The structure of a given molecular formula C 8 H 16 to be predicted using spectrum details. Concept introduction: 1 HNMR : The 1 HNMR spectrum gives information on the different electronic environment of protons. The number of signal (proton types) generated in 1 HNMR are predicted by performing symmetry operations (rotation or reflection symmetry). The 13 CNMR spectrum gives information on the different electronic environments of carbon. As like 1 HNMR, the number of signals generated in 13 CNMR are predicted by performing symmetry operations (rotation or reflection symmetry). Only chemical shift values are reported in the spectrum but not the multiplicity and integration values because the coupling between two neighboring 13 C - 13 C nuclei are weakly involved due to the low abundance of 13 C isotopes of carbon atom. HDI Calculation: Where C represent number of carbons. N represent number of nitrogens. H represent number of hydrogens. X represent number of halogens. To identify: The structure of a given molecular formula C 8 H 16 .

Question

You are trying to decide if there is a single reagent you can add that will make the following synthesis possible without any other major side products: xi 1. ☑ 2. H₂O хе i Draw the missing reagent X you think will make this synthesis work in the drawing area below. If there is no reagent that will make your desired product in good yield or without complications, just check the box under the drawing area and leave it blank. Click and drag to start drawing a structure. There is no reagent that will make this synthesis work without complications. : ☐ S ☐

Answer 1

Question

Chapter 13.SE, Problem 46AP

Interpretation Introduction

Interpretation:

The structure of a given molecular formula C₈H₁₆ to be predicted using spectrum details.

Concept introduction:

¹HNMR : The ¹HNMR spectrum gives information on the different electronic environment of protons. The number of signal (proton types) generated in ¹HNMR are predicted by performing symmetry operations (rotation or reflection symmetry).

The ¹³CNMR spectrum gives information on the different electronic environments of carbon. As like ¹HNMR, the number of signals generated in ¹³CNMR are predicted by performing symmetry operations (rotation or reflection symmetry). Only chemical shift values are reported in the spectrum but not the multiplicity and integration values because the coupling between two neighboring ¹³C - ¹³C nuclei are weakly involved due to the low abundance of ¹³C isotopes of carbon atom.

HDI Calculation:

Where

C represent number of carbons.

N represent number of nitrogens.

H represent number of hydrogens.

X represent number of halogens.

To identify:

The structure of a given molecular formula C₈H₁₆.

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Students have asked these similar questions

You are trying to decide if there is a single reagent you can add that will make the following synthesis possible without any other major side products: xi 1. ☑ 2. H₂O хе i Draw the missing reagent X you think will make this synthesis work in the drawing area below. If there is no reagent that will make your desired product in good yield or without complications, just check the box under the drawing area and leave it blank. Click and drag to start drawing a structure. There is no reagent that will make this synthesis work without complications. : ☐ S ☐

Predict the major products of this organic reaction: H OH 1. LiAlH4 2. H₂O ? Note: be sure you use dash and wedge bonds when necessary, for example to distinguish between major products with different stereochemistry. Click and drag to start drawing a structure. G C टे

For each reaction below, decide if the first stable organic product that forms in solution will create a new C-C bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. NH2 CI MgCl ? Will the first product that forms in this reaction create a new CC bond? Yes No MgBr ? Will the first product that forms in this reaction create a new CC bond? Yes No G टे