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Concept explainers
(a)
Interpretation: A name for given compound needs to be assigned.
Concept Introduction: Nomenclature of
First method- Parent
Second method: Oxirane ring is considered as parent and groups attached to it are considered as substituents.
(b)
Interpretation: A name for given compound needs to be assigned.
Concept Introduction: Nomenclature of epoxides: Epoxides are cyclic ethers having an oxygen atom incorporated in three-membered ring system having up to four R groups. Due to ring strain, they are more reactive than other ethers. The simplest epoxide does not have any R group and known as ethylene oxide. Naming is done by two methods.
First method- Parent alkane chain is identified and oxygen is considered as substituent on that chain. Location of epoxide group is written with two numbers with suffix epoxy. While naming, epoxy substituents are alphabetically arranged.
Second method: Oxirane ring is considered as parent and groups attached to it are considered as substituents.
(c)
Interpretation: A name for given compound needs to be assigned.
Concept Introduction: Nomenclature of epoxides: Epoxides are cyclic ethers having an oxygen atom incorporated in three-membered ring system having up to four R groups. Due to ring strain, they are more reactive than other ethers. The simplest epoxide does not have any R group and known as ethylene oxide. Naming is done by two methods.
First method- Parent alkane chain is identified and oxygen is considered as substituent on that chain. Location of epoxide group is written with two numbers with suffix epoxy. While naming, epoxy substituents are alphabetically arranged.
Second method: Oxirane ring is considered as parent and groups attached to it are considered as substituents.
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Chapter 13 Solutions
EBK ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG
- CHEM2323 E Tt PS CH03 Draw and name all monobromo derivatives of pentane, C5H11Br. Problem 3-33 Name: Draw structures for the following: (a) 2-Methylheptane (d) 2,4,4-Trimethylheptane Problem 3-35 (b) 4-Ethyl-2,2-dimethylhexane (e) 3,3-Diethyl-2,5-dimethylnonane (c) 4-Ethyl-3,4-dimethyloctane 2 (f) 4-Isopropyl-3-methylheptane KNIE>arrow_forwardProblem 3-42 Consider 2-methylbutane (isopentane). Sighting along the C2-C3 bond: (a) Draw a Newman projection of the most stable conformation. (b) Draw a Newman projection of the least stable conformation. Problem 3-44 Construct a qualitative potential-energy diagram for rotation about the C-C bond of 1,2-dibromoethane. Which conformation would you expect to be most stable? Label the anti and gauche conformations of 1,2- dibromoethane. Problem 3-45 Which conformation of 1,2-dibromoethane (Problem 3-44) would you expect to have the largest dipole moment? The observed dipole moment of 1,2-dibromoethane is µ = 1.0 D. What does this tell you about the actual conformation of the molecule?arrow_forwardGas Law Studies 1. Mass of zinc Determination of 0.899 2) Moles of zinc 0.01361 mol 3.) Moles of hydrogen 00? ← I was told to calculate this number from mole of zinc. 350m So does that mean it will be 0.01361 mol too? 4 Volume of water collected (mL) 5) VL of water collected (Liters) 0.350 L 6) Temp of water collected (°C) 7) Temp of water collected (°K) 8) Atmospheric pressure (mm) 9) Vapor pressure of water (mm) 10) Corrected pressure of hydrogen 20% 29°C 764.0mm Hg (mm) 17.5mm 11) Corrected pressure of hydrogen (atm) 12) Experimentally calculated value of 19 13. Literature value of R 14) % Error 15) Suggest reasons for the % error (#14)arrow_forward
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