The reason for the difference in change in temperature when 100 mL of 9 M H 2 SO 4 at 0°C is added to 100 mL of liquid water and when the same H 2 SO 4 is added to 100 g of solid ice at 0 °C needs to be explained. Concept introduction: Colligative properties are the properties that depend on the number of particles present in the solution. Elevation in boiling point, depression in freezing point, lowering in vapor pressure and osmotic pressure are some common examples of colligative properties. Vapor pressure is the pressure that is exerted by vapor on the liquid surface in a closed system when the system is in thermodynamic equilibrium. The temperature at which the vapor pressure becomes equal to the atmospheric pressure is called as boiling point.
The reason for the difference in change in temperature when 100 mL of 9 M H 2 SO 4 at 0°C is added to 100 mL of liquid water and when the same H 2 SO 4 is added to 100 g of solid ice at 0 °C needs to be explained. Concept introduction: Colligative properties are the properties that depend on the number of particles present in the solution. Elevation in boiling point, depression in freezing point, lowering in vapor pressure and osmotic pressure are some common examples of colligative properties. Vapor pressure is the pressure that is exerted by vapor on the liquid surface in a closed system when the system is in thermodynamic equilibrium. The temperature at which the vapor pressure becomes equal to the atmospheric pressure is called as boiling point.
Solution Summary: The author explains the difference in temperature between adding 9 M H_Text2 and adding 100 g of solid ice at 0°C. Elevation in boiling point, depression in
Science that deals with the amount of energy transferred from one equilibrium state to another equilibrium state.
Chapter 13, Problem 13.99SP
Interpretation Introduction
Interpretation:
The reason for the difference in change in temperature when 100 mL of 9 M H2SO4 at 0°C is added to 100 mL of liquid water and when the same H2SO4 is added to 100 g of solid ice at 0 °C needs to be explained.
Concept introduction:
Colligative properties are the properties that depend on the number of particles present in the solution. Elevation in boiling point, depression in freezing point, lowering in vapor pressure and osmotic pressure are some common examples of colligative properties. Vapor pressure is the pressure that is exerted by vapor on the liquid surface in a closed system when the system is in thermodynamic equilibrium. The temperature at which the vapor pressure becomes equal to the atmospheric pressure is called as boiling point.
Devise electrochemical cells in which the following reactions could be made to occur. If liquid
junctions are necessary, note them in the cell schematic appropriately, but neglect their effects.
(a) H2OH + OH¯
(b) 2H2O2
H₂O
(c) 2PbSO4 + 2H2O
(d) An
TMPD
PыO₂+ Pb + 4H+ + 20%¯¯
An + TMPD (in acetonitrile, where An and An are anthracene and its
anion radical, and TMPD and TMPD are N,N,N',N'-tetramethyl-p-phenylenediamine and its
cation radical. Use anthracene potentials for DMF solutions given in Appendix C.3).
(e) 2Ce3+ + 2H + BQ 2Ce4+ + H2Q (aqueous, where BQ is p-benzoquinone and H₂Q is p-
hydroquinone)
(f) Ag +Agl (aqueous)
(g) Fe3+ + Fe(CN)6 Fe²+ + Fe(CN) (aqueous)
Consider each of the following electrode-solution interfaces, and write the equation for the elec-
trode reaction that occurs first when the potential is moved in (1) a negative direction and (2) a posi-
tive direction from the open-circuit potential. Next to each reaction write the approximate potential
for the reaction in V vs. SCE (assuming the reaction is reversible).
(a) Pt/Cu2+ (0.01 M), Cd2+ (0.01 M), H2SO4(1 M)
(b) Pt/Sn2+ (0.01 M), Sn4+ (0.01 M), HCl(1 M)
(c) Hg/Cd2+ (0.01 M), Zn2+ (0.01 M), HCl(1 M)
What are the major products of both of the organic reactions. Please be sure to use wedge and dash bonds to show the stereochemistry of the products if it is needed. Please include the final product as well as a digram/drawing to show the mechanism of the reaction.
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell