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Concept explainers
Interpretation:
The reagent that has to be used for the given transformation must be identified.
Concept Introduction:
In a reaction if the oxidation state of the carbon atom is increased means, then oxidation reaction has occurred. Conversion of primary alcohol into an
In case of primary alcohol, if we use a very strong oxidizing agent, then the final product is carboxylic acid. If the alcohol taken is a secondary alcohol then the final product is a ketone. When primary alcohol is oxidized, first aldehyde is obtained and then it is further oxidized to carboxylic acid. In case, if we use a mild oxidizing agent, the aldehyde product can be obtained from primary alcohol.
Primary alcohol is oxidized to carboxylic acid by strong oxidizing agent like chromic acid.
In order to obtain aldehyde as a product from primary alcohol, a mild oxidizing agent is used like pyridinium chlorochromate (PCC).
Secondary alcohol on oxidation gives ketone as the product.
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Chapter 13 Solutions
Organic Chemistry As a Second Language: First Semester Topics
- X Draw the major products of the elimination reaction below. If elimination would not occur at a significant rate, check the box under the drawing area instead. ది www. Cl + OH Elimination will not occur at a significant rate. Click and drag to start drawing a structure.arrow_forwardNonearrow_forward1A H 2A Li Be Use the References to access important values if needed for this question. 8A 3A 4A 5A 6A 7A He B C N O F Ne Na Mg 3B 4B 5B 6B 7B 8B-1B 2B Al Si P 1B 2B Al Si P S Cl Ar K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe * Cs Ba La Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn Fr Ra Ac Rf Ha ****** Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr Analyze the following reaction by looking at the electron configurations given below each box. Put a number and a symbol in each box to show the number and kind of the corresponding atom or ion. Use the smallest integers possible. cation anion + + Shell 1: 2 Shell 2: 8 Shell 3: 1 Shell 1 : 2 Shell 2 : 6 Shell 1 : 2 Shell 2: 8 Shell 1: 2 Shell 2: 8arrow_forward
- Nonearrow_forwardIV. Show the detailed synthesis strategy for the following compounds. a. CH3CH2CH2CH2Br CH3CH2CCH2CH2CH3arrow_forwardDo the electrons on the OH participate in resonance with the ring through a p orbital? How many pi electrons are in the ring, 4 (from the two double bonds) or 6 (including the electrons on the O)?arrow_forward
- Predict and draw the product of the following organic reaction:arrow_forwardNonearrow_forwardRedraw the molecule below as a skeletal ("line") structure. Be sure to use wedge and dash bonds if necessary to accurately represent the direction of the bonds to ring substituents. Cl. Br Click and drag to start drawing a structure. : ☐ ☑ Parrow_forward
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