Organic Chemistry As a Second Language: First Semester Topics
4th Edition
ISBN: 9781119110668
Author: David R. Klein
Publisher: WILEY
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Chapter 13.1, Problem 13.5P
Interpretation Introduction
Interpretation:
The given alcohol has to be identified as primary, secondary or tertiary.
Concept Introduction:
Alcohols are the organic compounds that contain hydroxyl group (
The carbon atom that is attached to the hydroxyl group is known as the alpha (
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Would the following organic synthesis occur in one step? Add any missing products, required catalysts, inorganic reagents, and other important conditions. Please include a detailed explanation and drawings showing how the reaction may occur in one step.
This organic molecule is dissolved in an acidic aqueous solution:
OH
OH
A short time later sensitive infrared spectroscopy reveals the presence of a new C = O stretch absorption. That is, there must now be a new molecule present
with at least one C = O bond.
In the drawing area below, show the detailed mechanism that could convert the molecule above into the new molecule.
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Curved arrows are used to
illustrate the flow of electrons.
Use the reaction conditions
provided and follow the curved
arrows to draw the product of
this carbocation rearrangement.
Include all lone pairs and
charges as appropriate.
H
1,2-alkyl shift
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Chapter 13 Solutions
Organic Chemistry As a Second Language: First Semester Topics
Ch. 13.1 - Prob. 13.2PCh. 13.1 - Prob. 13.3PCh. 13.1 - Prob. 13.4PCh. 13.1 - Prob. 13.5PCh. 13.2 - Prob. 13.7PCh. 13.2 - Prob. 13.8PCh. 13.2 - Prob. 13.9PCh. 13.2 - Prob. 13.10PCh. 13.3 - PROBLEMS For each pair of compounds, identify the...Ch. 13.3 - Prob. 13.13P
Ch. 13.3 - Prob. 13.14PCh. 13.3 - Prob. 13.15PCh. 13.3 - Prob. 13.16PCh. 13.3 - Prob. 13.17PCh. 13.4 - Prob. 13.19PCh. 13.4 - Prob. 13.20PCh. 13.4 - Prob. 13.21PCh. 13.4 - Prob. 13.22PCh. 13.5 - Prob. 13.24PCh. 13.5 - Prob. 13.25PCh. 13.5 - Prob. 13.26PCh. 13.5 - Prob. 13.27PCh. 13.5 - Prob. 13.28PCh. 13.5 - Prob. 13.29PCh. 13.5 - Prob. 13.31PCh. 13.5 - Prob. 13.32PCh. 13.5 - Prob. 13.33PCh. 13.5 - Prob. 13.34PCh. 13.5 - Prob. 13.35PCh. 13.5 - Prob. 13.36PCh. 13.6 - Prob. 13.38PCh. 13.6 - Prob. 13.39PCh. 13.6 - Prob. 13.40PCh. 13.6 - Prob. 13.41PCh. 13.6 - Prob. 13.42PCh. 13.6 - Prob. 13.43PCh. 13.6 - Prob. 13.44PCh. 13.6 - Prob. 13.45PCh. 13.6 - Prob. 13.46PCh. 13.6 - Prob. 13.47PCh. 13.6 - Prob. 13.48PCh. 13.6 - Prob. 13.49PCh. 13.7 - Prob. 13.51PCh. 13.7 - Prob. 13.52PCh. 13.7 - Prob. 13.53PCh. 13.7 - Prob. 13.54PCh. 13.7 - Prob. 13.55PCh. 13.7 - Prob. 13.56PCh. 13.8 - Prob. 13.58PCh. 13.8 - Prob. 13.59PCh. 13.8 - Prob. 13.60PCh. 13.8 - Prob. 13.61PCh. 13.9 - Prob. 13.63PCh. 13.9 - Prob. 13.64PCh. 13.9 - Prob. 13.65PCh. 13.9 - Prob. 13.66PCh. 13.9 - Prob. 13.67PCh. 13.9 - Prob. 13.68PCh. 13.10 - Prob. 13.70PCh. 13.10 - Prob. 13.71P
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