(a) Interpretation: The product formed when p-xylene is treated with Cl 2 , FeCl 3 needs to be identified. Concept Introduction: Aromatic compoundsundergo substitution reactions in which one of the hydrogen in the benzene ring is replaced by another atom or groups. Chlorination, nitration, and sulfonation are common substitution reactions wherein one of the H atoms is replaced by a -Cl, -NO 2 or -SO 3 H group, respectively.

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Answer 1

Question

Chapter 13, Problem 13.85P

Interpretation Introduction

(a)

Interpretation:

The product formed when p-xylene is treated with Cl₂, FeCl₃ needs to be identified.

Concept Introduction:

Aromatic compoundsundergo substitution reactions in which one of the hydrogen in the benzene ring is replaced by another atom or groups.

Chlorination, nitration, and sulfonation are common substitution reactions wherein one of the H atoms is replaced by a -Cl, -NO₂ or -SO₃H group, respectively.

Interpretation Introduction

(b)

Interpretation:

The product formed when p-xylene is treated with HNO₃, H₂SO₄ needs to be identified.

Concept Introduction:

Aromatic compounds undergo substitution reactions in which one of thehydrogens in the benzene ring is replaced by another atom or groups.

Chlorination, nitration, and sulfonation are common substitution reactions wherein one of the H atoms is replaced by a -Cl, -NO₂ or -SO₃H group, respectively.

Interpretation Introduction

(c)

Interpretation:

The product formed when p-xylene is treated with SO₃, H₂SO₄ needs to be identified.

Concept Introduction:

Aromatic compounds undergo substitution reactions in which one of the hydrogen in the benzene ring is replaced by another atom or groups.

Chlorination, nitration, and sulfonation are common substitution reactions wherein one of the H atoms is replaced by a -Cl, -NO₂ or -SO₃H group respectively.

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Using a cell of known pathlength b = 1.25115 x 10-3 cm, a water absorption spectrum was measured. The band at 1645 cm-1, assigned to the O-H bending, showed an absorbance, A, of 1.40. a) Assuming that water density is 1.00 g/mL, calculate the water molar concentration c (hint: M= mole/L) b) Calculate the molar absorptivity, a, of the 1645 cm-1 band c) The transmitted light, I, can be written as I= Ioexp(-xb), where x is the absorption coefficient (sometimes designated as alpha), Io is the input light, and b is the cell pathlength. Prove that x= (ln10)*x*c d) Calculate x for the 1645 cm-1 band

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Answer 2

Question

Chapter 13, Problem 13.85P

Interpretation Introduction

(a)

Interpretation:

The product formed when p-xylene is treated with Cl₂, FeCl₃ needs to be identified.

Concept Introduction:

Aromatic compoundsundergo substitution reactions in which one of the hydrogen in the benzene ring is replaced by another atom or groups.

Chlorination, nitration, and sulfonation are common substitution reactions wherein one of the H atoms is replaced by a -Cl, -NO₂ or -SO₃H group, respectively.

Interpretation Introduction

(b)

Interpretation:

The product formed when p-xylene is treated with HNO₃, H₂SO₄ needs to be identified.

Concept Introduction:

Aromatic compounds undergo substitution reactions in which one of thehydrogens in the benzene ring is replaced by another atom or groups.

Chlorination, nitration, and sulfonation are common substitution reactions wherein one of the H atoms is replaced by a -Cl, -NO₂ or -SO₃H group, respectively.

Interpretation Introduction

(c)

Interpretation:

The product formed when p-xylene is treated with SO₃, H₂SO₄ needs to be identified.

Concept Introduction:

Aromatic compounds undergo substitution reactions in which one of the hydrogen in the benzene ring is replaced by another atom or groups.

Chlorination, nitration, and sulfonation are common substitution reactions wherein one of the H atoms is replaced by a -Cl, -NO₂ or -SO₃H group respectively.

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Answer 3

Question

Chapter 13, Problem 13.85P

Interpretation Introduction

(a)

Interpretation:

The product formed when p-xylene is treated with Cl₂, FeCl₃ needs to be identified.

Concept Introduction:

Aromatic compoundsundergo substitution reactions in which one of the hydrogen in the benzene ring is replaced by another atom or groups.

Chlorination, nitration, and sulfonation are common substitution reactions wherein one of the H atoms is replaced by a -Cl, -NO₂ or -SO₃H group, respectively.

Interpretation Introduction

(b)

Interpretation:

The product formed when p-xylene is treated with HNO₃, H₂SO₄ needs to be identified.

Concept Introduction:

Aromatic compounds undergo substitution reactions in which one of thehydrogens in the benzene ring is replaced by another atom or groups.

Chlorination, nitration, and sulfonation are common substitution reactions wherein one of the H atoms is replaced by a -Cl, -NO₂ or -SO₃H group, respectively.

Interpretation Introduction

(c)

Interpretation:

The product formed when p-xylene is treated with SO₃, H₂SO₄ needs to be identified.

Concept Introduction:

Aromatic compounds undergo substitution reactions in which one of the hydrogen in the benzene ring is replaced by another atom or groups.

Chlorination, nitration, and sulfonation are common substitution reactions wherein one of the H atoms is replaced by a -Cl, -NO₂ or -SO₃H group respectively.

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Answer 4

Question

Chapter 13, Problem 13.85P

Interpretation Introduction

(a)

Interpretation:

The product formed when p-xylene is treated with Cl₂, FeCl₃ needs to be identified.

Concept Introduction:

Aromatic compoundsundergo substitution reactions in which one of the hydrogen in the benzene ring is replaced by another atom or groups.

Chlorination, nitration, and sulfonation are common substitution reactions wherein one of the H atoms is replaced by a -Cl, -NO₂ or -SO₃H group, respectively.

Interpretation Introduction

(b)

Interpretation:

The product formed when p-xylene is treated with HNO₃, H₂SO₄ needs to be identified.

Concept Introduction:

Aromatic compounds undergo substitution reactions in which one of thehydrogens in the benzene ring is replaced by another atom or groups.

Chlorination, nitration, and sulfonation are common substitution reactions wherein one of the H atoms is replaced by a -Cl, -NO₂ or -SO₃H group, respectively.

Interpretation Introduction

(c)

Interpretation:

The product formed when p-xylene is treated with SO₃, H₂SO₄ needs to be identified.

Concept Introduction:

Aromatic compounds undergo substitution reactions in which one of the hydrogen in the benzene ring is replaced by another atom or groups.

Chlorination, nitration, and sulfonation are common substitution reactions wherein one of the H atoms is replaced by a -Cl, -NO₂ or -SO₃H group respectively.

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Answer 5

Chapter 13, Problem 13.85P

Interpretation Introduction

(a)

Interpretation:

The product formed when p-xylene is treated with Cl₂, FeCl₃ needs to be identified.

Concept Introduction:

Aromatic compoundsundergo substitution reactions in which one of the hydrogen in the benzene ring is replaced by another atom or groups.

Chlorination, nitration, and sulfonation are common substitution reactions wherein one of the H atoms is replaced by a -Cl, -NO₂ or -SO₃H group, respectively.

Interpretation Introduction

(b)

Interpretation:

The product formed when p-xylene is treated with HNO₃, H₂SO₄ needs to be identified.

Concept Introduction:

Aromatic compounds undergo substitution reactions in which one of thehydrogens in the benzene ring is replaced by another atom or groups.

Chlorination, nitration, and sulfonation are common substitution reactions wherein one of the H atoms is replaced by a -Cl, -NO₂ or -SO₃H group, respectively.

Interpretation Introduction

(c)

Interpretation:

The product formed when p-xylene is treated with SO₃, H₂SO₄ needs to be identified.

Concept Introduction:

Aromatic compounds undergo substitution reactions in which one of the hydrogen in the benzene ring is replaced by another atom or groups.

Chlorination, nitration, and sulfonation are common substitution reactions wherein one of the H atoms is replaced by a -Cl, -NO₂ or -SO₃H group respectively.

Answer 6

Chapter 13, Problem 13.85P

Interpretation Introduction

(a)

Interpretation:

The product formed when p-xylene is treated with Cl₂, FeCl₃ needs to be identified.

Concept Introduction:

Aromatic compoundsundergo substitution reactions in which one of the hydrogen in the benzene ring is replaced by another atom or groups.

Chlorination, nitration, and sulfonation are common substitution reactions wherein one of the H atoms is replaced by a -Cl, -NO₂ or -SO₃H group, respectively.

Answer 7

Chapter 13, Problem 13.85P

Interpretation Introduction

(a)

Interpretation:

The product formed when p-xylene is treated with Cl₂, FeCl₃ needs to be identified.

Concept Introduction:

Aromatic compoundsundergo substitution reactions in which one of the hydrogen in the benzene ring is replaced by another atom or groups.

Chlorination, nitration, and sulfonation are common substitution reactions wherein one of the H atoms is replaced by a -Cl, -NO₂ or -SO₃H group, respectively.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The product formed when p-xylene is treated with HNO₃, H₂SO₄ needs to be identified.

Concept Introduction:

Aromatic compounds undergo substitution reactions in which one of thehydrogens in the benzene ring is replaced by another atom or groups.

Chlorination, nitration, and sulfonation are common substitution reactions wherein one of the H atoms is replaced by a -Cl, -NO₂ or -SO₃H group, respectively.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The product formed when p-xylene is treated with HNO₃, H₂SO₄ needs to be identified.

Concept Introduction:

Aromatic compounds undergo substitution reactions in which one of thehydrogens in the benzene ring is replaced by another atom or groups.

Chlorination, nitration, and sulfonation are common substitution reactions wherein one of the H atoms is replaced by a -Cl, -NO₂ or -SO₃H group, respectively.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The product formed when p-xylene is treated with SO₃, H₂SO₄ needs to be identified.

Concept Introduction:

Aromatic compounds undergo substitution reactions in which one of the hydrogen in the benzene ring is replaced by another atom or groups.

Chlorination, nitration, and sulfonation are common substitution reactions wherein one of the H atoms is replaced by a -Cl, -NO₂ or -SO₃H group respectively.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The product formed when p-xylene is treated with SO₃, H₂SO₄ needs to be identified.

Concept Introduction:

Aromatic compounds undergo substitution reactions in which one of the hydrogen in the benzene ring is replaced by another atom or groups.

Chlorination, nitration, and sulfonation are common substitution reactions wherein one of the H atoms is replaced by a -Cl, -NO₂ or -SO₃H group respectively.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 13.1 - Convert each condensed structure to a complete...Ch. 13.1 - Prob. 13.2P Ch. 13.1 - Complete the structure of zingiberene, a component...Ch. 13.2 - Prob. 13.4P Ch. 13.2 - Prob. 13.5P Ch. 13.2 - Prob. 13.6P Ch. 13.3 - Prob. 13.7P Ch. 13.3 - Prob. 13.8P Ch. 13.3 - Prob. 13.9P Ch. 13.3 - Prob. 13.10P

Solution Summary: The author explains that aromatic compounds undergo substitution reactions in which one of thehydrogens in the benzene ring is replaced by another atom or groups.

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Chapter 13 Solutions