EBK ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG
EBK ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG
4th Edition
ISBN: 9781119659525
Author: Klein
Publisher: WILEY CONS
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Chapter 13, Problem 35PP
Interpretation Introduction

Interpretation: The unknown product of the given reaction to be predicted.

Concept Introduction:

Useful reagents:

  1. 1. NaH : A strong base which abstract the acidic proton and generate alkoxide ion.

Intramolecular SN2 reaction: The groups like esters, sulfides, carboxylates, ethers, amines or alkoxide also assist substitution reactions through neighboring group participation. All must possess an electron-rich heteroatom with a lone pair of electron that can be used to form the cyclic intermediates or cyclic products.

To Identify: The reagents for the transformation of the given reaction.

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16. The proton NMR spectral information shown in this problem is for a compound with formula CioH,N. Expansions are shown for the region from 8.7 to 7.0 ppm. The normal carbon-13 spec- tral results, including DEPT-135 and DEPT-90 results, are tabulated: 7 J Normal Carbon DEPT-135 DEPT-90 19 ppm Positive No peak 122 Positive Positive cus и 124 Positive Positive 126 Positive Positive 128 No peak No peak 4° 129 Positive Positive 130 Positive Positive (144 No peak No peak 148 No peak No peak 150 Positive Positive してし
3. Propose a synthesis for the following transformation. Do not draw an arrow-pushing mechanism below, but make sure to draw the product of each proposed step (3 points). + En CN CN
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Chapter 13 Solutions

EBK ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG

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