ORGANIC CHEMISTRY-PACKAGE >CUSTOM<
ORGANIC CHEMISTRY-PACKAGE >CUSTOM<
10th Edition
ISBN: 9781260028355
Author: Carey
Publisher: MCG CUSTOM
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Chapter 13.15, Problem 20P
Interpretation Introduction

Interpretation:

The reaction mechanism for a reaction between 4-chloro-N-methylaniline and bromine is to be written.

Concept Introduction:

Amines are very strongly activating groups because the lone pair of nitrogen can delocalize on the ring and they are ortho/para directing.

Chlorine atom in electrophilic aromatic substitution act as weakly deactivating and it is ortho/para directing.

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Questions 4 and 5
For a titration of 40.00 mL of 0.0500 M oxalic acid H2C2O4 with 0.1000 M KOH, calculate the pH at each of the following volume of KOH used in the titration: 1) before the titration begin;2) 15 mL; 3) 20 mL; 4) 25 mL; 5) 40 mL; 6) 50 mL. Ka1 = 5.90×10^-2, Ka2 = 6.50×10^-5 for oxalic acid.
Predict the major organic product(s), if any, of the following reactions.  Assume all reagents are in excess unless otherwise indicated.

Chapter 13 Solutions

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