CAREY: ORGANIC CHEMISTRY
CAREY: ORGANIC CHEMISTRY
10th Edition
ISBN: 9781260364002
Author: VALUE EDITION
Publisher: MCG CUSTOM
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Chapter 13, Problem 39P
Interpretation Introduction

Interpretation:

The structure for the expected product for each of the given compounds through an intramolecular Friedel-Craft acylation reaction that yield a cyclic ketone is to be written.

Concept introduction:

In Friedel-Crafts acylation, to yield aryl ketones, acyl halides are used.

In the intramolecular Friedel-Craft acylation, the electrophile and nucleophile present on the same molecule, resulting in the formation of a ring.

The electron releasing effect of the methoxy group attached to benzene ring makes the ring electron rich.

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1. Base on this experimental results, how do you know that the product which you are turning in is methyl 3-nitrobenzoate(meta substituted product ) rather than either of the other two products?  2. What observation suggests that at least a small amount of one or both of the other two isomers are in the mother liquor?
Explain Huckel's rule.
here is my question can u help me please!

Chapter 13 Solutions

CAREY: ORGANIC CHEMISTRY

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