Modified Mastering Chemistry with Pearson eText -- Standalone Access Card -- for Chemistry: An Introduction to General, Organic, and Biological Chemistry (13th Edition)
13th Edition
ISBN: 9780134562254
Author: Karen C Timberlake
Publisher: PEARSON
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Chapter 14, Problem 14.68APP
Draw the condensed structural or line-angle formula if cyclic, for each of the following: (14.5)
a. dibutylamine
b. triethylamine
c. N,N-dipropylaniline
d. ethylmethylammonium bromide
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- Rank the following groups of compounds from most acidic (1) to least acidic (4). Place the number
corresponding to the compound's relative rank in the blank below the structure.
a.
NO₂
NO₂
CH2CH2CH2CH2OH
CH3 CH3CH2CHOH
CH3CH2CH2CH2OH
NO₂
CH3CHCH2CH2OH
b.
OH
OH
CH₂OH
CO₂H
HC
CN
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Give the major organic product(s) of the following reactions or sequences of reactions. Show all
relevant stereochemistry
a.
H
MgBr
1. ether
2. H₂O*
4
COH
b.
1. LIAIH, ether
2. H₂O
Choose the best reagent(s) for carrying out the following conversions from the list provided below.
Place the letter of the best choice in the blank to the left of the conversion. Reagents may be used
more than once.
a. 1.
CH3MgBr, ether
2. H3O+
NaOH
b. 1.
PBr3
2.
C.
2.
1. (CH3)3SiCl, (CH3CH2)3N
CH3MgBr, ether
3. H₂O*+
2. H3O+
e. 1. p-TosCl, pyridine
f.
نها
g.
2. NaOH
CrO3, H₂SO4, H₂O
1.
NaBH4, ethanol
2. H30*
h. PCC, CH2Cl2
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a.
b.
OH
OH
H
OH
O
any organic
Determine the rate law for sodium thiosulfate from the following data:
[Na2S2O3] Time (s)
0.0318 230.
0.0636 57.5
Chapter 14 Solutions
Modified Mastering Chemistry with Pearson eText -- Standalone Access Card -- for Chemistry: An Introduction to General, Organic, and Biological Chemistry (13th Edition)
Ch. 14.1 - What carboxylic acid is responsible for the pain...Ch. 14.1 - What carboxylic acid is found in vinegar?Ch. 14.1 - Prob. 14.3PPCh. 14.1 - Prob. 14.4PPCh. 14.1 - Draw the condensed structural formulas for a and b...Ch. 14.1 - Draw the condensed structural formulas for a and b...Ch. 14.2 - Identify the compound in each group that is most...Ch. 14.2 - Prob. 14.8PPCh. 14.2 - Prob. 14.9PPCh. 14.2 - Prob. 14.10PP
Ch. 14.2 - Prob. 14.11PPCh. 14.2 - Prob. 14.12PPCh. 14.2 - Prob. 14.13PPCh. 14.2 - Prob. 14.14PPCh. 14.3 - Prob. 14.15PPCh. 14.3 - Prob. 14.16PPCh. 14.3 - Prob. 14.17PPCh. 14.3 - Prob. 14.18PPCh. 14.3 - Prob. 14.19PPCh. 14.3 - Prob. 14.20PPCh. 14.3 - Prob. 14.21PPCh. 14.3 - Prob. 14.22PPCh. 14.3 - Prob. 14.23PPCh. 14.3 - Prob. 14.24PPCh. 14.4 - What are the products of the acid hydrolysis of an...Ch. 14.4 - Prob. 14.26PPCh. 14.4 - Prob. 14.27PPCh. 14.4 - Prob. 14.28PPCh. 14.5 - Prob. 14.29PPCh. 14.5 - Prob. 14.30PPCh. 14.5 - Prob. 14.31PPCh. 14.5 - Prob. 14.32PPCh. 14.5 - Prob. 14.33PPCh. 14.5 - Prob. 14.34PPCh. 14.5 - Prob. 14.35PPCh. 14.5 - Prob. 14.36PPCh. 14.5 - Prob. 14.37PPCh. 14.5 - Prob. 14.38PPCh. 14.6 - Prob. 14.39PPCh. 14.6 - Prob. 14.40PPCh. 14.6 - Prob. 14.41PPCh. 14.6 - Prob. 14.42PPCh. 14.6 - Prob. 14.43PPCh. 14.6 - Prob. 14.44PPCh. 14.6 - Draw the condensed structural or line-angle...Ch. 14.6 - Draw the condensed structural or line-angle...Ch. 14.6 - a. Identify the functional groups in dicyclanil....Ch. 14.6 - a. Identify the functional groups in enrofloxacin....Ch. 14 - Prob. 14.49UTCCh. 14 - Prob. 14.50UTCCh. 14 - The ester methyl butanoate has the odor and flavor...Ch. 14 - Prob. 14.52UTCCh. 14 - Phenylephrine is the active ingredient in some...Ch. 14 - Melatonin is a naturally occurring compound in...Ch. 14 - Prob. 14.55UTCCh. 14 - Prob. 14.56UTCCh. 14 - Prob. 14.57APPCh. 14 - 14.58 Write the IUPAC and common names, if any,...Ch. 14 - Prob. 14.59APPCh. 14 - Prob. 14.60APPCh. 14 - Draw the condensed structural or line-angle...Ch. 14 - Prob. 14.62APPCh. 14 - Prob. 14.63APPCh. 14 - 14.64 Draw the condensed structural or line-angle...Ch. 14 - Prob. 14.65APPCh. 14 - 14.66 Write the common name and classify each of...Ch. 14 - Prob. 14.67APPCh. 14 - Draw the condensed structural or line-angle...Ch. 14 - Prob. 14.69APPCh. 14 - Prob. 14.70APPCh. 14 - Write the IUPAC name for each of the following:...Ch. 14 - Prob. 14.72APPCh. 14 - Prob. 14.73APPCh. 14 - Prob. 14.74APPCh. 14 - Prob. 14.75APPCh. 14 - Toradol is used in dentistry to relieve pain....Ch. 14 - Prob. 14.77CPCh. 14 - Draw the line-angle formula and write the IUPAC...Ch. 14 - Prob. 14.79CPCh. 14 - Prob. 14.80CPCh. 14 - Prob. 14.81CPCh. 14 - Prob. 14.82CP
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