Draw the trigonal prismatic MH6 molecular compound, where M is a 3d transition metal. a) Draw the trigonal prismatic MH6 molecular compound and determine its point group. b) i. What is the symmetry species for the 4s orbital on the central metal? ii. What is the symmetry species for the 3dx²-y² orbital on the central metal? Note: The z-axis is the principal axis. iii. Suggest a crystal field energy diagram for a d² electron configuration in a trigonal prismatic coordination environment. Label the metal d-orbital with their corresponding symmetry species label. Use the appropriate character table in the resource section.

Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter13: Introduction To Symmetry In Quantum Mechanics
Section: Chapter Questions
Problem 13.31E: Structural isomers can have very different point groups. There are three isomers of dichlorobenzene....
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Draw the trigonal prismatic MH6 molecular compound, where M is a 3d transition metal.
a) Draw the trigonal prismatic MH6 molecular compound and determine its point group.
b) i.
What is the symmetry species for the 4s orbital on the central metal?
ii.
What is the symmetry species for the 3dx²-y² orbital on the central metal? Note: The z-axis is
the principal axis.
iii.
Suggest a crystal field energy diagram for a d² electron configuration in a trigonal prismatic
coordination environment. Label the metal d-orbital with their corresponding symmetry species
label. Use the appropriate character table in the resource section.
Transcribed Image Text:Draw the trigonal prismatic MH6 molecular compound, where M is a 3d transition metal. a) Draw the trigonal prismatic MH6 molecular compound and determine its point group. b) i. What is the symmetry species for the 4s orbital on the central metal? ii. What is the symmetry species for the 3dx²-y² orbital on the central metal? Note: The z-axis is the principal axis. iii. Suggest a crystal field energy diagram for a d² electron configuration in a trigonal prismatic coordination environment. Label the metal d-orbital with their corresponding symmetry species label. Use the appropriate character table in the resource section.
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