Determine the point group of the following. Consider all square planar PtCl4²- Pt(CO)Cl3 cis-Pt(CO)₂Cl₂ trans-Pt(CO)2Cl2

Q: Please draw the structures of the following molecules based on valence shell electron pair repulsion…

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Q: Use ligand group orbital approach to describe the bonding in [CO3] 2- . Include schematic…

A: Carbonates [CO3] 2-are polyatomic ligands. They are found to bind to two or three metals…

Q: a) Show the molecular orbital energy level diagram for o and t interaction of the orbitals in…

A: The detailed answer is attached below.

Q: .Draw the diatomic molecular orbital for NO* (assume the 2s and 2p orbitals for both N and O are…

A: Here the problem is based on molecular orbital Theory ( MOT). In the second question we have to use…

Q: Which of the following objects is chiral: (a) a left shoe,(b) a slice of bread, (c) a wood screw,…

A: a.

Q: Consider IF3O2 (with I as the central atom). How many isomers are possible (draw them)?Which is…

A: The isomers of IF3O2 are,   The most stable isomer is figure (III).  This is because, the adjacent…

Q: How many possible isomers are there of the ion IO2F32-? Sketch these, and indicate the point group…

A: We have to draw the possible isomers of IO2F3^-2 and also Sketch these isomers and indicate the…

Q: What is the point group of XeOF2 (Xe is the central atom) ?

A: In XeOF2 the central atom Xe undergo SP3d hybridization. Xe contains two lone pairs. So, the…

Q: Which would have a higher CO stretching frequency, Cr(CO)6 or V(CO)6–? Explain why in detail using…

A: A higher electron density on the metal causes an increase in the extent of back bonding. This leads…

Q: According to valence bond theory, what set of orbitals isused by a Period 4 metal ion in forming (a)…

A: a.

Q: 2.Why does   K4[NiBr6]  behave as a simple Curie paramagnet , but K2 [NiBr4] exhibit complex…

A: The spontaneous magnetization disappears at the Curie temperature, Tc.  Magnetization can still…

Q: Draw the LCAO MO diagram of CO₂ and show its ground-state electron configuration using the D₂h point…

A: In MO diagram of heteronuclear molecules, electronegativity plays an important role.Oxygen is more…

Q: NiCl4]2- and Ni(CO)4 have sp3 or dsp2 hybridization? Explain. What type of hybridization is shown by…

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Q: Please draw the structure of cis-[CoBr4C12]°¯ and determine its point group.

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Q: Define the terms ligang and coordination sphere.

A: Here are two terms we have to define: Ligand & Coordination sphere

Q: Which of the following molecular ions is paramagnetic and has a bond order equal to 2?…

A: (C) N22–

Q: Draw The Octahedral MO Diagram Of [CoF6]3-

A: The molecular orbital diagram of the given octahedral complex can be drawn as follows:

Q: Which is a major product of the reaction of lithium aluminum hydride with water? hydronium ion…

A: Given :Reactant : Lithium aluminium hydride and waterObjective : Predict the major product of the…

Q: 6. The point group for IF5 is C4v. Sketch the molecule.

A: Given: The point group for IF5 is C4v. To sketch the molecule.

Q: 2. Consider IF:O2 (with I as the central atom). How many isomers are possible (draw them)? Which is…

A: The chemical name of IF3O2 is iodine fluoride oxide. It has 5 sets of electron pairs around the…

Q: Apply IR and 13CNMR to identify isomers of [PtCl(CO)(PMe3)(C2H4)]+

A: IR) https://drive.google.com/file/d/1y-UIahNAHkcZt0aBN9CS9ODt5H1pGLZn/view?usp=drivesdk   Here, CO…

Q: 5. A molecule of Co(CN)3(CI)3 exists as both a fac- and mer- isomer which both exhibit unique…

A: Lewis structure ,point group and symmetry elements of the complex and it's isomer detail is given…

Q: Give the electron configuration and the number of unpaired electrons for (a) Sc³⁺; (b) Cu²⁺; (c)…

A: The distribution of electrons of an atom or molecule in atomic or molecular orbital is called…

Q: Draw a pz and a d orbital and assign their point groups.

A: Pz is unsymmetrical in phase but dz2 is symmetrical.

Q: Determine the point group for P CI Cl CI 1.

A: Determine point group of the given structure---

Q: draw structures of the following cations and determine their point groups: 1.…

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Q: Which of the following molecular ions is paramagnetic and has a bond order equal to 2?…

A: C N2-2 Is correct

Q: Draw the Lewis structure of SF4, determine its molecular geometry and point group, you will find…

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Q: cis [Fe(NH3)2(CO)2Br2] symmetry elements and point group?

A: Structure of cis Fe(NH3)2(CO)2Br2 is

Q: O Define chrómophore. Classify according to the type of electronic transitions, giving examples. the…

A: a)CHROMOPHORE: The term chromophore turned into formerly used to indicate a purposeful organization…

Q: Use ligand group orbital approach to describe the bonding in [CO3] 2- . Include schematic…

A: Solution: Bonding in [CO3] 2-  using ligand group molecular approach.

Q: Which is the strongest reductant: Al, Cu, I-, Al3+, Cu2+, or I2? Explain.

A: A reducing agent is an element or compound that loses an electron to an electron recipient in a…

Q: Using a group theory approach and the CO bond vectors as your basis determine if MnCl(CO)5 is…

A: The point group of MnCl(CO)5 is C4V.The character table of C4V is given below.

Q: (H2S2). These are trans (dihedral angle is 180), cis (dihedral angle is 0), and skew (any…

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Q: what's the point group of an octahedron with one blue face, the others yellow

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Q: Why Cs2[Cu(CN)4] doesn't exhibit a Jahn-Teller distortion

A: We have the complex We need to discuss why does not this complex exhibit Jahn-Teller distortion.