
Concept explainers
(a)
Interpretation:
The predominant organic product that is formed in the given reaction has to be written.
Concept Introduction:
Alcohol is an organic compound that has hydroxyl as its
Alkenes are compounds that contain a double bond between carbon atoms. When alkenes undergo hydration in presence of sulfuric acid as catalyst, an alcohol is formed as product. The major product formed in case of unsymmetrical alkene is found by using Markovnikov’s rule. The general scheme for hydration of alkene can be given as,
(b)
Interpretation:
The predominant organic product that is formed in the given reaction has to be written.
Concept Introduction:
Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate. Alcohols can be prepared in laboratory by hydration of alkenes and reduction of carbonyl compounds.
Double bond between a carbon atom and oxygen atom means that the compound is a carbonyl compound. Addition of hydrogen to this carbonyl group leads to the formation of alcohol. When hydrogen is added to the carbonyl, the oxygen of the carbonyl is converted into hydroxyl group. A scheme for the addition of hydrogen to the carbonyl group can be given as shown below,
(c)
Interpretation:
The predominant organic product that is formed in the given reaction has to be written.
Concept Introduction:
Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate. Alcohols can be prepared in laboratory by hydration of alkenes and reduction of carbonyl compounds.
Double bond between a carbon atom and oxygen atom means that the compound is a carbonyl compound. Addition of hydrogen to this carbonyl group leads to the formation of alcohol. When hydrogen is added to the carbonyl, the oxygen of the carbonyl is converted into hydroxyl group. A scheme for the addition of hydrogen to the carbonyl group can be given as shown below,
(d)
Interpretation:
The predominant organic product that is formed in the given reaction has to be written.
Concept Introduction:
Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate. Alcohols can be prepared in laboratory by hydration of alkenes and reduction of carbonyl compounds.
Alkenes are compounds that contain a double bond between carbon atoms. When alkenes undergo hydration in presence of sulfuric acid as catalyst, an alcohol is formed as product. The major product formed in case of unsymmetrical alkene is found by using Markovnikov’s rule. The general scheme for hydration of alkene can be given as,

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Chapter 14 Solutions
GENERAL,ORGANIC,+BIO.CHEM.-MINDTAP
- ✓ Check the box under each molecule that has a total of five ẞ hydrogens. If none of the molecules fit this description, check the box underneath the table. tab OH CI 0 Br xx Br None of these molecules have a total of five ẞ hydrogens. esc Explanation Check caps lock shift 1 fn control 02 F2 W Q A N #3 S 80 F3 E $ t 01 205 % 5 F5 & 7 © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center | Accessibility FT * 8 R T Y U כ F6 9 FIG F11 F D G H J K L C X V B < N M H option command P H + F12 commandarrow_forwardDraw the major product of this reaction. Ignore inorganic byproducts and the carboxylic acid side product. O 1. CHзMgBr (excess) 2. H₂O ✓ W X 人arrow_forwardIf cyclopentyl acetaldehyde reacts with NaOH, state the product (formula).arrow_forward
- Draw the major product of this reaction. Ignore inorganic byproducts. N S S HgCl2, H2SO4 く 8 W X Parrow_forwardtab esc く Drawing the After running various experiments, you determine that the mechanism for the following reaction occurs in a step-wise fashion. Br + OH + Using this information, draw the correct mechanism in the space below. 1 Explanation Check F2 F1 @2 Q W A os lock control option T S # 3 80 F3 Br $ 4 0105 % OH2 + Br Add/Remove step X C F5 F6 6 R E T Y 29 & 7 F D G H Click and drag to start drawing a structure. © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Ce A F7 DII F8 C Ո 8 * 9 4 F10 F C J K L C V Z X B N M H command P ge Coarrow_forwardIndicate compound A that must react with ethylbenzene to obtain 4-ethylbenzene-1-sulfonic acid. 3-bromo-4-ethylbenzene-1-sulfonic acid.arrow_forward
- Part 1 of 2 Draw the structure of A, the minor E1 product of the reaction. esc I Skip Part Check H₂O, D 2 A + Click and drag to start drawing a structure. -0- F1 F2 1 2 # 3 Q A 80 F3 W E S D F4 $ 4 % 5 F5 ㅇ F6 R T Y F G X 5 & 7 + Save 2025 McGraw Hill LLC. All Rights Reserved. DII F7 F8 H * C 80 J Z X C V B N 4 F9 6arrow_forwardFile Preview The following is a total synthesis of the pheromone of the western pine beetle. Such syntheses are interesting both because of the organic chemistry, and because of the possibility of using species specific insecticides, rather than broad band insecticides. Provide the reagents for each step. There is some chemistry from our most recent chapter in this synthesis, but other steps are review from earlier chapters. (8 points) COOEt COOEt A C COOEt COOEt COOH B OH OTS CN D E See the last homework set F for assistance on this one. H+, H₂O G OH OH The last step is just nucleophilic addition reactions, taking the ketone to an acetal, intramolecularly. But it is hard to visualize the three dimensional shape as it occurs. Frontalin, pheromone of the western pine beetlearrow_forwardFor the reaction below: 1. Draw all reasonable elimination products to the right of the arrow. 2. In the box below the reaction, redraw any product you expect to be a major product. C Major Product: Check + ◎ + X ง © Cl I F2 80 F3 I σ F4 I F5 NaOH Click and drawing F6 A 2025 McGraw Hill LLC. All Rights E F7 F8 $ # % & 2 3 4 5 6 7 8 Q W E R T Y U A S D F G H Jarrow_forward
- Can I please get help with this graph. If you can show exactly where it needs to pass through.arrow_forwardN Draw the major product of this reaction. Ignore inorganic byproducts. D 1. H₂O, pyridine 2. neutralizing work-up V P W X DE CO e C Larrow_forwardDraw the major product of this reaction. Ignore inorganic byproducts. N O' 1. H2O, pyridine 2. neutralizing work-up く 8 W aarrow_forward
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