The structure of 1-nonanol along with its oxidation reaction has to be given. Concept Introduction: Aldehydes and ketones are prepared by the oxidation of the corresponding alcohols. The oxidation of a primary alcohol produces an aldehyde and the oxidation of secondary alcohol yields a ketone. Tertiary alcohols do not undergo oxidation under the conditions normally used.

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Answer 1

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 13, Problem 13.58QP

(a)

Interpretation Introduction

Interpretation:

The structure of 1-nonanol along with its oxidation reaction has to be given.

Concept Introduction:

Aldehydes and ketones are prepared by the oxidation of the corresponding alcohols. The oxidation of a primary alcohol produces an aldehyde and the oxidation of secondary alcohol yields a ketone. Tertiary alcohols do not undergo oxidation under the conditions normally used.

(b)

Interpretation Introduction

Interpretation:

The structure of 4-methyl-1-pentanol along with its oxidation reaction has to be given.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The structure of 4,6-diethyl-3-methyl-3-octanol along with its oxidation reaction has to be given.

Concept Introduction:

Refer to part (a).

(d)

Interpretation Introduction

Interpretation:

The structure of 5-bromo-4-octanol along with its oxidation reaction has to be given.

Concept Introduction:

Refer to part (a).

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Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following: (a) match structures of isomers given their mass spectra below (spectra A and spectra B) (b) Draw the fragments given the following prominent peaks from each spectrum: Spectra A m/2 =43 and 1/2-57 spectra B m/2 = 43 (c) why is 1/2=57 peak in spectrum A more intense compared to the same peak in spectrum B. Relative abundance Relative abundance 100 A 50 29 29 0 10 -0 -0 100 B 50 720 30 41 43 57 71 4-0 40 50 60 70 m/z 43 57 8-0 m/z = 86 M 90 100 71 m/z = 86 M -O 0 10 20 30 40 50 60 70 80 -88 m/z 90 100

Part IV. C6H5 CH2CH2OH is an aromatic compound which was subjected to Electron Ionization - mass spectrometry (El-MS) analysis. Prominent m/2 values: m/2 = 104 and m/2 = 9) was obtained. Draw the structures of these fragments.

For each reaction shown below follow the curved arrows to complete each equationby showing the structure of the products. Identify the acid, the base, the conjugated acid andconjugated base. Consutl the pKa table and choose the direciton theequilibrium goes. However show the curved arrows. Please explain if possible.

Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 13, Problem 13.58QP

(a)

Interpretation Introduction

Interpretation:

The structure of 1-nonanol along with its oxidation reaction has to be given.

Concept Introduction:

Aldehydes and ketones are prepared by the oxidation of the corresponding alcohols. The oxidation of a primary alcohol produces an aldehyde and the oxidation of secondary alcohol yields a ketone. Tertiary alcohols do not undergo oxidation under the conditions normally used.

(b)

Interpretation Introduction

Interpretation:

The structure of 4-methyl-1-pentanol along with its oxidation reaction has to be given.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The structure of 4,6-diethyl-3-methyl-3-octanol along with its oxidation reaction has to be given.

Concept Introduction:

Refer to part (a).

(d)

Interpretation Introduction

Interpretation:

The structure of 5-bromo-4-octanol along with its oxidation reaction has to be given.

Concept Introduction:

Refer to part (a).

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Answer 3

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 13, Problem 13.58QP

(a)

Interpretation Introduction

Interpretation:

The structure of 1-nonanol along with its oxidation reaction has to be given.

Concept Introduction:

Aldehydes and ketones are prepared by the oxidation of the corresponding alcohols. The oxidation of a primary alcohol produces an aldehyde and the oxidation of secondary alcohol yields a ketone. Tertiary alcohols do not undergo oxidation under the conditions normally used.

(b)

Interpretation Introduction

Interpretation:

The structure of 4-methyl-1-pentanol along with its oxidation reaction has to be given.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The structure of 4,6-diethyl-3-methyl-3-octanol along with its oxidation reaction has to be given.

Concept Introduction:

Refer to part (a).

(d)

Interpretation Introduction

Interpretation:

The structure of 5-bromo-4-octanol along with its oxidation reaction has to be given.

Concept Introduction:

Refer to part (a).

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Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 13, Problem 13.58QP

(a)

Interpretation Introduction

Interpretation:

The structure of 1-nonanol along with its oxidation reaction has to be given.

Concept Introduction:

Aldehydes and ketones are prepared by the oxidation of the corresponding alcohols. The oxidation of a primary alcohol produces an aldehyde and the oxidation of secondary alcohol yields a ketone. Tertiary alcohols do not undergo oxidation under the conditions normally used.

(b)

Interpretation Introduction

Interpretation:

The structure of 4-methyl-1-pentanol along with its oxidation reaction has to be given.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The structure of 4,6-diethyl-3-methyl-3-octanol along with its oxidation reaction has to be given.

Concept Introduction:

Refer to part (a).

(d)

Interpretation Introduction

Interpretation:

The structure of 5-bromo-4-octanol along with its oxidation reaction has to be given.

Concept Introduction:

Refer to part (a).

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Answer 5

Chapter 13, Problem 13.58QP

(a)

Interpretation Introduction

Interpretation:

The structure of 1-nonanol along with its oxidation reaction has to be given.

Concept Introduction:

Aldehydes and ketones are prepared by the oxidation of the corresponding alcohols. The oxidation of a primary alcohol produces an aldehyde and the oxidation of secondary alcohol yields a ketone. Tertiary alcohols do not undergo oxidation under the conditions normally used.

(b)

Interpretation Introduction

Interpretation:

The structure of 4-methyl-1-pentanol along with its oxidation reaction has to be given.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The structure of 4,6-diethyl-3-methyl-3-octanol along with its oxidation reaction has to be given.

Concept Introduction:

Refer to part (a).

(d)

Interpretation Introduction

Interpretation:

The structure of 5-bromo-4-octanol along with its oxidation reaction has to be given.

Concept Introduction:

Refer to part (a).

Answer 6

Chapter 13, Problem 13.58QP

(a)

Interpretation Introduction

Interpretation:

The structure of 1-nonanol along with its oxidation reaction has to be given.

Concept Introduction:

Aldehydes and ketones are prepared by the oxidation of the corresponding alcohols. The oxidation of a primary alcohol produces an aldehyde and the oxidation of secondary alcohol yields a ketone. Tertiary alcohols do not undergo oxidation under the conditions normally used.

Answer 7

Chapter 13, Problem 13.58QP

(a)

Interpretation Introduction

Interpretation:

The structure of 1-nonanol along with its oxidation reaction has to be given.

Concept Introduction:

Aldehydes and ketones are prepared by the oxidation of the corresponding alcohols. The oxidation of a primary alcohol produces an aldehyde and the oxidation of secondary alcohol yields a ketone. Tertiary alcohols do not undergo oxidation under the conditions normally used.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The structure of 4-methyl-1-pentanol along with its oxidation reaction has to be given.

Concept Introduction:

Refer to part (a).

Answer 9

(b)

Interpretation Introduction

Interpretation:

The structure of 4-methyl-1-pentanol along with its oxidation reaction has to be given.

Concept Introduction:

Refer to part (a).

Answer 10

(c)

Interpretation Introduction

Interpretation:

The structure of 4,6-diethyl-3-methyl-3-octanol along with its oxidation reaction has to be given.

Concept Introduction:

Refer to part (a).

Answer 11

(c)

Interpretation Introduction

Interpretation:

The structure of 4,6-diethyl-3-methyl-3-octanol along with its oxidation reaction has to be given.

Concept Introduction:

Refer to part (a).

Answer 12

(d)

Interpretation Introduction

Interpretation:

The structure of 5-bromo-4-octanol along with its oxidation reaction has to be given.

Concept Introduction:

Refer to part (a).

Answer 13

(d)

Interpretation Introduction

Interpretation:

The structure of 5-bromo-4-octanol along with its oxidation reaction has to be given.

Concept Introduction:

Refer to part (a).

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 13.1 - Which member in each of the following pairs will...Ch. 13.1 - Which member in each of the following pairs will...Ch. 13.1 - Prob. 13.3Q Ch. 13.1 - Prob. 13.4Q Ch. 13.2 - Prob. 13.1PP Ch. 13.2 - Prob. 13.2PP Ch. 13.2 - Prob. 13.3PP Ch. 13.2 - Prob. 13.4PP Ch. 13.2 - Prob. 13.5Q Ch. 13.2 - Write the condensed formula for each of the...

Interpretation: The structure of 4-methyl-1-pentanol along with its oxidation reaction has to be given. Concept Introduction: Refer to part (a).

Interpretation: The structure of 4,6-diethyl-3-methyl-3-octanol along with its oxidation reaction has to be given. Concept Introduction: Refer to part (a).

Interpretation: The structure of 5-bromo-4-octanol along with its oxidation reaction has to be given. Concept Introduction: Refer to part (a).

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Chapter 13 Solutions

Interpretation:

The structure of 4-methyl-1-pentanol along with its oxidation reaction has to be given.

Concept Introduction:

Refer to part (a).

Interpretation:

The structure of 4,6-diethyl-3-methyl-3-octanol along with its oxidation reaction has to be given.

Concept Introduction:

Refer to part (a).

Interpretation:

The structure of 5-bromo-4-octanol along with its oxidation reaction has to be given.

Concept Introduction:

Refer to part (a).