(a) Interpretation: The structure corresponding to 4-methyl-1-hexene should be given. Concept Introduction: Alkenes are named in the same way as alkanes , but the alkenes are identified by the suffix −ene, replaced instead of the ending of the name of the parent alkane. The longest carbon chain should be numbered in a way that gives the double bond the lower number. Then the compound should be named using the first number assigned to the double bond. The names of the substituents should be written first in the alphabetic order with their position on the chain.

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Answer 1

Question

Chapter 13.2, Problem 13.6P

Interpretation Introduction

(a)

Interpretation:

The structure corresponding to 4-methyl-1-hexene should be given.

Concept Introduction:

Alkenes are named in the same way as alkanes, but the alkenes are identified by the suffix −ene, replaced instead of the ending of the name of the parent alkane. The longest carbon chain should be numbered in a way that gives the double bond the lower number. Then the compound should be named using the first number assigned to the double bond. The names of the substituents should be written first in the alphabetic order with their position on the chain.

Interpretation Introduction

(b)

Interpretation:

The structure corresponding to 5-ethyl-2-methyl-2-heptene should be given.

Concept Introduction:

Alkenes are named in the same way as alkanes, but the alkenes are identified by the suffix −ene, replaced instead of the ending of the name of the parent alkane. The longest carbon chain should be numbered in a way that gives the double bond the lower number. Then the compound should be named using the first number assigned to the double bond. The names of the substituents should be written first in the alphabetic order with their position on the chain.

Interpretation Introduction

(c)

Interpretation:

The structure corresponding to 2,5-dimethyl-3-hexyne should be given.

Concept Introduction:

Alkynes are named in the same way as alkanes, but the alkynes are identified by the suffix −yne, replaced instead of the ending of the name of the parent alkane. The longest carbon chain should be numbered in a way that gives the triple bond the lower number. Then the compound should be named using the first number assigned to the triple bond. The names of the substituents should be written first in the alphabetic order with their position on the chain.

Interpretation Introduction

(d)

Interpretation:

The structure corresponding to 1-propylcyclobutene should be given.

Concept Introduction:

In the nomenclature of cycloalkenes, the double bond is always located between C-1 and C-2. And 1 is not mentioned in the name. The ring is then numbered in a way that the first substituent gets the lowest number.

Interpretation Introduction

(e)

Interpretation:

The structure corresponding to 1,3-cyclohexadiene should be given.

Concept Introduction:

In the nomenclature of cycloalkenes, the double bond is always located between C-1 and C-2. And 1 is not mentioned in the name. the ring is then numbered in a way that the first substituent getting the lowest number.

Interpretation Introduction

(f)

Interpretation:

The structure corresponding to 4-ethyl-1-decyne should be given.

Concept Introduction:

Alkynes are named in the same way as alkanes, but the alkynes are identified by the suffix −yne, replaced instead of the ending of the name of the parent alkane. The longest carbon chain should be numbered in a way that gives the triple bond the lower number. Then the compound should be named using the first number assigned to the triple bond. The names of the substituents should be written first in the alphabetic order with their position on the chain.

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For Raman spectroscopy/imaging, which statement is not true regarding its disadvantages? a) Limited spatial resolution. b) Short integration time. c) A one-dimensional technique. d) Weak signal, only 1 in 108 incident photons is Raman scattered. e) Fluorescence interference.

Using a cell of known pathlength b = 1.25115 x 10-3 cm, a water absorption spectrum was measured. The band at 1645 cm-1, assigned to the O-H bending, showed an absorbance, A, of 1.40. a) Assuming that water density is 1.00 g/mL, calculate the water molar concentration c (hint: M= mole/L) b) Calculate the molar absorptivity, a, of the 1645 cm-1 band c) The transmitted light, I, can be written as I= Ioexp(-xb), where x is the absorption coefficient (sometimes designated as alpha), Io is the input light, and b is the cell pathlength. Prove that x= (ln10)*x*c. (Please provide a full derivation of the equation for x from the equation for I). d) Calculate x for the 1645 cm-1 band

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Answer 2

Question

Chapter 13.2, Problem 13.6P

Interpretation Introduction

(a)

Interpretation:

The structure corresponding to 4-methyl-1-hexene should be given.

Concept Introduction:

Alkenes are named in the same way as alkanes, but the alkenes are identified by the suffix −ene, replaced instead of the ending of the name of the parent alkane. The longest carbon chain should be numbered in a way that gives the double bond the lower number. Then the compound should be named using the first number assigned to the double bond. The names of the substituents should be written first in the alphabetic order with their position on the chain.

Interpretation Introduction

(b)

Interpretation:

The structure corresponding to 5-ethyl-2-methyl-2-heptene should be given.

Concept Introduction:

Alkenes are named in the same way as alkanes, but the alkenes are identified by the suffix −ene, replaced instead of the ending of the name of the parent alkane. The longest carbon chain should be numbered in a way that gives the double bond the lower number. Then the compound should be named using the first number assigned to the double bond. The names of the substituents should be written first in the alphabetic order with their position on the chain.

Interpretation Introduction

(c)

Interpretation:

The structure corresponding to 2,5-dimethyl-3-hexyne should be given.

Concept Introduction:

Alkynes are named in the same way as alkanes, but the alkynes are identified by the suffix −yne, replaced instead of the ending of the name of the parent alkane. The longest carbon chain should be numbered in a way that gives the triple bond the lower number. Then the compound should be named using the first number assigned to the triple bond. The names of the substituents should be written first in the alphabetic order with their position on the chain.

Interpretation Introduction

(d)

Interpretation:

The structure corresponding to 1-propylcyclobutene should be given.

Concept Introduction:

In the nomenclature of cycloalkenes, the double bond is always located between C-1 and C-2. And 1 is not mentioned in the name. The ring is then numbered in a way that the first substituent gets the lowest number.

Interpretation Introduction

(e)

Interpretation:

The structure corresponding to 1,3-cyclohexadiene should be given.

Concept Introduction:

In the nomenclature of cycloalkenes, the double bond is always located between C-1 and C-2. And 1 is not mentioned in the name. the ring is then numbered in a way that the first substituent getting the lowest number.

Interpretation Introduction

(f)

Interpretation:

The structure corresponding to 4-ethyl-1-decyne should be given.

Concept Introduction:

Alkynes are named in the same way as alkanes, but the alkynes are identified by the suffix −yne, replaced instead of the ending of the name of the parent alkane. The longest carbon chain should be numbered in a way that gives the triple bond the lower number. Then the compound should be named using the first number assigned to the triple bond. The names of the substituents should be written first in the alphabetic order with their position on the chain.

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Answer 3

Question

Chapter 13.2, Problem 13.6P

Interpretation Introduction

(a)

Interpretation:

The structure corresponding to 4-methyl-1-hexene should be given.

Concept Introduction:

Alkenes are named in the same way as alkanes, but the alkenes are identified by the suffix −ene, replaced instead of the ending of the name of the parent alkane. The longest carbon chain should be numbered in a way that gives the double bond the lower number. Then the compound should be named using the first number assigned to the double bond. The names of the substituents should be written first in the alphabetic order with their position on the chain.

Interpretation Introduction

(b)

Interpretation:

The structure corresponding to 5-ethyl-2-methyl-2-heptene should be given.

Concept Introduction:

Alkenes are named in the same way as alkanes, but the alkenes are identified by the suffix −ene, replaced instead of the ending of the name of the parent alkane. The longest carbon chain should be numbered in a way that gives the double bond the lower number. Then the compound should be named using the first number assigned to the double bond. The names of the substituents should be written first in the alphabetic order with their position on the chain.

Interpretation Introduction

(c)

Interpretation:

The structure corresponding to 2,5-dimethyl-3-hexyne should be given.

Concept Introduction:

Alkynes are named in the same way as alkanes, but the alkynes are identified by the suffix −yne, replaced instead of the ending of the name of the parent alkane. The longest carbon chain should be numbered in a way that gives the triple bond the lower number. Then the compound should be named using the first number assigned to the triple bond. The names of the substituents should be written first in the alphabetic order with their position on the chain.

Interpretation Introduction

(d)

Interpretation:

The structure corresponding to 1-propylcyclobutene should be given.

Concept Introduction:

In the nomenclature of cycloalkenes, the double bond is always located between C-1 and C-2. And 1 is not mentioned in the name. The ring is then numbered in a way that the first substituent gets the lowest number.

Interpretation Introduction

(e)

Interpretation:

The structure corresponding to 1,3-cyclohexadiene should be given.

Concept Introduction:

In the nomenclature of cycloalkenes, the double bond is always located between C-1 and C-2. And 1 is not mentioned in the name. the ring is then numbered in a way that the first substituent getting the lowest number.

Interpretation Introduction

(f)

Interpretation:

The structure corresponding to 4-ethyl-1-decyne should be given.

Concept Introduction:

Alkynes are named in the same way as alkanes, but the alkynes are identified by the suffix −yne, replaced instead of the ending of the name of the parent alkane. The longest carbon chain should be numbered in a way that gives the triple bond the lower number. Then the compound should be named using the first number assigned to the triple bond. The names of the substituents should be written first in the alphabetic order with their position on the chain.

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Answer 4

Question

Chapter 13.2, Problem 13.6P

Interpretation Introduction

(a)

Interpretation:

The structure corresponding to 4-methyl-1-hexene should be given.

Concept Introduction:

Alkenes are named in the same way as alkanes, but the alkenes are identified by the suffix −ene, replaced instead of the ending of the name of the parent alkane. The longest carbon chain should be numbered in a way that gives the double bond the lower number. Then the compound should be named using the first number assigned to the double bond. The names of the substituents should be written first in the alphabetic order with their position on the chain.

Interpretation Introduction

(b)

Interpretation:

The structure corresponding to 5-ethyl-2-methyl-2-heptene should be given.

Concept Introduction:

Alkenes are named in the same way as alkanes, but the alkenes are identified by the suffix −ene, replaced instead of the ending of the name of the parent alkane. The longest carbon chain should be numbered in a way that gives the double bond the lower number. Then the compound should be named using the first number assigned to the double bond. The names of the substituents should be written first in the alphabetic order with their position on the chain.

Interpretation Introduction

(c)

Interpretation:

The structure corresponding to 2,5-dimethyl-3-hexyne should be given.

Concept Introduction:

Alkynes are named in the same way as alkanes, but the alkynes are identified by the suffix −yne, replaced instead of the ending of the name of the parent alkane. The longest carbon chain should be numbered in a way that gives the triple bond the lower number. Then the compound should be named using the first number assigned to the triple bond. The names of the substituents should be written first in the alphabetic order with their position on the chain.

Interpretation Introduction

(d)

Interpretation:

The structure corresponding to 1-propylcyclobutene should be given.

Concept Introduction:

In the nomenclature of cycloalkenes, the double bond is always located between C-1 and C-2. And 1 is not mentioned in the name. The ring is then numbered in a way that the first substituent gets the lowest number.

Interpretation Introduction

(e)

Interpretation:

The structure corresponding to 1,3-cyclohexadiene should be given.

Concept Introduction:

In the nomenclature of cycloalkenes, the double bond is always located between C-1 and C-2. And 1 is not mentioned in the name. the ring is then numbered in a way that the first substituent getting the lowest number.

Interpretation Introduction

(f)

Interpretation:

The structure corresponding to 4-ethyl-1-decyne should be given.

Concept Introduction:

Alkynes are named in the same way as alkanes, but the alkynes are identified by the suffix −yne, replaced instead of the ending of the name of the parent alkane. The longest carbon chain should be numbered in a way that gives the triple bond the lower number. Then the compound should be named using the first number assigned to the triple bond. The names of the substituents should be written first in the alphabetic order with their position on the chain.

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Answer 5

Chapter 13.2, Problem 13.6P

Interpretation Introduction

(a)

Interpretation:

The structure corresponding to 4-methyl-1-hexene should be given.

Concept Introduction:

Alkenes are named in the same way as alkanes, but the alkenes are identified by the suffix −ene, replaced instead of the ending of the name of the parent alkane. The longest carbon chain should be numbered in a way that gives the double bond the lower number. Then the compound should be named using the first number assigned to the double bond. The names of the substituents should be written first in the alphabetic order with their position on the chain.

Interpretation Introduction

(b)

Interpretation:

The structure corresponding to 5-ethyl-2-methyl-2-heptene should be given.

Concept Introduction:

Alkenes are named in the same way as alkanes, but the alkenes are identified by the suffix −ene, replaced instead of the ending of the name of the parent alkane. The longest carbon chain should be numbered in a way that gives the double bond the lower number. Then the compound should be named using the first number assigned to the double bond. The names of the substituents should be written first in the alphabetic order with their position on the chain.

Interpretation Introduction

(c)

Interpretation:

The structure corresponding to 2,5-dimethyl-3-hexyne should be given.

Concept Introduction:

Alkynes are named in the same way as alkanes, but the alkynes are identified by the suffix −yne, replaced instead of the ending of the name of the parent alkane. The longest carbon chain should be numbered in a way that gives the triple bond the lower number. Then the compound should be named using the first number assigned to the triple bond. The names of the substituents should be written first in the alphabetic order with their position on the chain.

Interpretation Introduction

(d)

Interpretation:

The structure corresponding to 1-propylcyclobutene should be given.

Concept Introduction:

In the nomenclature of cycloalkenes, the double bond is always located between C-1 and C-2. And 1 is not mentioned in the name. The ring is then numbered in a way that the first substituent gets the lowest number.

Interpretation Introduction

(e)

Interpretation:

The structure corresponding to 1,3-cyclohexadiene should be given.

Concept Introduction:

In the nomenclature of cycloalkenes, the double bond is always located between C-1 and C-2. And 1 is not mentioned in the name. the ring is then numbered in a way that the first substituent getting the lowest number.

Interpretation Introduction

(f)

Interpretation:

The structure corresponding to 4-ethyl-1-decyne should be given.

Concept Introduction:

Alkynes are named in the same way as alkanes, but the alkynes are identified by the suffix −yne, replaced instead of the ending of the name of the parent alkane. The longest carbon chain should be numbered in a way that gives the triple bond the lower number. Then the compound should be named using the first number assigned to the triple bond. The names of the substituents should be written first in the alphabetic order with their position on the chain.

Answer 6

Chapter 13.2, Problem 13.6P

Interpretation Introduction

(a)

Interpretation:

The structure corresponding to 4-methyl-1-hexene should be given.

Concept Introduction:

Alkenes are named in the same way as alkanes, but the alkenes are identified by the suffix −ene, replaced instead of the ending of the name of the parent alkane. The longest carbon chain should be numbered in a way that gives the double bond the lower number. Then the compound should be named using the first number assigned to the double bond. The names of the substituents should be written first in the alphabetic order with their position on the chain.

Answer 7

Chapter 13.2, Problem 13.6P

Interpretation Introduction

(a)

Interpretation:

The structure corresponding to 4-methyl-1-hexene should be given.

Concept Introduction:

Alkenes are named in the same way as alkanes, but the alkenes are identified by the suffix −ene, replaced instead of the ending of the name of the parent alkane. The longest carbon chain should be numbered in a way that gives the double bond the lower number. Then the compound should be named using the first number assigned to the double bond. The names of the substituents should be written first in the alphabetic order with their position on the chain.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The structure corresponding to 5-ethyl-2-methyl-2-heptene should be given.

Concept Introduction:

Alkenes are named in the same way as alkanes, but the alkenes are identified by the suffix −ene, replaced instead of the ending of the name of the parent alkane. The longest carbon chain should be numbered in a way that gives the double bond the lower number. Then the compound should be named using the first number assigned to the double bond. The names of the substituents should be written first in the alphabetic order with their position on the chain.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The structure corresponding to 5-ethyl-2-methyl-2-heptene should be given.

Concept Introduction:

Alkenes are named in the same way as alkanes, but the alkenes are identified by the suffix −ene, replaced instead of the ending of the name of the parent alkane. The longest carbon chain should be numbered in a way that gives the double bond the lower number. Then the compound should be named using the first number assigned to the double bond. The names of the substituents should be written first in the alphabetic order with their position on the chain.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The structure corresponding to 2,5-dimethyl-3-hexyne should be given.

Concept Introduction:

Alkynes are named in the same way as alkanes, but the alkynes are identified by the suffix −yne, replaced instead of the ending of the name of the parent alkane. The longest carbon chain should be numbered in a way that gives the triple bond the lower number. Then the compound should be named using the first number assigned to the triple bond. The names of the substituents should be written first in the alphabetic order with their position on the chain.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The structure corresponding to 2,5-dimethyl-3-hexyne should be given.

Concept Introduction:

Alkynes are named in the same way as alkanes, but the alkynes are identified by the suffix −yne, replaced instead of the ending of the name of the parent alkane. The longest carbon chain should be numbered in a way that gives the triple bond the lower number. Then the compound should be named using the first number assigned to the triple bond. The names of the substituents should be written first in the alphabetic order with their position on the chain.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The structure corresponding to 1-propylcyclobutene should be given.

Concept Introduction:

In the nomenclature of cycloalkenes, the double bond is always located between C-1 and C-2. And 1 is not mentioned in the name. The ring is then numbered in a way that the first substituent gets the lowest number.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The structure corresponding to 1-propylcyclobutene should be given.

Concept Introduction:

In the nomenclature of cycloalkenes, the double bond is always located between C-1 and C-2. And 1 is not mentioned in the name. The ring is then numbered in a way that the first substituent gets the lowest number.

Answer 14

Interpretation Introduction

(e)

Interpretation:

The structure corresponding to 1,3-cyclohexadiene should be given.

Concept Introduction:

In the nomenclature of cycloalkenes, the double bond is always located between C-1 and C-2. And 1 is not mentioned in the name. the ring is then numbered in a way that the first substituent getting the lowest number.

Answer 15

Interpretation Introduction

(e)

Interpretation:

The structure corresponding to 1,3-cyclohexadiene should be given.

Concept Introduction:

In the nomenclature of cycloalkenes, the double bond is always located between C-1 and C-2. And 1 is not mentioned in the name. the ring is then numbered in a way that the first substituent getting the lowest number.

Answer 16

Interpretation Introduction

(f)

Interpretation:

The structure corresponding to 4-ethyl-1-decyne should be given.

Concept Introduction:

Alkynes are named in the same way as alkanes, but the alkynes are identified by the suffix −yne, replaced instead of the ending of the name of the parent alkane. The longest carbon chain should be numbered in a way that gives the triple bond the lower number. Then the compound should be named using the first number assigned to the triple bond. The names of the substituents should be written first in the alphabetic order with their position on the chain.

Answer 17

Interpretation Introduction

(f)

Interpretation:

The structure corresponding to 4-ethyl-1-decyne should be given.

Concept Introduction:

Alkynes are named in the same way as alkanes, but the alkynes are identified by the suffix −yne, replaced instead of the ending of the name of the parent alkane. The longest carbon chain should be numbered in a way that gives the triple bond the lower number. Then the compound should be named using the first number assigned to the triple bond. The names of the substituents should be written first in the alphabetic order with their position on the chain.

Answer 18

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Answer 19

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Answer 20

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Answer 21

Ch. 13.1 - Convert each condensed structure to a complete...Ch. 13.1 - Prob. 13.2P Ch. 13.1 - Complete the structure of zingiberene, a component...Ch. 13.2 - Prob. 13.4P Ch. 13.2 - Prob. 13.5P Ch. 13.2 - Prob. 13.6P Ch. 13.3 - Prob. 13.7P Ch. 13.3 - Prob. 13.8P Ch. 13.3 - Prob. 13.9P Ch. 13.3 - Prob. 13.10P

Solution Summary: The author explains the structure corresponding to 4-methyl-1-hexene and 5-ethyl-2-methyl-2 heptene. The names of the substituents should be written first in the alphabetic order

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