
Organic Chemistry, Binder Ready Version
2nd Edition
ISBN: 9781118454312
Author: David R. Klein
Publisher: WILEY
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Question
Chapter 13, Problem 63IP
Interpretation Introduction
Interpretation:
The synthesis of the given product transformation should be identified.
Concept introduction:
Reduction:
Hydrogenation: Molecular hydrogen (
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Identify and provide an explanation that distinguishes a qualitative and quantitative chemical analysis. Provide examples.
Identify and provide an explanation of the operational principles behind a Atomic Absorption Spectrometer (AAS). List the steps involved.
Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
Chapter 13 Solutions
Organic Chemistry, Binder Ready Version
Ch. 13.1 - Prob. 1LTSCh. 13.1 - Prob. 1PTSCh. 13.1 - Prob. 2ATSCh. 13.1 - Prob. 3CCCh. 13.2 - Prob. 4CCCh. 13.2 - Prob. 2LTSCh. 13.2 - Prob. 5PTSCh. 13.2 - Prob. 6ATSCh. 13.3 - Prob. 7CCCh. 13.3 - Prob. 8CC
Ch. 13.4 - Prob. 3LTSCh. 13.4 - Prob. 9PTSCh. 13.4 - Prob. 10ATSCh. 13.4 - Prob. 11ATSCh. 13.4 - Prob. 4LTSCh. 13.4 - Prob. 12PTSCh. 13.4 - Prob. 13ATSCh. 13.6 - Prob. 5LTSCh. 13.6 - Prob. 14PTSCh. 13.6 - Prob. 15ATSCh. 13.6 - Prob. 16ATSCh. 13.6 - Prob. 17ATSCh. 13.7 - Prob. 18CCCh. 13.9 - Prob. 6LTSCh. 13.9 - Prob. 19PTSCh. 13.9 - Prob. 20ATSCh. 13.9 - Prob. 21CCCh. 13.10 - Prob. 7LTSCh. 13.10 - Prob. 22PTSCh. 13.10 - Prob. 23ATSCh. 13.13 - Prob. 8LTSCh. 13.13 - Prob. 24PTSCh. 13.13 - Prob. 25ATSCh. 13.13 - Prob. 26ATSCh. 13.13 - Prob. 27CCCh. 13.13 - Prob. 9LTSCh. 13.13 - Prob. 28PTSCh. 13.13 - Prob. 29ATSCh. 13 - Prob. 30PPCh. 13 - Prob. 31PPCh. 13 - Prob. 32PPCh. 13 - Prob. 33PPCh. 13 - Prob. 34PPCh. 13 - Prob. 35PPCh. 13 - Prob. 36PPCh. 13 - Prob. 37PPCh. 13 - Prob. 38PPCh. 13 - Prob. 39PPCh. 13 - Prob. 40PPCh. 13 - Prob. 41PPCh. 13 - Prob. 42PPCh. 13 - Prob. 43PPCh. 13 - Prob. 44PPCh. 13 - Prob. 45PPCh. 13 - Prob. 46PPCh. 13 - Prob. 47PPCh. 13 - Prob. 48PPCh. 13 - Prob. 49PPCh. 13 - Prob. 50PPCh. 13 - Prob. 51IPCh. 13 - Prob. 52IPCh. 13 - Prob. 53IPCh. 13 - Prob. 54IPCh. 13 - Prob. 55IPCh. 13 - Prob. 56IPCh. 13 - Prob. 57IPCh. 13 - Prob. 58IPCh. 13 - Prob. 59IPCh. 13 - Prob. 60IPCh. 13 - Prob. 61IPCh. 13 - Prob. 62IPCh. 13 - Prob. 63IP
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