Connect 2-Year Online Access for General, Organic, and Biochemistry
Connect 2-Year Online Access for General, Organic, and Biochemistry
9th Edition
ISBN: 9781259677946
Author: Denniston
Publisher: Mcgraw-hill Higher Education (us)
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Chapter 13, Problem 13.67QP

(a)

Interpretation Introduction

Interpretation:

The reaction of 3-pentanone with Tollens’ reagent has to be written.

Concept Introduction:

Aldehydes and ketone can be identified based on their oxidations.  Aldehydes readily are oxidized whereas ketones are not.  The most common laboratory test for aldehydes is Tollens’ reagent.

Tollens’ reagent is basic solution of silver ammonia complex.  It is mainly used for oxidation of aldehydes.  The silver ion is reduced to silver metal as the aldehyde is oxidized to a carboxylate anion.  Silver metal precipitates from the solution and coats the flask, producing a smooth silver mirror.  The test is often called tollens’ silver mirror test.

Ketones cannot be oxidized acids and do not react with the tollens’ reagent.

The general reaction is,

Connect 2-Year Online Access for General, Organic, and Biochemistry, Chapter 13, Problem 13.67QP

(b)

Interpretation Introduction

Interpretation:

The reaction of cyclohexanone with Tollens’ reagent has to be written.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The reaction of 3-methylbutanal with Tollens’ reagent has to be written.

Concept Introduction:

Refer to part (a).

(d)

Interpretation Introduction

Interpretation:

The reaction of cyclopentanol with Tollens’ reagent has to be written.

Concept Introduction:

Refer to part (a).

(e)

Interpretation Introduction

Interpretation:

The reaction of 2,2-dimethyl-1-pentanol with Tollens’ reagent has to be written.

Concept Introduction:

Refer to part (a).

(f)

Interpretation Introduction

Interpretation:

The reaction of acetaldehyde with Tollens’ reagent has to be written.

Concept Introduction:

Refer to part (a).

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Chapter 13 Solutions

Connect 2-Year Online Access for General, Organic, and Biochemistry

Ch. 13.2 - Prob. 13.7QCh. 13.2 - Write the condensed formula for each of the...Ch. 13.3 - Draw the structure of the aldehyde synthesized...Ch. 13.3 - Prob. 13.10QCh. 13.4 - Prob. 13.5PPCh. 13.4 - Prob. 13.6PPCh. 13.4 - Prob. 13.7PPCh. 13.4 - Prob. 13.8PPCh. 13.4 - Prob. 13.11QCh. 13.4 - Prob. 13.12QCh. 13.4 - Identify each of the following structures as a...Ch. 13.4 - Identify each of the following structures as a...Ch. 13.4 - Prob. 13.9PPCh. 13 - Prob. 13.15QPCh. 13 - Prob. 13.16QPCh. 13 - Prob. 13.17QPCh. 13 - Prob. 13.18QPCh. 13 - Prob. 13.19QPCh. 13 - Prob. 13.20QPCh. 13 - Prob. 13.21QPCh. 13 - Why do hydrocarbons have lower boiling points than...Ch. 13 - Prob. 13.23QPCh. 13 - Prob. 13.24QPCh. 13 - Prob. 13.25QPCh. 13 - Prob. 13.26QPCh. 13 - Prob. 13.27QPCh. 13 - Prob. 13.28QPCh. 13 - Draw each of the following using condensed...Ch. 13 - Prob. 13.30QPCh. 13 - Prob. 13.31QPCh. 13 - Prob. 13.32QPCh. 13 - Prob. 13.33QPCh. 13 - Prob. 13.34QPCh. 13 - Prob. 13.35QPCh. 13 - Prob. 13.36QPCh. 13 - Prob. 13.37QPCh. 13 - Prob. 13.38QPCh. 13 - Give the IUPAC name for each of the following...Ch. 13 - Give the IUPAC name for each of the following...Ch. 13 - Prob. 13.41QPCh. 13 - Prob. 13.42QPCh. 13 - Prob. 13.43QPCh. 13 - Prob. 13.44QPCh. 13 - Prob. 13.45QPCh. 13 - Prob. 13.46QPCh. 13 - Prob. 13.47QPCh. 13 - Prob. 13.48QPCh. 13 - Prob. 13.49QPCh. 13 - Prob. 13.50QPCh. 13 - Prob. 13.51QPCh. 13 - Prob. 13.52QPCh. 13 - Prob. 13.53QPCh. 13 - Prob. 13.54QPCh. 13 - Prob. 13.55QPCh. 13 - Prob. 13.56QPCh. 13 - Prob. 13.57QPCh. 13 - Prob. 13.58QPCh. 13 - Prob. 13.59QPCh. 13 - Prob. 13.60QPCh. 13 - Prob. 13.61QPCh. 13 - An unknown has been determined to be one of the...Ch. 13 - Prob. 13.63QPCh. 13 - Prob. 13.64QPCh. 13 - Prob. 13.65QPCh. 13 - Prob. 13.66QPCh. 13 - Which of the following compounds would be expected...Ch. 13 - Write an equation representing the reaction of...Ch. 13 - Prob. 13.69QPCh. 13 - Prob. 13.70QPCh. 13 - Prob. 13.71QPCh. 13 - Prob. 13.72QPCh. 13 - Prob. 13.73QPCh. 13 - Prob. 13.74QPCh. 13 - Prob. 13.75QPCh. 13 - Prob. 13.76QPCh. 13 - Prob. 13.77QPCh. 13 - Prob. 13.78QPCh. 13 - Prob. 13.79QPCh. 13 - Prob. 13.80QPCh. 13 - Prob. 13.81QPCh. 13 - Prob. 13.82QPCh. 13 - Prob. 13.83QPCh. 13 - Prob. 13.84QPCh. 13 - Prob. 1CPCh. 13 - Prob. 2CPCh. 13 - Design a synthesis for each of the following...Ch. 13 - Prob. 4CPCh. 13 - Prob. 6CP
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