SPCh. 14 - Prob. 14.61SPCh. 14 - Prob. 14.62SPCh. 14 - Prob. 14.63SPCh. 14 - Prob. 14.64SPCh. 14 - Prob. 14.65SPCh. 14 - Prob. 14.66SPCh. 14 - Prob. 14.67SPCh. 14 - The oxidation of iodide ion by hydrogen peroxide...Ch. 14 - Prob. 14.69SPCh. 14 - At 500 °C, cyclopropane (C3H6) rearranges to...Ch. 14 - The rearrangement of methyl isonitrile (CH3NC) to...Ch. 14 - What is the half-life (in minutes) of the reaction...Ch. 14 - Prob. 14.73SPCh. 14 - Prob. 14.74SPCh. 14 - Hydrogen iodide decomposes slowly to H2 and I2 at...Ch. 14 - What is the half-life (in minutes) of the reaction...Ch. 14 - Prob. 14.77SPCh. 14 - At 25 °C, the half-life of a certain first-order...Ch. 14 - The decomposition of N2O5 is a first-order...Ch. 14 - Prob. 14.80SPCh. 14 - Prob. 14.81SPCh. 14 - Prob. 14.82SPCh. 14 - Consider the following concentration-time data for...Ch. 14 - Trans-cycloheptene (C7H12), a strained cyclic...Ch. 14 - Thelight-stimulatedconversionof 11-cis-retinalto...Ch. 14 - Why don't all collisions between reactant...Ch. 14 - Prob. 14.87SPCh. 14 - Prob. 14.88SPCh. 14 - Prob. 14.89SPCh. 14 - The values of Ea=183 kJ/mol and E=9 kJ/mol have...Ch. 14 - Prob. 14.91SPCh. 14 - Consider three reactions with different values of...Ch. 14 - Prob. 14.93SPCh. 14 - Rate constants for the reaction...Ch. 14 - Prob. 14.95SPCh. 14 - Prob. 14.96SPCh. 14 - Prob. 14.97SPCh. 14 - If the rate of a reaction increases by a factor of...Ch. 14 - Prob. 14.99SPCh. 14 - Prob. 14.100SPCh. 14 - Rate constants for the reaction...Ch. 14 - Prob. 14.102SPCh. 14 - Poly(ethylene terephthalate) is a synthetic...Ch. 14 - Prob. 14.104SPCh. 14 - Prob. 14.105SPCh. 14 - Prob. 14.106SPCh. 14 - The following mechanism has been proposed for the...Ch. 14 - Prob. 14.108SPCh. 14 - Prob. 14.109SPCh. 14 - The thermal decomposition of nitryl chloride,...Ch. 14 - The substitution reactions of molybdenum...Ch. 14 - The reaction 2NO2(g)+F2(g)2NO2F(g) has a second...Ch. 14 - The decomposition of ozone in the upper atmosphere...Ch. 14 - Prob. 14.114SPCh. 14 - The following mechanism has been proposed for the...Ch. 14 - Prob. 14.116SPCh. 14 - Prob. 14.117SPCh. 14 - Prob. 14.118SPCh. 14 - Prob. 14.119SPCh. 14 - Prob. 14.120SPCh. 14 - Prob. 14.121SPCh. 14 - Prob. 14.122SPCh. 14 - Prob. 14.123SPCh. 14 - Consider the reaction 2NO(g)+O2(g)2NO2(g) . The...Ch. 14 - Concentration-time data for the conversion of A...Ch. 14 - Prob. 14.126MPCh. 14 - Prob. 14.127MPCh. 14 - Prob. 14.128MPCh. 14 - Prob. 14.129MPCh. 14 - Prob. 14.130MPCh. 14 - Prob. 14.131MPCh. 14 - Prob. 14.132MPCh. 14 - Prob. 14.133MPCh. 14 - Prob. 14.134MPCh. 14 - Polytetrafluoroethylene (Teflon) decomposes when...Ch. 14 - The reaction A is first order in the reactant A...Ch. 14 - Prob. 14.137MPCh. 14 - A 1.50 L sample of gaseous HI having a density of...Ch. 14 - The rate constant for the decomposition of gaseous...Ch. 14 - The rate constant for the first-order...Ch. 14 - Prob. 14.141MPCh. 14 - Prob. 14.142MPCh. 14 - At 791 K and relatively low pressures, the...
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