Interpretation The reasons why methanol and ethanol are soluble in water whereas octanol is poorly soluble have to be determined. Concept introduction: ‘Like dissolves like’ principle said that polar compounds including ionic compound should be more soluble in polar solvent. Likewise, non-polar compound should be more soluble in non-polar solvent. Other hand, compounds with similar intermolecular force capability to soluble in one another because solute-solvent interactions are similar signification to the solute-solute interaction. ‘ The set of repulsive and attractive force between molecules that result from the polarity between neighboring molecules is represented as intermolecular force. There are four types of intermolecular forces: Hydrogen bonding London dispersion force Ion – dipole force Dipole – Dipole force Hydrogen bond: Hydrogen is bonded to strong electronegative atom like oxygen, nitrogen etc.

Question

Please draw the structure in the box that is consistent with all the spectral data and alphabetically label all of the equivalent protons in the structure (Ha, Hb, Hc....) in order to assign all the proton NMR peaks. The integrations are computer generated and approximate the number of equivalent protons. Molecular formula: C13H1802 14 13 12 11 10 11 (ppm) Structure with assigned H peaks 2.08 3.13

Answer 1

Question

Chapter 13, Problem 98SCQ

Interpretation Introduction

Interpretation The reasons why methanol and ethanol are soluble in water whereas octanol is poorly soluble have to be determined.

Concept introduction:

‘Like dissolves like’ principle said that polar compounds including ionic compound should be more soluble in polar solvent. Likewise, non-polar compound should be more soluble in non-polar solvent. Other hand, compounds with similar intermolecular force capability to soluble in one another because solute-solvent interactions are similar signification to the solute-solute interaction.

‘ The set of repulsive and attractive force between molecules that result from the polarity between neighboring molecules is represented as intermolecular force. There are four types of intermolecular forces:

Hydrogen bonding

London dispersion force

Ion – dipole force

Dipole – Dipole force

Hydrogen bond: Hydrogen is bonded to strong electronegative atom like oxygen, nitrogen etc.

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