Each of the following names is wrong. Give the structure and correct name of
each compound.
a
b
c.
d.
(a)
Interpretation:
The structural formula of
Concept introduction:
The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.
Rules for writing the structural formula from IUPAC are:
• First identify the word root for the given compound.
• The suffix used in the compound like –ane, ene, yne, ol, al and so on.
• Identify the position, location, and number of the substituent bonded to the carbon chain.
Aldehydes and ketones contain carbonyl functional group in their parent chain and are named by adding suffix –al and –one to the name of the parent alkane.
Answer to Problem 14.11E
The structural formula of
The correct name is
Explanation of Solution
The given name is
Figure 1
The longest carbon chain contains five carbon atoms. One methyl substituent is attached to the third carbon atom. The functional group present in the given compound is ketone
The structural formula is shown in Figure 1.
The correct name of the compound is
(b)
Interpretation:
The structural formula of
Concept introduction:
The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.
Rules for writing the structural formula from IUPAC are:
• First identify the word root for the given compound.
• The suffix used in the compound like –ane, ene, yne, ol, al and so on.
• Identify the position, location, and number of the substituent bonded to the carbon chain.
Aldehydes and ketones contain carbonyl functional group in their parent chain and are named by adding suffix –al and –one to the name of the parent alkane.
Answer to Problem 14.11E
The structural formula of
The correct name is
Explanation of Solution
The given name is
Figure 2
The longest carbon chain contains four carbon atoms. One methyl substituent is attached to the second carbon atom. The functional group present in the given compound is aldehyde
The structural formula is shown in Figure 2.
The correct name of the compound is
(c)
Interpretation:
The structural formula of
Concept introduction:
The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.
Rules for writing the structural formula from IUPAC are:
• First identify the word root for the given compound.
• The suffix used in the compound like –ane, ene, yne, ol, al and so on.
• Identify the position, location, and number of the substituent bonded to the carbon chain.
Aldehydes and ketones contain carbonyl functional group in their parent chain and are named by adding suffix –al and –one to the name of the parent alkane.
Answer to Problem 14.11E
The structural formula of
The correct name is
Explanation of Solution
The given name is
Figure 3
The longest carbon chain contains eight carbon atoms. One methyl substituent is attached to the fourth carbon atom and the other methyl group is attached to the fifth carbon atom. The functional group present in the given compound is ketone
The structural formula is shown in Figure 3.
The correct name of the compound is
(d)
Interpretation:
The structural formula of
Concept introduction:
The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.
Rules for writing the structural formula from IUPAC are:
• First identify the word root for the given compound.
• The suffix used in the compound like –ane, ene, yne, ol, al and so on.
• Identify the position, location, and number of the substituent bonded to the carbon chain.
Aldehydes and ketones contain carbonyl functional group in their parent chain and are named by adding suffix –al and –one to the name of the parent alkane.
Answer to Problem 14.11E
The structural formula of
The correct name is
Explanation of Solution
The given name is
Figure 4
The longest carbon chain contains three carbon atoms. One phenyl substituent is attached to the second carbon atom. The functional group present in the given compound is aldehyde
The structural formula is shown in Figure 4.
The correct name of the compound is
Want to see more full solutions like this?
Chapter 14 Solutions
Bundle: Chemistry for Today: General, Organic, and Biochemistry, Loose-Leaf Version, 9th + LMS Integrated OWLv2, 4 terms (24 months) Printed Access Card
- MATERIALS. Differentiate between interstitial position and reticular position.arrow_forwardFor each of the following, indicate whether the arrow pushes are valid. Do we break any rules via the arrows? If not, indicate what is incorrect. Hint: Draw the product of the arrow and see if you still have a valid structure. a. b. N OH C. H N + H d. e. f. مه N COHarrow_forwardDecide which is the most acidic proton (H) in the following compounds. Which one can be removed most easily? a) Ha Нь b) Ha Нь c) CI CI Cl Ha Ньarrow_forward
- Provide all of the possible resonanse structures for the following compounds. Indicate which is the major contributor when applicable. Show your arrow pushing. a) H+ O: b) c) : N :O : : 0 d) e) Оarrow_forwardDraw e arrows between the following resonance structures: a) b) : 0: :0: c) :0: N t : 0: بار Narrow_forwardDraw the major substitution products you would expect for the reaction shown below. If substitution would not occur at a significant rate under these conditions, check the box underneath the drawing area instead. Be sure you use wedge and dash bonds where necessary, for example to distinguish between major products. Note for advanced students: you can assume that the reaction mixture is heated mildly, somewhat above room temperature, but strong heat or reflux is not used. Cl Substitution will not occur at a significant rate. Explanation Check :☐ O-CH + Х Click and drag to start drawing a structure.arrow_forward
- Draw the major substitution products you would expect for the reaction shown below. If substitution would not occur at a significant rate under these conditions, check the box underneath the drawing area instead. Be sure you use wedge and dash bonds where necessary, for example to distinguish between major products. Note for advanced students: you can assume that the reaction mixture is heated mildly, somewhat above room temperature, but strong heat or reflux is not used. Cl C O Substitution will not occur at a significant rate. Explanation Check + O-CH3 Х Click and drag to start drawing a structure.arrow_forward✓ aw the major substitution products you would expect for the reaction shown below. If substitution would not occur at a significant rate under these conditions, check the box underneath the drawing area instead. Be sure you use wedge and dash bonds where necessary, for example to distinguish between major products. Note for advanced students: you can assume that the reaction mixture is heated mildly, somewhat above room temperature, but strong heat or reflux is not used. C Cl HO–CH O Substitution will not occur at a significant rate. Explanation Check -3 ☐ : + D Click and drag to start drawing a structure. © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use Privacy Cearrow_forwardPlease correct answer and don't used hand raitingarrow_forward
- Don't used hand raiting and don't used Ai solutionarrow_forwardDetermine whether the following reaction is an example of a nucleophilic substitution reaction: Br OH HO 2 -- Molecule A Molecule B + Br 义 ollo 18 Is this a nucleophilic substitution reaction? If this is a nucleophilic substitution reaction, answer the remaining questions in this table. Which of the reactants is referred to as the nucleophile in this reaction? Which of the reactants is referred to as the organic substrate in this reaction? Use a ŏ + symbol to label the electrophilic carbon that is attacked during the substitution. Highlight the leaving group on the appropriate reactant. ◇ Yes O No O Molecule A Molecule B Molecule A Molecule B टेarrow_forwardPlease correct answer and don't used hand raitingarrow_forward
- Introductory Chemistry: An Active Learning Approa...ChemistryISBN:9781305079250Author:Mark S. Cracolice, Ed PetersPublisher:Cengage LearningChemistry for Today: General, Organic, and Bioche...ChemistryISBN:9781305960060Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. HansenPublisher:Cengage LearningChemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning
- General Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage LearningChemistry: Matter and ChangeChemistryISBN:9780078746376Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl WistromPublisher:Glencoe/McGraw-Hill School Pub CoChemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning