Pearson eText for Essential Organic Chemistry -- Instant Access (Pearson+)
Pearson eText for Essential Organic Chemistry -- Instant Access (Pearson+)
3rd Edition
ISBN: 9780137533268
Author: Paula Bruice
Publisher: PEARSON+
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Chapter 13, Problem 39P
Interpretation Introduction

Interpretation:

Structure of cyclic product with six-membered rings when 2,6-heptanedione and 2,8-nonanedione is treated with sodium hydroxide has to be drawn.

Concept introduction:

Aldol reaction is an addition reaction of aldehydes and ketones. Aldol reaction is a reversible reaction and occurs in the presence of a strong base like sodium hydroxide.

One molecule (aldehyde or ketone) acts a nucleophile and attacks the electrophilic carbon center of the other molecule to give the addition product.  The product is named β-hydroxy aldehyde if two aldehydes combine and β-hydroxy ketone if two ketones combine.

If a compound has two functional groups that can react with each other, an intramolecular reaction readily occurs if the reaction leads to occur five or six-membered rings.

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Pearson eText for Essential Organic Chemistry -- Instant Access (Pearson+)

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