The major product in the reaction needs to be identified. Concept introduction: The problem is based on the concept of enantioselective epoxidation. In this process, if a chiral epoxide needs to be formed, a racemic mixture of epoxide will be formed. Here for enantioselective epoxidation of allylic alcohols where the hydroxyl group is attached to the allylic position which is next to a C-C double bond, a catalyst is developed. This catalyst contains titanium tetraisopropoxide and enantiomer of diethyl tartrate.

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Answer 1

Question

Chapter 13.9, Problem 15CC

(a)

Interpretation Introduction

Interpretation: The major product in the reaction needs to be identified.

Concept introduction: The problem is based on the concept of enantioselective epoxidation. In this process, if a chiral epoxide needs to be formed, a racemic mixture of epoxide will be formed.

Here for enantioselective epoxidation of allylic alcohols where the hydroxyl group is attached to the allylic position which is next to a C-C double bond, a catalyst is developed. This catalyst contains titanium tetraisopropoxide and enantiomer of diethyl tartrate.

(b)

Interpretation Introduction

Interpretation: The major product in the reaction needs to be identified.

Concept introduction: The problem is based on the concept of enantioselective epoxidation. In this process, if a chiral epoxide needs to be formed, a racemic mixture of epoxide will be formed.

Here for enantioselective epoxidation of allylic alcohols where the hydroxyl group is attached to the allylic position which is next to a C-C double bond, a catalyst is developed. This catalyst contains titanium tetraisopropoxide and enantiomer of diethyl tartrate.

(c)

Interpretation Introduction

Interpretation; The major product in the reaction needs to be identified.

Concept introduction: The problem is based on the concept of enantioselective epoxidation. In this process, if a chiral epoxide needs to be formed, a racemic mixture of epoxide will be formed.

Here for enantioselective epoxidation of allylic alcohols where the hydroxyl group is attached to the allylic position which is next to a C-C double bond, a catalyst is developed. This catalyst contains titanium tetraisopropoxide and enantiomer of diethyl tartrate.

(d)

Interpretation Introduction

Interpretation: The major product in the reaction needs to be identified.

Concept introduction: The problem is based on the concept of enantioselective epoxidation. In this process, if a chiral epoxide needs to be formed, a racemic mixture of epoxide will be formed.

Here for enantioselective epoxidation of allylic alcohols where the hydroxyl group is attached to the allylic position which is next to a C-C double bond, a catalyst is developed. This catalyst contains titanium tetraisopropoxide and enantiomer of diethyl tartrate.

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Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the compound. Find the structure. Show complete solutions. Predicted 1H NMR Spectrum 4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 f1 (ppm) Predicted 13C NMR Spectrum 100 f1 (ppm) 30 220 210 200 190 180 170 160 150 140 130 120 110 90 80 70 -26 60 50 40 46 30 20 115 10 1.0 0.9 0.8 0 -10

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Answer 2

Question

Chapter 13.9, Problem 15CC

(a)

Interpretation Introduction

Interpretation: The major product in the reaction needs to be identified.

Concept introduction: The problem is based on the concept of enantioselective epoxidation. In this process, if a chiral epoxide needs to be formed, a racemic mixture of epoxide will be formed.

Here for enantioselective epoxidation of allylic alcohols where the hydroxyl group is attached to the allylic position which is next to a C-C double bond, a catalyst is developed. This catalyst contains titanium tetraisopropoxide and enantiomer of diethyl tartrate.

(b)

Interpretation Introduction

Interpretation: The major product in the reaction needs to be identified.

Concept introduction: The problem is based on the concept of enantioselective epoxidation. In this process, if a chiral epoxide needs to be formed, a racemic mixture of epoxide will be formed.

Here for enantioselective epoxidation of allylic alcohols where the hydroxyl group is attached to the allylic position which is next to a C-C double bond, a catalyst is developed. This catalyst contains titanium tetraisopropoxide and enantiomer of diethyl tartrate.

(c)

Interpretation Introduction

Interpretation; The major product in the reaction needs to be identified.

Concept introduction: The problem is based on the concept of enantioselective epoxidation. In this process, if a chiral epoxide needs to be formed, a racemic mixture of epoxide will be formed.

Here for enantioselective epoxidation of allylic alcohols where the hydroxyl group is attached to the allylic position which is next to a C-C double bond, a catalyst is developed. This catalyst contains titanium tetraisopropoxide and enantiomer of diethyl tartrate.

(d)

Interpretation Introduction

Interpretation: The major product in the reaction needs to be identified.

Concept introduction: The problem is based on the concept of enantioselective epoxidation. In this process, if a chiral epoxide needs to be formed, a racemic mixture of epoxide will be formed.

Here for enantioselective epoxidation of allylic alcohols where the hydroxyl group is attached to the allylic position which is next to a C-C double bond, a catalyst is developed. This catalyst contains titanium tetraisopropoxide and enantiomer of diethyl tartrate.

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Answer 3

Question

Chapter 13.9, Problem 15CC

(a)

Interpretation Introduction

Interpretation: The major product in the reaction needs to be identified.

Concept introduction: The problem is based on the concept of enantioselective epoxidation. In this process, if a chiral epoxide needs to be formed, a racemic mixture of epoxide will be formed.

Here for enantioselective epoxidation of allylic alcohols where the hydroxyl group is attached to the allylic position which is next to a C-C double bond, a catalyst is developed. This catalyst contains titanium tetraisopropoxide and enantiomer of diethyl tartrate.

(b)

Interpretation Introduction

Interpretation: The major product in the reaction needs to be identified.

Concept introduction: The problem is based on the concept of enantioselective epoxidation. In this process, if a chiral epoxide needs to be formed, a racemic mixture of epoxide will be formed.

Here for enantioselective epoxidation of allylic alcohols where the hydroxyl group is attached to the allylic position which is next to a C-C double bond, a catalyst is developed. This catalyst contains titanium tetraisopropoxide and enantiomer of diethyl tartrate.

(c)

Interpretation Introduction

Interpretation; The major product in the reaction needs to be identified.

Concept introduction: The problem is based on the concept of enantioselective epoxidation. In this process, if a chiral epoxide needs to be formed, a racemic mixture of epoxide will be formed.

Here for enantioselective epoxidation of allylic alcohols where the hydroxyl group is attached to the allylic position which is next to a C-C double bond, a catalyst is developed. This catalyst contains titanium tetraisopropoxide and enantiomer of diethyl tartrate.

(d)

Interpretation Introduction

Interpretation: The major product in the reaction needs to be identified.

Concept introduction: The problem is based on the concept of enantioselective epoxidation. In this process, if a chiral epoxide needs to be formed, a racemic mixture of epoxide will be formed.

Here for enantioselective epoxidation of allylic alcohols where the hydroxyl group is attached to the allylic position which is next to a C-C double bond, a catalyst is developed. This catalyst contains titanium tetraisopropoxide and enantiomer of diethyl tartrate.

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Answer 4

Question

Chapter 13.9, Problem 15CC

(a)

Interpretation Introduction

Interpretation: The major product in the reaction needs to be identified.

Concept introduction: The problem is based on the concept of enantioselective epoxidation. In this process, if a chiral epoxide needs to be formed, a racemic mixture of epoxide will be formed.

Here for enantioselective epoxidation of allylic alcohols where the hydroxyl group is attached to the allylic position which is next to a C-C double bond, a catalyst is developed. This catalyst contains titanium tetraisopropoxide and enantiomer of diethyl tartrate.

(b)

Interpretation Introduction

Interpretation: The major product in the reaction needs to be identified.

Concept introduction: The problem is based on the concept of enantioselective epoxidation. In this process, if a chiral epoxide needs to be formed, a racemic mixture of epoxide will be formed.

Here for enantioselective epoxidation of allylic alcohols where the hydroxyl group is attached to the allylic position which is next to a C-C double bond, a catalyst is developed. This catalyst contains titanium tetraisopropoxide and enantiomer of diethyl tartrate.

(c)

Interpretation Introduction

Interpretation; The major product in the reaction needs to be identified.

Concept introduction: The problem is based on the concept of enantioselective epoxidation. In this process, if a chiral epoxide needs to be formed, a racemic mixture of epoxide will be formed.

Here for enantioselective epoxidation of allylic alcohols where the hydroxyl group is attached to the allylic position which is next to a C-C double bond, a catalyst is developed. This catalyst contains titanium tetraisopropoxide and enantiomer of diethyl tartrate.

(d)

Interpretation Introduction

Interpretation: The major product in the reaction needs to be identified.

Concept introduction: The problem is based on the concept of enantioselective epoxidation. In this process, if a chiral epoxide needs to be formed, a racemic mixture of epoxide will be formed.

Here for enantioselective epoxidation of allylic alcohols where the hydroxyl group is attached to the allylic position which is next to a C-C double bond, a catalyst is developed. This catalyst contains titanium tetraisopropoxide and enantiomer of diethyl tartrate.

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Answer 5

Chapter 13.9, Problem 15CC

(a)

Interpretation Introduction

Interpretation: The major product in the reaction needs to be identified.

Concept introduction: The problem is based on the concept of enantioselective epoxidation. In this process, if a chiral epoxide needs to be formed, a racemic mixture of epoxide will be formed.

Here for enantioselective epoxidation of allylic alcohols where the hydroxyl group is attached to the allylic position which is next to a C-C double bond, a catalyst is developed. This catalyst contains titanium tetraisopropoxide and enantiomer of diethyl tartrate.

(b)

Interpretation Introduction

Interpretation: The major product in the reaction needs to be identified.

Concept introduction: The problem is based on the concept of enantioselective epoxidation. In this process, if a chiral epoxide needs to be formed, a racemic mixture of epoxide will be formed.

Here for enantioselective epoxidation of allylic alcohols where the hydroxyl group is attached to the allylic position which is next to a C-C double bond, a catalyst is developed. This catalyst contains titanium tetraisopropoxide and enantiomer of diethyl tartrate.

(c)

Interpretation Introduction

Interpretation; The major product in the reaction needs to be identified.

Concept introduction: The problem is based on the concept of enantioselective epoxidation. In this process, if a chiral epoxide needs to be formed, a racemic mixture of epoxide will be formed.

Here for enantioselective epoxidation of allylic alcohols where the hydroxyl group is attached to the allylic position which is next to a C-C double bond, a catalyst is developed. This catalyst contains titanium tetraisopropoxide and enantiomer of diethyl tartrate.

(d)

Interpretation Introduction

Interpretation: The major product in the reaction needs to be identified.

Concept introduction: The problem is based on the concept of enantioselective epoxidation. In this process, if a chiral epoxide needs to be formed, a racemic mixture of epoxide will be formed.

Here for enantioselective epoxidation of allylic alcohols where the hydroxyl group is attached to the allylic position which is next to a C-C double bond, a catalyst is developed. This catalyst contains titanium tetraisopropoxide and enantiomer of diethyl tartrate.

Answer 6

Chapter 13.9, Problem 15CC

(a)

Interpretation Introduction

Interpretation: The major product in the reaction needs to be identified.

Concept introduction: The problem is based on the concept of enantioselective epoxidation. In this process, if a chiral epoxide needs to be formed, a racemic mixture of epoxide will be formed.

Here for enantioselective epoxidation of allylic alcohols where the hydroxyl group is attached to the allylic position which is next to a C-C double bond, a catalyst is developed. This catalyst contains titanium tetraisopropoxide and enantiomer of diethyl tartrate.

Answer 7

Chapter 13.9, Problem 15CC

(a)

Interpretation Introduction

Interpretation: The major product in the reaction needs to be identified.

Concept introduction: The problem is based on the concept of enantioselective epoxidation. In this process, if a chiral epoxide needs to be formed, a racemic mixture of epoxide will be formed.

Here for enantioselective epoxidation of allylic alcohols where the hydroxyl group is attached to the allylic position which is next to a C-C double bond, a catalyst is developed. This catalyst contains titanium tetraisopropoxide and enantiomer of diethyl tartrate.

Answer 8

(b)

Interpretation Introduction

Interpretation: The major product in the reaction needs to be identified.

Concept introduction: The problem is based on the concept of enantioselective epoxidation. In this process, if a chiral epoxide needs to be formed, a racemic mixture of epoxide will be formed.

Here for enantioselective epoxidation of allylic alcohols where the hydroxyl group is attached to the allylic position which is next to a C-C double bond, a catalyst is developed. This catalyst contains titanium tetraisopropoxide and enantiomer of diethyl tartrate.

Answer 9

(b)

Interpretation Introduction

Interpretation: The major product in the reaction needs to be identified.

Concept introduction: The problem is based on the concept of enantioselective epoxidation. In this process, if a chiral epoxide needs to be formed, a racemic mixture of epoxide will be formed.

Here for enantioselective epoxidation of allylic alcohols where the hydroxyl group is attached to the allylic position which is next to a C-C double bond, a catalyst is developed. This catalyst contains titanium tetraisopropoxide and enantiomer of diethyl tartrate.

Answer 10

(c)

Interpretation Introduction

Interpretation; The major product in the reaction needs to be identified.

Concept introduction: The problem is based on the concept of enantioselective epoxidation. In this process, if a chiral epoxide needs to be formed, a racemic mixture of epoxide will be formed.

Here for enantioselective epoxidation of allylic alcohols where the hydroxyl group is attached to the allylic position which is next to a C-C double bond, a catalyst is developed. This catalyst contains titanium tetraisopropoxide and enantiomer of diethyl tartrate.

Answer 11

(c)

Interpretation Introduction

Interpretation; The major product in the reaction needs to be identified.

Concept introduction: The problem is based on the concept of enantioselective epoxidation. In this process, if a chiral epoxide needs to be formed, a racemic mixture of epoxide will be formed.

Here for enantioselective epoxidation of allylic alcohols where the hydroxyl group is attached to the allylic position which is next to a C-C double bond, a catalyst is developed. This catalyst contains titanium tetraisopropoxide and enantiomer of diethyl tartrate.

Answer 12

(d)

Interpretation Introduction

Interpretation: The major product in the reaction needs to be identified.

Concept introduction: The problem is based on the concept of enantioselective epoxidation. In this process, if a chiral epoxide needs to be formed, a racemic mixture of epoxide will be formed.

Here for enantioselective epoxidation of allylic alcohols where the hydroxyl group is attached to the allylic position which is next to a C-C double bond, a catalyst is developed. This catalyst contains titanium tetraisopropoxide and enantiomer of diethyl tartrate.

Answer 13

(d)

Interpretation Introduction

Interpretation: The major product in the reaction needs to be identified.

Concept introduction: The problem is based on the concept of enantioselective epoxidation. In this process, if a chiral epoxide needs to be formed, a racemic mixture of epoxide will be formed.

Here for enantioselective epoxidation of allylic alcohols where the hydroxyl group is attached to the allylic position which is next to a C-C double bond, a catalyst is developed. This catalyst contains titanium tetraisopropoxide and enantiomer of diethyl tartrate.

Answer 14

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Answer 15

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Answer 17

Ch. 13.2 - Prob. 1LTS Ch. 13.2 - Prob. 1PTS Ch. 13.2 - Prob. 2PTS Ch. 13.2 - Prob. 3ATS Ch. 13.4 - Prob. 4CC Ch. 13.5 - Prob. 2LTS Ch. 13.5 - Prob. 5PTS Ch. 13.5 - Prob. 6ATS Ch. 13.5 - Prob. 7CC Ch. 13.5 - Prob. 8CC

Solution Summary: The author explains the concept of enantioselective epoxidation, where the hydroxyl group is at the right corner, and the reaction with peroxy acid and (+)-DET results in the

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