(a)
Interpretation:
The rate constant for the given reaction needs to be determined.
Concept introduction:
In chemistry, activation energy is the minimum energy which is needed to activate molecules or atoms to a situation in which they can experience chemical transformation. The activation energy is usually denoted by Eaand below is the relation between rate constant and activation energy:
The above equation is Arrhenius equation.
Here, A is Arrhenius constant, R is Universal gas constant and T is temperature.
(b)
Interpretation:
Whether the ONF molecule is linear or bent needs to be determined.
Concept introduction:
The geometry of the molecule can be determined by calculating the hybridization of the central atom in the molecule. The lone pair of electron/s present in the central atom plays an important role in determining the exact geometry or shape of the molecule.
(c)
Interpretation:
A plausible transition state for the below reaction needs to be drawn.
Concept introduction:
Transition state is defined as an intermediate state of the reaction. It is less stable and immediately converts to product.
(d)
Interpretation:
The reason for the low activation energy of the given reaction needs to be explained.
Concept introduction:
The activation energy for a reaction is defined as the minimum energy which is needed for a reaction to takes place.

Want to see the full answer?
Check out a sample textbook solution
Chapter 14 Solutions
LCPO CHEMISTRY W/MODIFIED MASTERING
- Can I please get all final concentrations please!arrow_forwardState the detailed mechanism of the reaction of benzene with isopropanol in sulfuric acid.arrow_forwardDo not apply the calculations, based on the approximation of the stationary state, to make them perform correctly. Basta discard the 3 responses that you encounter that are obviously erroneous if you apply the formula to determine the speed of a reaction. For the decomposition reaction of N2O5(g): 2 N2O5(g) · 4 NO2(g) + O2(g), the following mechanism has been proposed: N2O5 -> NO2 + NO3_(K1) NO2 + NO3 →> N2O5 (k-1) → NO2 + NO3 → NO2 + O2 + NO (K2) NO + N2O5 → NO2 + NO2 + NO2 (K3) Give the expression for the acceptable rate. (A). d[N₂O] dt = -1 2k,k₂[N205] k₁+k₂ d[N₂O5] (B). dt =-k₁[N₂O₂] + k₁[NO2][NO3] - k₂[NO2]³ (C). d[N₂O] dt =-k₁[N₂O] + k₁[N205] - K3 [NO] [N205] (D). d[N2O5] =-k₁[NO] - K3[NO] [N₂05] dtarrow_forward
- A 0.10 M solution of acetic acid (CH3COOH, Ka = 1.8 x 10^-5) is titrated with a 0.0250 M solution of magnesium hydroxide (Mg(OH)2). If 10.0 mL of the acid solution is titrated with 20.0 mL of the base solution, what is the pH of the resulting solution?arrow_forwardFor the decomposition reaction of N2O5(g): 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed: N2O5 NO2 + NO3 (K1) | NO2 + NO3 → N2O5 (k-1) | NO2 + NO3 NO2 + O2 + NO (k2) | NO + N2O51 NO2 + NO2 + NO2 (K3) → Give the expression for the acceptable rate. → → (A). d[N205] dt == 2k,k₂[N₂O₂] k₁+k₁₂ (B). d[N2O5] =-k₁[N₂O] + k₁[NO₂] [NO3] - k₂[NO₂]³ dt (C). d[N2O5] =-k₁[N₂O] + k [NO] - k₂[NO] [NO] d[N2O5] (D). = dt = -k₁[N2O5] - k¸[NO][N₂05] dt Do not apply the calculations, based on the approximation of the stationary state, to make them perform correctly. Basta discard the 3 responses that you encounter that are obviously erroneous if you apply the formula to determine the speed of a reaction.arrow_forwardFor the decomposition reaction of N2O5(g): 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed: N2O5 NO2 + NO3 (K1) | NO2 + NO3 → N2O5 (k-1) | NO2 + NO3 NO2 + O2 + NO (k2) | NO + N2O51 NO2 + NO2 + NO2 (K3) → Give the expression for the acceptable rate. → → (A). d[N205] dt == 2k,k₂[N₂O₂] k₁+k₁₂ (B). d[N2O5] =-k₁[N₂O] + k₁[NO₂] [NO3] - k₂[NO₂]³ dt (C). d[N2O5] =-k₁[N₂O] + k [NO] - k₂[NO] [NO] d[N2O5] (D). = dt = -k₁[N2O5] - k¸[NO][N₂05] dt Do not apply the calculations, based on the approximation of the stationary state, to make them perform correctly. Basta discard the 3 responses that you encounter that are obviously erroneous if you apply the formula to determine the speed of a reaction.arrow_forward
- R lactam or lactone considering as weak acid or weak base and whyarrow_forward81. a. Propose a mechanism for the following reaction: OH CH2=CHCHC=N b. What is the product of the following reaction? HO H₂O N=CCH2CH2CH OH HO CH3CCH=CH2 H₂O C=N 82. Unlike a phosphonium ylide that reacts with an aldehyde or a ketone to form an alkene a sulfonium uliaarrow_forwardFor each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. ? NH2 MgBr Will the first product that forms in this reaction create a new CC bond? ○ Yes ○ No MgBr ? Will the first product that forms in this reaction create a new CC bond? O Yes O No Click and drag to start drawing a structure. :☐ G x c olo Ar HEarrow_forward
- Predicting As the lead product manager at OrganometALEKS Industries, you are trying to decide if the following reaction will make a molecule with a new C - C bond as its major product: H₂N O H 1. ? 2. H3O+ If this reaction will work, draw the major organic product or products you would expect in the drawing area below. If there's more than one major product, you can draw them in any arrangement you like. Be sure you use wedge and dash bonds if necessary, for example to distinguish between major products with different stereochemistry. 0 If the major products of this reaction won't have a new CC bond, just check the box under the drawing area and leave it blank. فا Explanation Check Click and drag to start drawing a structure.arrow_forwardHighlight the chirality (or stereogenic) center(s) in the given compound. A compound may have one or more stereogenic centers. OH OH OH OH OH OHarrow_forwardUsing wedge-and-dash bonds, modify the bonds on the chiral carbon in the molecule below so the molecule has R stereochemical configuration. NH H Br X टेarrow_forward
- Chemistry: Matter and ChangeChemistryISBN:9780078746376Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl WistromPublisher:Glencoe/McGraw-Hill School Pub CoChemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage LearningChemistry for Engineering StudentsChemistryISBN:9781337398909Author:Lawrence S. Brown, Tom HolmePublisher:Cengage Learning
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning




