Write the complex hydrogen atom wave functions, 2p-1, 2po, and 2p, in terms of the real wave functions 2px, 2py, and 2pz. Step 1 of 3 Use the Real Hydrogen Atom Wave Functions Table to give the real angular wave functions. (Use the following as necessary: P, A, and 0.) V 3 sin (0) cos () 2px = sin (0)cos(@) 3 sin (0)sin(@) | 3 V sin (0) sin (ø) 2py = 3 cos (0 2pz = VE Cos (0) Step 2 of 3 Use the Complex Hydrogen Atom Wave Functions Table to give the complex angular wave functions. (Use the following as necessary: P, 7, and 0.) sin (0)e¯io 3 2p-1 = V 87 - sin (0) e-io cos (0) 3 Cos (0) 2po = sin (0)e 3 V sin (0) c** 2p+1 = 81 Step 3 of 3 Give the complex wave functions from Step 2 in terms of the real wave functions from Step 1. (Recall the Euler relations: etix = cos(x) ± i sin(x). Use the following as necessary: 2px, 2py, and 2pz.) 2p-1= 2po = 2p+1 =

Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter15: Introduction To Electronic Spectroscopy And Structure
Section: Chapter Questions
Problem 15.12E
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Write the complex hydrogen atom wave functions, 2p-1, 2po, and 2p1 in terms of the real wave functions 2px, 2py, and 2p7.
Step 1 of 3
Use the Real Hydrogen Atom Wave Functions Table to give the real angular wave functions. (Use the following as necessary: p, TT, and 0.)
3
sin (0)cos(9)
3
sin (0) cos (o)
2px =
3
sin (0)sin(9)
3
sin (0) sin ()
V 47
2py
4T
cos(0)
4t
3
Cos (0)
V 47
2pz =
Step 2 of 3
Use the Complex Hydrogen Atom Wave Functions Table to give the complex angular wave functions. (Use the following as necessary: P, 7, and 0.)
3
sin (0)e-i9
8T
3
2р-1 %3D
- sin (0) e
-io
V 87
3
2 cos (0)
2po =
V 4T
cos (e)
3
sin (0)e
sin (0) e*
2p+1 =
81
Step 3 of 3
Give the complex wave functions from Step 2 in terms of the real wave functions from Step 1. (Recall the Euler relations: e*IX = cos(x) ± i sin(x). Use the following as necessary: 2px, 2py, and 2p,.)
2р-1 %3
2po =
2p+1
Transcribed Image Text:Write the complex hydrogen atom wave functions, 2p-1, 2po, and 2p1 in terms of the real wave functions 2px, 2py, and 2p7. Step 1 of 3 Use the Real Hydrogen Atom Wave Functions Table to give the real angular wave functions. (Use the following as necessary: p, TT, and 0.) 3 sin (0)cos(9) 3 sin (0) cos (o) 2px = 3 sin (0)sin(9) 3 sin (0) sin () V 47 2py 4T cos(0) 4t 3 Cos (0) V 47 2pz = Step 2 of 3 Use the Complex Hydrogen Atom Wave Functions Table to give the complex angular wave functions. (Use the following as necessary: P, 7, and 0.) 3 sin (0)e-i9 8T 3 2р-1 %3D - sin (0) e -io V 87 3 2 cos (0) 2po = V 4T cos (e) 3 sin (0)e sin (0) e* 2p+1 = 81 Step 3 of 3 Give the complex wave functions from Step 2 in terms of the real wave functions from Step 1. (Recall the Euler relations: e*IX = cos(x) ± i sin(x). Use the following as necessary: 2px, 2py, and 2p,.) 2р-1 %3 2po = 2p+1
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