The P − x 1 − y 1 diagram is to be generated for the given systems at 100 ∘ C using two procedures, (i) Modified Raoult’s law, and (ii) gamma/phi approach. Concept Introduction: Equation used for Gamma/Phi formulation for VLE is: y i Φ i P = x i γ i P i sat .......(1) Here, Φ i for a binary system is: Φ i = φ ^ i v φ i sat Φ i = exp [ P r T r i ( B i 0 + ω i B i 1 ) ] exp [ P r i sat T r i ( B i 0 + ω i B i 1 ) ] Φ i = exp [ ( P r i − P r i sat ) T r i ( B i 0 + ω i B i 1 ) ] ...... (2) And, B i 0 = 0.083 − 0.422 T r i 1.6 B i 1 = 0.139 − 0.172 T r i 4.2 .......(3) Reduced pressure and temperature are calculated by: P r = P P c ...... (4) T r = T T c ...... (5) Here, P c and T c are the critical pressure and temperature respectively. Equation to be used for Modified Raoult’s law is: y i P = x i γ i P i sat .......(6) Wilson equations to be used are: ln γ 1 = − ln ( x 1 + x 2 Λ 12 ) + x 2 ( Λ 12 x 1 + x 2 Λ 12 − Λ 21 x 2 + x 1 Λ 21 ) ln γ 2 = − ln ( x 2 + x 1 Λ 21 ) + x 1 ( Λ 12 x 1 + x 2 Λ 12 − Λ 21 x 2 + x 1 Λ 21 ) .......(7) Antoine equation is used to determine the vapor pressure of any substance at the given temperature by the equation: ln P sat ( kPa ) = A − B ( T ∘ C ) + C .......(8) Here, A , B and C are the constants specific for a substance given in table B.2 of appendix B.

Question

Want to see the full answer?

Answer 1

Question

Chapter 13, Problem 13.76P

Interpretation Introduction

Interpretation:

The P−x1−y1 diagram is to be generated for the given systems at 100∘C using two procedures, (i) Modified Raoult’s law, and (ii) gamma/phi approach.

Concept Introduction:

Equation used for Gamma/Phi formulation for VLE is:

yiΦiP=xiγiPisat .......(1)

Here, Φi

for a binary system is:

Φi= φ ^ivφi satΦi=exp[ P r T ri ( B i 0 + ω i B i 1 )]exp[ P ri sat T ri ( B i 0 + ω i B i 1 )]Φi=exp[( P ri − P ri sat ) T ri( B i 0+ ω i B i 1)] ...... (2)

And,

Bi0=0.083−0.422T ri 1.6Bi1=0.139−0.172T ri 4.2 .......(3)

Reduced pressure and temperature are calculated by:

Pr=PPc ...... (4)Tr=TTc ...... (5)

Here, Pc and Tc are the critical pressure and temperature respectively.

Equation to be used for Modified Raoult’s law is:

yiP=xiγiPisat .......(6)

Wilson equations to be used are:

lnγ1=−ln(x1+x2Λ 12)+x2( Λ 12 x 1 + x 2 Λ 12 − Λ 21 x 2 + x 1 Λ 21 )lnγ2=−ln(x2+x1Λ 21)+x1( Λ 12 x 1 + x 2 Λ 12 − Λ 21 x 2 + x 1 Λ 21 ) .......(7)

Antoine equation is used to determine the vapor pressure of any substance at the given temperature by the equation:

lnPsat(kPa)=A−B(T∘C)+C .......(8)

Here, A, B and C are the constants specific for a substance given in table B.2 of appendix B.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

please provide me the solution with more details. because the previous solution is not clear

please, provide me the solution with details.

please, provide me the solution with details

Answer 2

Question

Chapter 13, Problem 13.76P

Interpretation Introduction

Interpretation:

The P−x1−y1 diagram is to be generated for the given systems at 100∘C using two procedures, (i) Modified Raoult’s law, and (ii) gamma/phi approach.

Concept Introduction:

Equation used for Gamma/Phi formulation for VLE is:

yiΦiP=xiγiPisat .......(1)

Here, Φi

for a binary system is:

Φi= φ ^ivφi satΦi=exp[ P r T ri ( B i 0 + ω i B i 1 )]exp[ P ri sat T ri ( B i 0 + ω i B i 1 )]Φi=exp[( P ri − P ri sat ) T ri( B i 0+ ω i B i 1)] ...... (2)

And,

Bi0=0.083−0.422T ri 1.6Bi1=0.139−0.172T ri 4.2 .......(3)

Reduced pressure and temperature are calculated by:

Pr=PPc ...... (4)Tr=TTc ...... (5)

Here, Pc and Tc are the critical pressure and temperature respectively.

Equation to be used for Modified Raoult’s law is:

yiP=xiγiPisat .......(6)

Wilson equations to be used are:

lnγ1=−ln(x1+x2Λ 12)+x2( Λ 12 x 1 + x 2 Λ 12 − Λ 21 x 2 + x 1 Λ 21 )lnγ2=−ln(x2+x1Λ 21)+x1( Λ 12 x 1 + x 2 Λ 12 − Λ 21 x 2 + x 1 Λ 21 ) .......(7)

Antoine equation is used to determine the vapor pressure of any substance at the given temperature by the equation:

lnPsat(kPa)=A−B(T∘C)+C .......(8)

Here, A, B and C are the constants specific for a substance given in table B.2 of appendix B.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 13, Problem 13.76P

Interpretation Introduction

Interpretation:

The P−x1−y1 diagram is to be generated for the given systems at 100∘C using two procedures, (i) Modified Raoult’s law, and (ii) gamma/phi approach.

Concept Introduction:

Equation used for Gamma/Phi formulation for VLE is:

yiΦiP=xiγiPisat .......(1)

Here, Φi

for a binary system is:

Φi= φ ^ivφi satΦi=exp[ P r T ri ( B i 0 + ω i B i 1 )]exp[ P ri sat T ri ( B i 0 + ω i B i 1 )]Φi=exp[( P ri − P ri sat ) T ri( B i 0+ ω i B i 1)] ...... (2)

And,

Bi0=0.083−0.422T ri 1.6Bi1=0.139−0.172T ri 4.2 .......(3)

Reduced pressure and temperature are calculated by:

Pr=PPc ...... (4)Tr=TTc ...... (5)

Here, Pc and Tc are the critical pressure and temperature respectively.

Equation to be used for Modified Raoult’s law is:

yiP=xiγiPisat .......(6)

Wilson equations to be used are:

lnγ1=−ln(x1+x2Λ 12)+x2( Λ 12 x 1 + x 2 Λ 12 − Λ 21 x 2 + x 1 Λ 21 )lnγ2=−ln(x2+x1Λ 21)+x1( Λ 12 x 1 + x 2 Λ 12 − Λ 21 x 2 + x 1 Λ 21 ) .......(7)

Antoine equation is used to determine the vapor pressure of any substance at the given temperature by the equation:

lnPsat(kPa)=A−B(T∘C)+C .......(8)

Here, A, B and C are the constants specific for a substance given in table B.2 of appendix B.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 13, Problem 13.76P

Interpretation Introduction

Interpretation:

The P−x1−y1 diagram is to be generated for the given systems at 100∘C using two procedures, (i) Modified Raoult’s law, and (ii) gamma/phi approach.

Concept Introduction:

Equation used for Gamma/Phi formulation for VLE is:

yiΦiP=xiγiPisat .......(1)

Here, Φi

for a binary system is:

Φi= φ ^ivφi satΦi=exp[ P r T ri ( B i 0 + ω i B i 1 )]exp[ P ri sat T ri ( B i 0 + ω i B i 1 )]Φi=exp[( P ri − P ri sat ) T ri( B i 0+ ω i B i 1)] ...... (2)

And,

Bi0=0.083−0.422T ri 1.6Bi1=0.139−0.172T ri 4.2 .......(3)

Reduced pressure and temperature are calculated by:

Pr=PPc ...... (4)Tr=TTc ...... (5)

Here, Pc and Tc are the critical pressure and temperature respectively.

Equation to be used for Modified Raoult’s law is:

yiP=xiγiPisat .......(6)

Wilson equations to be used are:

lnγ1=−ln(x1+x2Λ 12)+x2( Λ 12 x 1 + x 2 Λ 12 − Λ 21 x 2 + x 1 Λ 21 )lnγ2=−ln(x2+x1Λ 21)+x1( Λ 12 x 1 + x 2 Λ 12 − Λ 21 x 2 + x 1 Λ 21 ) .......(7)

Antoine equation is used to determine the vapor pressure of any substance at the given temperature by the equation:

lnPsat(kPa)=A−B(T∘C)+C .......(8)

Here, A, B and C are the constants specific for a substance given in table B.2 of appendix B.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 13, Problem 13.76P

Interpretation Introduction

Interpretation:

The P−x1−y1 diagram is to be generated for the given systems at 100∘C using two procedures, (i) Modified Raoult’s law, and (ii) gamma/phi approach.

Concept Introduction:

Equation used for Gamma/Phi formulation for VLE is:

yiΦiP=xiγiPisat .......(1)

Here, Φi

for a binary system is:

Φi= φ ^ivφi satΦi=exp[ P r T ri ( B i 0 + ω i B i 1 )]exp[ P ri sat T ri ( B i 0 + ω i B i 1 )]Φi=exp[( P ri − P ri sat ) T ri( B i 0+ ω i B i 1)] ...... (2)

And,

Bi0=0.083−0.422T ri 1.6Bi1=0.139−0.172T ri 4.2 .......(3)

Reduced pressure and temperature are calculated by:

Pr=PPc ...... (4)Tr=TTc ...... (5)

Here, Pc and Tc are the critical pressure and temperature respectively.

Equation to be used for Modified Raoult’s law is:

yiP=xiγiPisat .......(6)

Wilson equations to be used are:

lnγ1=−ln(x1+x2Λ 12)+x2( Λ 12 x 1 + x 2 Λ 12 − Λ 21 x 2 + x 1 Λ 21 )lnγ2=−ln(x2+x1Λ 21)+x1( Λ 12 x 1 + x 2 Λ 12 − Λ 21 x 2 + x 1 Λ 21 ) .......(7)

Antoine equation is used to determine the vapor pressure of any substance at the given temperature by the equation:

lnPsat(kPa)=A−B(T∘C)+C .......(8)

Here, A, B and C are the constants specific for a substance given in table B.2 of appendix B.

Answer 6

Chapter 13, Problem 13.76P

Interpretation Introduction

Interpretation:

The P−x1−y1 diagram is to be generated for the given systems at 100∘C using two procedures, (i) Modified Raoult’s law, and (ii) gamma/phi approach.

Concept Introduction:

Equation used for Gamma/Phi formulation for VLE is:

yiΦiP=xiγiPisat .......(1)

Here, Φi

for a binary system is:

Φi= φ ^ivφi satΦi=exp[ P r T ri ( B i 0 + ω i B i 1 )]exp[ P ri sat T ri ( B i 0 + ω i B i 1 )]Φi=exp[( P ri − P ri sat ) T ri( B i 0+ ω i B i 1)] ...... (2)

And,

Bi0=0.083−0.422T ri 1.6Bi1=0.139−0.172T ri 4.2 .......(3)

Reduced pressure and temperature are calculated by:

Pr=PPc ...... (4)Tr=TTc ...... (5)

Here, Pc and Tc are the critical pressure and temperature respectively.

Equation to be used for Modified Raoult’s law is:

yiP=xiγiPisat .......(6)

Wilson equations to be used are:

lnγ1=−ln(x1+x2Λ 12)+x2( Λ 12 x 1 + x 2 Λ 12 − Λ 21 x 2 + x 1 Λ 21 )lnγ2=−ln(x2+x1Λ 21)+x1( Λ 12 x 1 + x 2 Λ 12 − Λ 21 x 2 + x 1 Λ 21 ) .......(7)

Antoine equation is used to determine the vapor pressure of any substance at the given temperature by the equation:

lnPsat(kPa)=A−B(T∘C)+C .......(8)

Here, A, B and C are the constants specific for a substance given in table B.2 of appendix B.

Answer 7

Chapter 13, Problem 13.76P

Interpretation Introduction

Interpretation:

The P−x1−y1 diagram is to be generated for the given systems at 100∘C using two procedures, (i) Modified Raoult’s law, and (ii) gamma/phi approach.

Concept Introduction:

Equation used for Gamma/Phi formulation for VLE is:

yiΦiP=xiγiPisat .......(1)

Here, Φi

for a binary system is:

Φi= φ ^ivφi satΦi=exp[ P r T ri ( B i 0 + ω i B i 1 )]exp[ P ri sat T ri ( B i 0 + ω i B i 1 )]Φi=exp[( P ri − P ri sat ) T ri( B i 0+ ω i B i 1)] ...... (2)

And,

Bi0=0.083−0.422T ri 1.6Bi1=0.139−0.172T ri 4.2 .......(3)

Reduced pressure and temperature are calculated by:

Pr=PPc ...... (4)Tr=TTc ...... (5)

Here, Pc and Tc are the critical pressure and temperature respectively.

Equation to be used for Modified Raoult’s law is:

yiP=xiγiPisat .......(6)

Wilson equations to be used are:

lnγ1=−ln(x1+x2Λ 12)+x2( Λ 12 x 1 + x 2 Λ 12 − Λ 21 x 2 + x 1 Λ 21 )lnγ2=−ln(x2+x1Λ 21)+x1( Λ 12 x 1 + x 2 Λ 12 − Λ 21 x 2 + x 1 Λ 21 ) .......(7)

Antoine equation is used to determine the vapor pressure of any substance at the given temperature by the equation:

lnPsat(kPa)=A−B(T∘C)+C .......(8)

Here, A, B and C are the constants specific for a substance given in table B.2 of appendix B.

Answer 8

Expert Solution & Answer

Answer 9

Expert Solution & Answer

Answer 10

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 11

Ch. 13 - Prob. 13.1P Ch. 13 - Assuming Raoult’s law to be valid, prepare a Pxy...Ch. 13 - Assuming Raoult’s law to apply to the system...Ch. 13 - Prob. 13.4P Ch. 13 - Prove: An equilibrium liquid/vapor system...Ch. 13 - Of the following binary liquid/vapor systems,...Ch. 13 - A single-stage liquid/vapor separation for the...Ch. 13 - Do all four parts of Prob. 13.7, and compare the...Ch. 13 - A mixture containing equimolar amounts of...Ch. 13 - Do all four parts of Prob. 13.9. and compare the...

Want to see the full answer?

Chapter 13 Solutions