Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN: 9781259696527
Author: J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher: McGraw-Hill Education
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Chapter 13, Problem 13.69P
For one of the following substances, determine Psat/bar from the Redlich/Kwong equation at two temperatures: T = Tn(the normal boiling point), and T = 0.857Tc. For the second temperature, compare your result with a value from the literature (e.g., Perry’s Chemical Engineers’ Handbook). Discuss your results.
(a) Acetylene; (b) Argon; (c) Benzene; (d) n-Butane; (e) Carbon monoxide;
(f) n-Decane; (g) Ethylene: (h) n-Heptane; (i) Methane; (j) Nitrogen
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Chapter 13 Solutions
Introduction to Chemical Engineering Thermodynamics
Ch. 13 - Prob. 13.1PCh. 13 - Assuming Raoult’s law to be valid, prepare a Pxy...Ch. 13 - Assuming Raoult’s law to apply to the system...Ch. 13 - Prob. 13.4PCh. 13 - Prove: An equilibrium liquid/vapor system...Ch. 13 - Of the following binary liquid/vapor systems,...Ch. 13 - A single-stage liquid/vapor separation for the...Ch. 13 - Do all four parts of Prob. 13.7, and compare the...Ch. 13 - A mixture containing equimolar amounts of...Ch. 13 - Do all four parts of Prob. 13.9. and compare the...
Ch. 13 - A binary mixture of mole fraction z1is flashed to...Ch. 13 - Humidity, relating to the quantity of moisture in...Ch. 13 - A concentrated binary solution containing mostly...Ch. 13 - Air, even more than carbon dioxide, is inexpensive...Ch. 13 - Helium-laced gases are used as breathing media for...Ch. 13 - A binary system of species 1 and 2 consists of...Ch. 13 - For the system ethyl ethanoate(l)/n-heptane(2) at...Ch. 13 - A liquid mixture of cyclohexanone(1)/phenol(2) for...Ch. 13 - A binary system of species 1 and 2 consists of...Ch. 13 - For the acetone(l)/methanol(2) system, a vapor...Ch. 13 - The following is a rule of thumb: For a binary...Ch. 13 - A process stream contains light species 1 and...Ch. 13 - If a system exhibits VLE, at least one of the...Ch. 13 - Flash calculations are simpler for binary systems...Ch. 13 - Prob. 13.25PCh. 13 - (a) A feed containing equimolar amounts of...Ch. 13 - A binary mixture of benzene(1) and toluene(2) is...Ch. 13 - Ten (10) kmolhr-1 of hydrogen sulfide gas is...Ch. 13 - Physiological studies show the neutral comfort...Ch. 13 - Prob. 13.30PCh. 13 - Prob. 13.31PCh. 13 - Prob. 13.32PCh. 13 - If Eq. (13.24) is valid for isothermal VLE in a...Ch. 13 - Prob. 13.34PCh. 13 - The excess Gibbs energy for binary systems...Ch. 13 - For the ethanol(l )/chloroform(2) system at 50°C,...Ch. 13 - VLE data for methyl tert-butyl...Ch. 13 - Prob. 13.38PCh. 13 - Prob. 13.39PCh. 13 - Following are VLE data for the system...Ch. 13 - Prob. 13.41PCh. 13 - Prob. 13.42PCh. 13 - Problems 13.43 through 13.54 require parameter...Ch. 13 - Problems 13.43 through 13.54 require parameter...Ch. 13 - Prob. 13.45PCh. 13 - Problems 13.43 through 13.54 require parameter...Ch. 13 - Prob. 13.47PCh. 13 - Prob. 13.48PCh. 13 - Prob. 13.49PCh. 13 - Prob. 13.50PCh. 13 - Problems 13.43 through 13.54 require parameter...Ch. 13 - Prob. 13.52PCh. 13 - The following expressions have been reported for...Ch. 13 - Possible correlating equations for In 1 in a...Ch. 13 - Prob. 13.57PCh. 13 - Binary VLE data are commonly measured at constant...Ch. 13 - Consider the following model for GE/RT of a binary...Ch. 13 - A breathalyzer measures volume-% ethanol in gases...Ch. 13 - Table 13.10 gives values of parameters for the...Ch. 13 - Prob. 13.62PCh. 13 - A single P-x1- y1data point is available for a...Ch. 13 - A single P- x1, data point is available for a...Ch. 13 - The excess Gibbs energy for the system...Ch. 13 - Prob. 13.66PCh. 13 - A system formed of methane(l) and a light oil(2)...Ch. 13 - Use Eq. (13.13) to reduce one of the following...Ch. 13 - For one of the following substances, determine...Ch. 13 - Departures from Raoult's law are primarily from...Ch. 13 - The relative volatility a12is commonly used in...Ch. 13 - Prob. 13.74PCh. 13 - Prob. 13.75PCh. 13 - Prob. 13.76P
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- 14.9. A forward feed double-effect vertical evaporator, with equal heating areas in each effect, is fed with 5 kg/s of a liquor of specific heat capacity of 4.18 kJ/kg K. and with no boiling point rise, so that 50 per cent of the feed liquor is evaporated. The overall heat transfer coefficient in the second effect is 75 per cent of that in the first effect. Steam is fed at 395 K and the boiling point in the second effect is 373 K. The feed is heated by an external heater to the boiling point in the first effect. It is decided to bleed off 0.25 kg/s of vapour from the vapour line to the second effect for use in another process. If the feed is still heated to the boiling point of the first effect by external means, what will be the change in steam consumption of the evaporator unit? For the purpose of calculation, the latent heat of the vapours and of the steam may both be taken as 2230 kJ/kgarrow_forwardExample(3): It is desired to design a double effect evaporator for concentrating a certain caustic soda solution from 12.5wt% to 40wt%. The feed at 50°C enters the first evaporator at a rate of 2500kg/h. Steam at atmospheric pressure is being used for the said purpose. The second effect is operated under 600mmHg vacuum. If the overall heat transfer coefficients of the two stages are 1952 and 1220kcal/ m2.h.°C. respectively, determine the heat transfer area of each effect. The BPR will be considered and present for the both effect 5:49arrow_forwardالعنوان ose only Q Example (7): Determine the heating surface area 개 required for the production of 2.5kg/s of 50wt% NaOH solution from 15 wt% NaOH feed solution which entering at 100 oC to a single effect evaporator. The steam is available as saturated at 451.5K and the boiling point rise (boiling point evaluation) of 50wt% solution is 35K. the overall heat transfer coefficient is 2000 w/m²K. The pressure in the vapor space of the evaporator at atmospheric pressure. The solution has a specific heat of 4.18kJ/ kg.K. The enthalpy of vaporization under these condition is 2257kJ/kg Example (6): 5:48 An evaporator is concentrating F kg/h at 311K of a 20wt% solution of NaOH to 50wt %. The saturated steam used for heating is at 399.3K. The pressure in the vapor space of the evaporator is 13.3 KPa abs. The 5:48 1 J ۲/۱ ostrarrow_forward
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