(a) Interpretation: The product formed when p-dichlorobenzene is treated with Cl 2 in the presence of FeCl 3 should be determined. Concept Introduction: The electrophilic substitution reactions are the most common reactions of aromatic compounds . It involves the substitution of one of the H atom of aromatic ring with electrophile. It leads to the formation of arenium ion as an intermediate which immediately loses hydrogen ion to form the substituted product. These reactions occur in the presence of certain catalyst like FeCl 3 for halogenation, H 2 SO 4 for nitration, AlCl 3 for alkylation and acylation. These catalystsare involved in the formation of electrophile which further reacts with benzene ring to form a substituted product.

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Answer 1

Question

Chapter 13.13, Problem 13.27P

Interpretation Introduction

(a)

Interpretation:

The product formed when p-dichlorobenzene is treated with Cl2 in the presence of FeCl3 should be determined.

Concept Introduction:

The electrophilic substitution reactions are the most common reactions of aromatic compounds. It involves the substitution of one of the H atom of aromatic ring with electrophile. It leads to the formation of arenium ion as an intermediate which immediately loses hydrogen ion to form the substituted product.

These reactions occur in the presence of certain catalyst like FeCl3 for halogenation, H2SO4 for nitration, AlCl3 for alkylation and acylation. These catalystsare involved in the formation of electrophile which further reacts with benzene ring to form a substituted product.

Interpretation Introduction

(b)

Interpretation:

The product formed when p-dichlorobenzene is treated with HNO3 in the presence of H2SO4 should be determined.

Concept Introduction:

The electrophilic substitution reactions are the most common reactions of aromatic compounds. It involves the substitution of one of the H atom of aromatic ring with electrophile. It leads to the formation of arenium ion as an intermediate which immediately loses hydrogen ion to form the substituted product.

These reactions occur in the presence of certain catalyst like FeCl3 for halogenation, H2SO4 for nitration, AlCl3 for alkylation and acylation. These catalysts are involved in the formation of electrophile which further reacts with benzene ring to form a substituted product.

Interpretation Introduction

(c)

Interpretation:

The product formed when p-dichlorobenzene is treated with SO3 in the presence of H2SO4 should be determined.

Concept Introduction:

The electrophilic substitution reactions are the most common reactions of aromatic compounds. It involves the substitution of one of the H atom of aromatic ring with electrophile. It leads to the formation of arenium ion as an intermediate which immediately loses hydrogen ion to form the substituted product.

These reactions occur in the presence of certain catalyst like FeCl3 for halogenation, H2SO4 for nitration, AlCl3 for alkylation and acylation. These catalysts are involved in the formation of electrophile which further reacts with benzene ring to form a substituted product.

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Answer 2

Question

Chapter 13.13, Problem 13.27P

Interpretation Introduction

(a)

Interpretation:

The product formed when p-dichlorobenzene is treated with Cl2 in the presence of FeCl3 should be determined.

Concept Introduction:

The electrophilic substitution reactions are the most common reactions of aromatic compounds. It involves the substitution of one of the H atom of aromatic ring with electrophile. It leads to the formation of arenium ion as an intermediate which immediately loses hydrogen ion to form the substituted product.

These reactions occur in the presence of certain catalyst like FeCl3 for halogenation, H2SO4 for nitration, AlCl3 for alkylation and acylation. These catalystsare involved in the formation of electrophile which further reacts with benzene ring to form a substituted product.

Interpretation Introduction

(b)

Interpretation:

The product formed when p-dichlorobenzene is treated with HNO3 in the presence of H2SO4 should be determined.

Concept Introduction:

The electrophilic substitution reactions are the most common reactions of aromatic compounds. It involves the substitution of one of the H atom of aromatic ring with electrophile. It leads to the formation of arenium ion as an intermediate which immediately loses hydrogen ion to form the substituted product.

These reactions occur in the presence of certain catalyst like FeCl3 for halogenation, H2SO4 for nitration, AlCl3 for alkylation and acylation. These catalysts are involved in the formation of electrophile which further reacts with benzene ring to form a substituted product.

Interpretation Introduction

(c)

Interpretation:

The product formed when p-dichlorobenzene is treated with SO3 in the presence of H2SO4 should be determined.

Concept Introduction:

The electrophilic substitution reactions are the most common reactions of aromatic compounds. It involves the substitution of one of the H atom of aromatic ring with electrophile. It leads to the formation of arenium ion as an intermediate which immediately loses hydrogen ion to form the substituted product.

These reactions occur in the presence of certain catalyst like FeCl3 for halogenation, H2SO4 for nitration, AlCl3 for alkylation and acylation. These catalysts are involved in the formation of electrophile which further reacts with benzene ring to form a substituted product.

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Answer 3

Question

Chapter 13.13, Problem 13.27P

Interpretation Introduction

(a)

Interpretation:

The product formed when p-dichlorobenzene is treated with Cl2 in the presence of FeCl3 should be determined.

Concept Introduction:

The electrophilic substitution reactions are the most common reactions of aromatic compounds. It involves the substitution of one of the H atom of aromatic ring with electrophile. It leads to the formation of arenium ion as an intermediate which immediately loses hydrogen ion to form the substituted product.

These reactions occur in the presence of certain catalyst like FeCl3 for halogenation, H2SO4 for nitration, AlCl3 for alkylation and acylation. These catalystsare involved in the formation of electrophile which further reacts with benzene ring to form a substituted product.

Interpretation Introduction

(b)

Interpretation:

The product formed when p-dichlorobenzene is treated with HNO3 in the presence of H2SO4 should be determined.

Concept Introduction:

The electrophilic substitution reactions are the most common reactions of aromatic compounds. It involves the substitution of one of the H atom of aromatic ring with electrophile. It leads to the formation of arenium ion as an intermediate which immediately loses hydrogen ion to form the substituted product.

These reactions occur in the presence of certain catalyst like FeCl3 for halogenation, H2SO4 for nitration, AlCl3 for alkylation and acylation. These catalysts are involved in the formation of electrophile which further reacts with benzene ring to form a substituted product.

Interpretation Introduction

(c)

Interpretation:

The product formed when p-dichlorobenzene is treated with SO3 in the presence of H2SO4 should be determined.

Concept Introduction:

The electrophilic substitution reactions are the most common reactions of aromatic compounds. It involves the substitution of one of the H atom of aromatic ring with electrophile. It leads to the formation of arenium ion as an intermediate which immediately loses hydrogen ion to form the substituted product.

These reactions occur in the presence of certain catalyst like FeCl3 for halogenation, H2SO4 for nitration, AlCl3 for alkylation and acylation. These catalysts are involved in the formation of electrophile which further reacts with benzene ring to form a substituted product.

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Answer 4

Question

Chapter 13.13, Problem 13.27P

Interpretation Introduction

(a)

Interpretation:

The product formed when p-dichlorobenzene is treated with Cl2 in the presence of FeCl3 should be determined.

Concept Introduction:

The electrophilic substitution reactions are the most common reactions of aromatic compounds. It involves the substitution of one of the H atom of aromatic ring with electrophile. It leads to the formation of arenium ion as an intermediate which immediately loses hydrogen ion to form the substituted product.

These reactions occur in the presence of certain catalyst like FeCl3 for halogenation, H2SO4 for nitration, AlCl3 for alkylation and acylation. These catalystsare involved in the formation of electrophile which further reacts with benzene ring to form a substituted product.

Interpretation Introduction

(b)

Interpretation:

The product formed when p-dichlorobenzene is treated with HNO3 in the presence of H2SO4 should be determined.

Concept Introduction:

The electrophilic substitution reactions are the most common reactions of aromatic compounds. It involves the substitution of one of the H atom of aromatic ring with electrophile. It leads to the formation of arenium ion as an intermediate which immediately loses hydrogen ion to form the substituted product.

These reactions occur in the presence of certain catalyst like FeCl3 for halogenation, H2SO4 for nitration, AlCl3 for alkylation and acylation. These catalysts are involved in the formation of electrophile which further reacts with benzene ring to form a substituted product.

Interpretation Introduction

(c)

Interpretation:

The product formed when p-dichlorobenzene is treated with SO3 in the presence of H2SO4 should be determined.

Concept Introduction:

The electrophilic substitution reactions are the most common reactions of aromatic compounds. It involves the substitution of one of the H atom of aromatic ring with electrophile. It leads to the formation of arenium ion as an intermediate which immediately loses hydrogen ion to form the substituted product.

These reactions occur in the presence of certain catalyst like FeCl3 for halogenation, H2SO4 for nitration, AlCl3 for alkylation and acylation. These catalysts are involved in the formation of electrophile which further reacts with benzene ring to form a substituted product.

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Answer 5

Chapter 13.13, Problem 13.27P

Interpretation Introduction

(a)

Interpretation:

The product formed when p-dichlorobenzene is treated with Cl2 in the presence of FeCl3 should be determined.

Concept Introduction:

The electrophilic substitution reactions are the most common reactions of aromatic compounds. It involves the substitution of one of the H atom of aromatic ring with electrophile. It leads to the formation of arenium ion as an intermediate which immediately loses hydrogen ion to form the substituted product.

These reactions occur in the presence of certain catalyst like FeCl3 for halogenation, H2SO4 for nitration, AlCl3 for alkylation and acylation. These catalystsare involved in the formation of electrophile which further reacts with benzene ring to form a substituted product.

Interpretation Introduction

(b)

Interpretation:

The product formed when p-dichlorobenzene is treated with HNO3 in the presence of H2SO4 should be determined.

Concept Introduction:

The electrophilic substitution reactions are the most common reactions of aromatic compounds. It involves the substitution of one of the H atom of aromatic ring with electrophile. It leads to the formation of arenium ion as an intermediate which immediately loses hydrogen ion to form the substituted product.

These reactions occur in the presence of certain catalyst like FeCl3 for halogenation, H2SO4 for nitration, AlCl3 for alkylation and acylation. These catalysts are involved in the formation of electrophile which further reacts with benzene ring to form a substituted product.

Interpretation Introduction

(c)

Interpretation:

The product formed when p-dichlorobenzene is treated with SO3 in the presence of H2SO4 should be determined.

Concept Introduction:

The electrophilic substitution reactions are the most common reactions of aromatic compounds. It involves the substitution of one of the H atom of aromatic ring with electrophile. It leads to the formation of arenium ion as an intermediate which immediately loses hydrogen ion to form the substituted product.

These reactions occur in the presence of certain catalyst like FeCl3 for halogenation, H2SO4 for nitration, AlCl3 for alkylation and acylation. These catalysts are involved in the formation of electrophile which further reacts with benzene ring to form a substituted product.

Answer 6

Chapter 13.13, Problem 13.27P

Interpretation Introduction

(a)

Interpretation:

The product formed when p-dichlorobenzene is treated with Cl2 in the presence of FeCl3 should be determined.

Concept Introduction:

The electrophilic substitution reactions are the most common reactions of aromatic compounds. It involves the substitution of one of the H atom of aromatic ring with electrophile. It leads to the formation of arenium ion as an intermediate which immediately loses hydrogen ion to form the substituted product.

These reactions occur in the presence of certain catalyst like FeCl3 for halogenation, H2SO4 for nitration, AlCl3 for alkylation and acylation. These catalystsare involved in the formation of electrophile which further reacts with benzene ring to form a substituted product.

Answer 7

Chapter 13.13, Problem 13.27P

Interpretation Introduction

(a)

Interpretation:

The product formed when p-dichlorobenzene is treated with Cl2 in the presence of FeCl3 should be determined.

Concept Introduction:

The electrophilic substitution reactions are the most common reactions of aromatic compounds. It involves the substitution of one of the H atom of aromatic ring with electrophile. It leads to the formation of arenium ion as an intermediate which immediately loses hydrogen ion to form the substituted product.

These reactions occur in the presence of certain catalyst like FeCl3 for halogenation, H2SO4 for nitration, AlCl3 for alkylation and acylation. These catalystsare involved in the formation of electrophile which further reacts with benzene ring to form a substituted product.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The product formed when p-dichlorobenzene is treated with HNO3 in the presence of H2SO4 should be determined.

Concept Introduction:

The electrophilic substitution reactions are the most common reactions of aromatic compounds. It involves the substitution of one of the H atom of aromatic ring with electrophile. It leads to the formation of arenium ion as an intermediate which immediately loses hydrogen ion to form the substituted product.

These reactions occur in the presence of certain catalyst like FeCl3 for halogenation, H2SO4 for nitration, AlCl3 for alkylation and acylation. These catalysts are involved in the formation of electrophile which further reacts with benzene ring to form a substituted product.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The product formed when p-dichlorobenzene is treated with HNO3 in the presence of H2SO4 should be determined.

Concept Introduction:

The electrophilic substitution reactions are the most common reactions of aromatic compounds. It involves the substitution of one of the H atom of aromatic ring with electrophile. It leads to the formation of arenium ion as an intermediate which immediately loses hydrogen ion to form the substituted product.

These reactions occur in the presence of certain catalyst like FeCl3 for halogenation, H2SO4 for nitration, AlCl3 for alkylation and acylation. These catalysts are involved in the formation of electrophile which further reacts with benzene ring to form a substituted product.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The product formed when p-dichlorobenzene is treated with SO3 in the presence of H2SO4 should be determined.

Concept Introduction:

The electrophilic substitution reactions are the most common reactions of aromatic compounds. It involves the substitution of one of the H atom of aromatic ring with electrophile. It leads to the formation of arenium ion as an intermediate which immediately loses hydrogen ion to form the substituted product.

These reactions occur in the presence of certain catalyst like FeCl3 for halogenation, H2SO4 for nitration, AlCl3 for alkylation and acylation. These catalysts are involved in the formation of electrophile which further reacts with benzene ring to form a substituted product.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The product formed when p-dichlorobenzene is treated with SO3 in the presence of H2SO4 should be determined.

Concept Introduction:

The electrophilic substitution reactions are the most common reactions of aromatic compounds. It involves the substitution of one of the H atom of aromatic ring with electrophile. It leads to the formation of arenium ion as an intermediate which immediately loses hydrogen ion to form the substituted product.

These reactions occur in the presence of certain catalyst like FeCl3 for halogenation, H2SO4 for nitration, AlCl3 for alkylation and acylation. These catalysts are involved in the formation of electrophile which further reacts with benzene ring to form a substituted product.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 13.1 - Convert each condensed structure to a complete...Ch. 13.1 - Prob. 13.2P Ch. 13.1 - Complete the structure of zingiberene, a component...Ch. 13.2 - Prob. 13.4P Ch. 13.2 - Prob. 13.5P Ch. 13.2 - Prob. 13.6P Ch. 13.3 - Prob. 13.7P Ch. 13.3 - Prob. 13.8P Ch. 13.3 - Prob. 13.9P Ch. 13.3 - Prob. 13.10P

Solution Summary: The author explains that electrophilic substitution reactions are the most common reactions of aromatic compounds.

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