Organic Chemistry As a Second Language: Second Semester Topics
4th Edition
ISBN: 9781119110651
Author: David R. Klein
Publisher: WILEY
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Textbook Question
Chapter 1.3, Problem 1.9P
Characterize each of the following structures as aromatic, nonaromatic, or antiaromatic:
Answer: _____
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Q2: Ranking Acidity
a) Rank the labeled protons in the following molecule in order of increasing pKa. Briefly
explain the ranking. Use Table 2.2 as reference.
Ha
Нь
HC
H-N
Ha
OHe
b) Atenolol is a drug used to treat high blood pressure. Which of the indicated N-H bonds is
more acidic? Explain. (Hint: use resonance structures to help)
Name the functional groups on atenolol.
H
H-N
atenolol
Ν
H-N
OH Н
Answer d, e, and f
If the rotational constant of a molecule is B = 120 cm-1, it can be stated that the transition from 2←1:a) gives rise to a line at 120 cm-1b) is a forbidden transitionc) gives rise to a line at 240 cm-1d) gives rise to a line at 480 cm-1
Chapter 1 Solutions
Organic Chemistry As a Second Language: Second Semester Topics
Ch. 1.2 - Prob. 1.2PCh. 1.2 - Prob. 1.3PCh. 1.2 - Prob. 1.4PCh. 1.2 - Prob. 1.5PCh. 1.2 - Prob. 1.6PCh. 1.3 - Characterize each of the following structures as...Ch. 1.3 - Characterize each of the following structures as...Ch. 1.3 - Characterize each of the following structures as...Ch. 1.3 - Characterize each of the following structures as...Ch. 1.3 - Characterize each of the following structures as...
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