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Concept explainers
Interpretation:
The reagent that has to be used for the given transformation must be identified.
Concept Introduction:
In a reaction if the oxidation state of the carbon atom is increased means, then oxidation reaction has occurred. Conversion of primary alcohol into an
In case of primary alcohol, if we use a very strong oxidizing agent, then the final product is carboxylic acid. If the alcohol taken is a secondary alcohol then the final product is a ketone. When primary alcohol is oxidized, first aldehyde is obtained and then it is further oxidized to carboxylic acid. In case, if we use a mild oxidizing agent, the aldehyde product can be obtained from primary alcohol.
Primary alcohol is oxidized to carboxylic acid by strong oxidizing agent like chromic acid.
In order to obtain aldehyde as a product from primary alcohol, a mild oxidizing agent is used like pyridinium chlorochromate (PCC).
Secondary alcohol on oxidation gives ketone as the product.
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Chapter 13 Solutions
Organic Chemistry As a Second Language: First Semester Topics
- Which statement about the following chemical reaction is not correct? 2NH3+202 →→→ N2O + 3H₂O ○ It requires 2 mol of ammonia to produce 3 mol of water. It requires 2 mol of dioxygen to produce 1 mol of N2O. ○ Nine moles of water are produced when four moles of ammonia are consumed. Two moles of N2O would be produced when four moles of dioxygen are consumed. Two moles of ammonia react with two moles of dioxygen.arrow_forwardIf 169.7 g of NaOH (40.0 g/mol) were used to prepare 3411.0 mL of solution, what would the concentration be? Group of answer choicesarrow_forwardThe mass of 3.6 mol of some element is 576 g. What is the element?arrow_forward
- I have a question about this problem involving mechanisms and drawing curved arrows for acids and bases. I know we need to identify the nucleophile and electrophile, but are there different types of reactions? For instance, what about Grignard reagents and other types that I might not be familiar with? Can you help me with this? I want to identify the names of the mechanisms for problems 1-14, such as Gilman reagents and others. Are they all the same? Also, could you rewrite it so I can better understand? The handwriting is pretty cluttered. Additionally, I need to label the nucleophile and electrophile, but my main concern is whether those reactions differ, like the "Brønsted-Lowry acid-base mechanism, Lewis acid-base mechanism, acid-catalyzed mechanisms, acid-catalyzed reactions, base-catalyzed reactions, nucleophilic substitution mechanisms (SN1 and SN2), elimination reactions (E1 and E2), organometallic mechanisms, and so forth."arrow_forwardI have a question about this problem involving mechanisms and drawing curved arrows for acids and bases. I know we need to identify the nucleophile and electrophile, but are there different types of reactions? For instance, what about Grignard reagents and other types that I might not be familiar with? Can you help me with this? I want to identify the names of the mechanisms for problems 1-14, such as Gilman reagents and others. Are they all the same? Also, could you rewrite it so I can better understand? The handwriting is pretty cluttered. Additionally, I need to label the nucleophile and electrophile, but my main concern is whether those reactions differ, like the "Brønsted-Lowry acid-base mechanism, Lewis acid-base mechanism, acid-catalyzed mechanisms, acid-catalyzed reactions, base-catalyzed reactions, nucleophilic substitution mechanisms (SN1 and SN2), elimination reactions (E1 and E2), organometallic mechanisms, and so forth."arrow_forwardI have a question about this problem involving mechanisms and drawing curved arrows for acids and bases. I know we need to identify the nucleophile and electrophile, but are there different types of reactions? For instance, what about Grignard reagents and other types that I might not be familiar with? Can you help me with this? I want to identify the names of the mechanisms for problems 1-14, such as Gilman reagents and others. Are they all the same? Also, could you rewrite it so I can better understand? The handwriting is pretty cluttered. Additionally, I need to label the nucleophile and electrophile, but my main concern is whether those reactions differ, like the "Brønsted-Lowry acid-base mechanism, Lewis acid-base mechanism, acid-catalyzed mechanisms, acid-catalyzed reactions, base-catalyzed reactions, nucleophilic substitution mechanisms (SN1 and SN2), elimination reactions (E1 and E2), organometallic mechanisms, and so forth."arrow_forward
- Show work with explanation. Don't give Ai generated solutionarrow_forwardShow work. don't give Ai generated solutionarrow_forwardUse the average molarity of acetic acid (0.0867M) to calculate the concentration in % (m/v). Then calculate the % difference between the calculated concentrations of your unknown vinegar solution with the 5.00% (w/v%) vinegar solution (check the formula for % difference in the previous lab or online). Before calculating the difference with vinegar, remember that this %(m/v) is of the diluted solution. It has been diluted 10 times.arrow_forward
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