Chemistry: The Molecular Nature of Matter
7th Edition
ISBN: 9781118516461
Author: Neil D. Jespersen, Alison Hyslop
Publisher: WILEY
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Chapter 14, Problem 12RQ
Equilibrium Laws Based on Pressures or Concentrations
State the equation relating
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Chapter 14 Solutions
Chemistry: The Molecular Nature of Matter
Ch. 14 - In what way dots the chapter-opening photo...Ch. 14 - Write the equilibrium law for each of the...Ch. 14 - The equilibrium law for a reaction is...Ch. 14 - At25C,Kc=7.01025forthereaction2SO2(g)+O2(g)2SO3(g)...Ch. 14 - At 25C, the following reactions have the...Ch. 14 - Write the equilibrium law in terms of partial...Ch. 14 - Using partial pressures, write the equilibrium law...Ch. 14 - Nitrous oxide, , is a gas used as an anesthetic;...Ch. 14 - Methanol, CH5OH, is a promising fuel that can be...Ch. 14 - Write the equilibrium law for the following...
Ch. 14 - Write the equilibrium law for each of the...Ch. 14 - Suppose a mixture contained equal concentrations...Ch. 14 - Arrange the following reactions in order of their...Ch. 14 - Consider the equilibrium...Ch. 14 - Consider the equilibrium PCl3(g)+Cl2(g)PCl5(g) for...Ch. 14 - In a particular experiment, it was found that when...Ch. 14 - An equilibrium was established for the reaction...Ch. 14 - A student placed 0.200 mol of PCl3(g) and 0.100...Ch. 14 - The decomposition of ,
has vessel contained...Ch. 14 - Prob. 20PECh. 14 - During an experiment, 0.200molofH2and0.200molofI2...Ch. 14 - In an experiment, were placed in a 1.00 L vessel...Ch. 14 - At 25C, the reaction...Ch. 14 - In air at and 1.00 atm, the concentration is...Ch. 14 - Dynamic Equilibrium in Chemical Systems 14.1...Ch. 14 - Dynamic Equilibrium in Chemical Systems
14.2 Using...Ch. 14 - Dynamic Equilibrium in Chemical Systems Repeat the...Ch. 14 - Dynamic Equilibrium in Chemical Systems
14.4 Using...Ch. 14 - 14.5 What meanings do the terms reactants and...Ch. 14 - Equilibrium Laws
14.6 What is an equilibrium law?....Ch. 14 - Equilibrium Laws
14.7 How is the term reaction...Ch. 14 - Equilibrium Laws
14.8 When a chemical equation and...Ch. 14 - Equilibrium Laws 14.9 Under what conditions does...Ch. 14 - Equilibrium Laws
14.10 Describe in words how the...Ch. 14 - Equilibrium Laws Based on Pressures or...Ch. 14 - Equilibrium Laws Based on Pressures or...Ch. 14 - Equilibrium Laws Based on Pressures or...Ch. 14 - Equilibrium Laws Based on Pressures or...Ch. 14 - Equilibrium Laws for Heterogeneous Reactions 14.15...Ch. 14 - Equilibrium Laws for Heterogeneous Reactions 14.16...Ch. 14 - Position of Equilibrium and the Equilibrium...Ch. 14 - Position of Equilibrium and the Equilibrium...Ch. 14 - Position of Equilibrium and the Equilibrium...Ch. 14 - Position of Equilibrium and the Equilibrium...Ch. 14 - Equilibrium and Le Chtelier's Principle State Le...Ch. 14 - Equilibrium and Le Chtelier's Principle Explain,...Ch. 14 - Equilibrium and Le Chteliers Principle Halving the...Ch. 14 - Equilibrium and Le Chteliers Principle How will...Ch. 14 - Equilibrium and Le Châtelier's Principle
14.25 Why...Ch. 14 - Equilibrium and Le Chtelier's Principle Why doesnt...Ch. 14 - Equilibrium Laws
14.27 Write the equilibrium law...Ch. 14 - Equilibrium Laws
14.28 Write the equilibrium law...Ch. 14 - Write the equilibrium law for the following...Ch. 14 - Write the equilibrium law for the following...Ch. 14 - At 25C,Kc=11085 for the reaction...Ch. 14 - Use the following equilibria...Ch. 14 - Write the equilibrium law for each of the...Ch. 14 - 14.34 Write the equilibrium law for the...Ch. 14 - Equilibrium Laws Based on Pressures and...Ch. 14 - 14.36 Write the equilibrium law for the reactions...Ch. 14 - Prob. 37RQCh. 14 - Prob. 38RQCh. 14 - For which of the following reactions does Kp=Kc?...Ch. 14 - For which of the following reactions does KpKc?...Ch. 14 - 14.41 The reaction has a . What is the value of ...Ch. 14 - 14.42 The reaction has a . What is the value of ...Ch. 14 - 14.43 The reaction has a . What is the value of ...Ch. 14 - One possible way of removing NO from the exhaust...Ch. 14 - At 773C the reaction CO(g)+2H2(g)CH3OH(g) has...Ch. 14 - The reaction...Ch. 14 - Equilibrium Laws for Heterogeneous Reactions...Ch. 14 - Equilibrium Laws for Heterogeneous Reactions The...Ch. 14 - Equilibrium Laws for Heterogeneous Reactions
14.49...Ch. 14 - Equilibrium Laws for Heterogeneous Reactions
14.50...Ch. 14 - The heterogeneous reaction...Ch. 14 - At 25C,Kc=360 for the reaction...Ch. 14 - Equilibrium and Le Chtelier's Principle The...Ch. 14 - Equilibrium and Le Chtelier's Principle How will...Ch. 14 - 14.55 Consider the equilibrium
In which direction...Ch. 14 - Consider the equilibrium 2NO(g)+Cl2(g)2NOCl(g) for...Ch. 14 - Calculating Equilibrium Constants At 773C, a...Ch. 14 - Calculating Equilibrium Constants Ethylene, C2H4,...Ch. 14 - At high temperature, 2.00 mol of HBr was placed in...Ch. 14 - A 0.050 mol sample of formaldehyde vapor, CH2O,...Ch. 14 - The reaction NO2(g)+NO(g)N2O(g)+O2(g) reached...Ch. 14 - At 25C,0.0560molO2and0.020molN2O were placed in a...Ch. 14 - Using Equilibrium Constants to Calculate...Ch. 14 - Using Equilibrium Constants to Calculate...Ch. 14 - 14.65 At a certain temperature, the reaction
has...Ch. 14 - 14.66 for the reaction
at a certain temperature....Ch. 14 - At 25C,Kc=0.145 for the following reaction in the...Ch. 14 - At 25C,Kc=0.145 for the following reaction in the...Ch. 14 - 14.69 The equilibrium constant, Kc, for the...Ch. 14 - For the reaction in Problem 14.69, a reaction...Ch. 14 - 14.71 At a certain temperature the reaction
has ....Ch. 14 - At 25C,Kc=0.145 for the following reaction in the...Ch. 14 - The reaction...Ch. 14 - 14.74 At for the reaction
If and are placed in...Ch. 14 - 14.75 At , the decomposition of , has . If a 1.00...Ch. 14 - At 500C, the decomposition of water into hydrogen...Ch. 14 - 14.77 At a certain temperature, for the...Ch. 14 - At 460C, the reaction SO2(g)+NO2(g)NO(g)+SO3(g)...Ch. 14 - 14.79 At a certain temperature, for the...Ch. 14 - At 25C,Kc=0.145 for the following reaction in the...Ch. 14 - *14.81 At a certain temperature, for the...Ch. 14 - The reaction...Ch. 14 - 14.83 The reaction at
. In a reaction vessel...Ch. 14 - 14.84 At , the following concentrations were found...Ch. 14 - The following reaction in aqueous solution has...Ch. 14 - At a certain temperature, Kc=0.914 for the...Ch. 14 - At 27C,Kc=1.51018 for the reaction...Ch. 14 - Consider the equilibrium...Ch. 14 - At a certain temperature, Kc=0.914 for the...Ch. 14 - At a certain temperature, Kc=0.914 for the...Ch. 14 - 14.91 Two 1.00 L bulbs are filled with 0.500 atm...Ch. 14 - For the equilibrium 3NO2(g)N2O5(g)+NO(g)...Ch. 14 - To study the following reaction at 20C,...Ch. 14 - Describe in words how the mass action expression...Ch. 14 - *14.95 For the reaction below,
A mixture of was...Ch. 14 - At 2000C, the decomposition of CO2,...Ch. 14 - *14.97 At , the reaction
has are placed in a...Ch. 14 - At 200.0C,Kc=1.410-10 for the reaction...Ch. 14 - At 400C,Kc=2.9104 for the reaction:...Ch. 14 - *14.100 The reaction . Into a 4.50 L reaction...Ch. 14 - 14.101 In an equilibrium law, coefficients in the...Ch. 14 - Why are equilibrium concentrations useful to know?Ch. 14 - 14.103 Suppose we set up a system in which water...Ch. 14 - 14.104 Do equilibrium laws apply to other systems...Ch. 14 - What might prevent a system from reaching dynamic...Ch. 14 - 14.106 After many centuries the earth’s atmosphere...Ch. 14 - 14.107 If a mixture consisting of many small...Ch. 14 - Why doesnt Le Chteliers principle apply to the...Ch. 14 - 14.109 Le Châtelier’s principle qualitatively...
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- For the reaction N2(g)+3H2(g)2NH3(g) show that Kc = Kp(RT)2 Do not use the formula Kp = Kc(RT)5n given in the text. Start from the fact that Pi = [i]RT, where Pi is the partial pressure of substance i and [i] is its molar concentration. Substitute into Kc.arrow_forwardWrite equilibrium-constant expressions Kp for each of the following reactions: a H2(g)+Br2(g)2HBr(g) b CS2(g)+4H2(g)CH4(g)+2H2S(g) c 4HCl(g)+O2(g)2H2O(g)+2Cl2(g) d CO(g)+2H2(g)CH3OH(g)arrow_forwardConsider the equilibrium N2(g)+O2(g)2NO(g) At 2300 K the equilibrium constant Kc = 1.7 103. If 0.15 mol NO(g) is placed into an empty, sealed 10.0-L flask and heated to 2300 K, calculate the equilibrium concentrations of all three substances at this temperature.arrow_forward
- Consider 0.200 mol phosphorus pentachloride sealed in a 2.0-L container at 620 K. The equilibrium constant, Kc, is 0.60 for PCl5(g) PCl3(g) + Cl2(g) Calculate the concentrations of all species after equilibrium has been reached.arrow_forwardCarbon dioxide reacts with carbon to give carbon monoxide according to the equation C(s)+CO2(g)2CO(g) At 700. C, a 2.0-L sealed flask at equilibrium contains 0.10 mol CO, 0.20 mol CO2, and 0.40 mol C. Calculate the equilibrium constant KP for this reaction at the specified temperature.arrow_forwardThe equilibrium constant Kc, for the reaction 2 NOCI(g) 2 NO(g) + Cl2(g) is 3.9 103 at 300 C. A mixture contains the gases at the following concentrations: [NOCl] = 5.0 103 mol/L, [NO] = 2.5 103 mol/L, and [Cl2] = 2.0 103 mol/L. Is the reaction at equilibrium at 300 C? If not, in which direction does the reaction proceed to come to equilibrium?arrow_forward
- Gaseous acetic acid molecules have a certain tendency to form dimers. (A dimer is a molecule formed by the association of two identical, simpler molecules.) The equilibrium constant Kc at 25C for this reaction is 3.2 104. a If the initial concentration of CH3COOH monomer (the simpler molecule) is 4.0 104 M, what are the concentrations of monomer and dimer when the system comes to equilibrium? (The simpler quadratic equation is obtained by assuming that all of the acid molecules have dimerized and then some of it dissociates to monomer.) b Why do acetic acid molecules dimerize? What type of structure would you draw for the dimer? c As the temperature increases would you expect the percentage of dimer to increase or decrease? Why?arrow_forwardCyclohexane, C6H12, a hydrocarbon, can isomerize or change into methylcyclopentane, a compound of the same formula (C5H9CH3) but with a different molecular structure. sssss The equilibrium constant has been estimated to be 0.12 at 25 C. If you had originally placed 0.045 mol of cyclohexane in a 2.8-L flask, what would be the concentrations of cyclohexane and methylcyclopentane when equilibrium is established?arrow_forwardAt high temperatures, a dynamic equilibrium exists between carbon monoxide, carbon dioxide, and solid carbon. C(s)+CO2(g)2CO(g);H=172.5kJ At 850C, Kc is 0.153. a What is the value of Kp? b If the original reaction system consisted of just carbon and 1.50 atm of CO2, what are the pressures of CO2 and CO when equilibrium has been established? c How will the equilibrium pressure of CO change if the temperature is decreased?arrow_forward
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