1 Chemistry: The Science Of Change 2 Atoms And The Periodic Table 3 Quantum Theory And The Electronic Structure Of Atoms 4 Periodic Trends Of Elements 5 Ionic And Covalent Compounds 6 Representing Molecules 7 Molecular Geometry, Intermolecular Forces, And Bonding Theories 8 Chemical Reactions 9 Chemical Reactions In Aqueous Solutions 10 Energy Changes In Chemical Reactions 11 Gases 12 Liquids And Solids 13 Physical Properties Of Solutions 14 Entropy And Free Energy 15 Chemical Equilibrium 16 Acids, Bases, And Salts 17 Acid-base Equilibria And Solubility Equilibria 18 Electrochemistry 19 Chemical Kinetics 20 Nuclear Chemistry 21 Metallurgy And The Chemistry Of Metals 22 Coordination Chemistry 23 Organic Chemistry 24 Modern Materials expand_more
13.1 Types Of Solutions 13.2 A Molecular View Of The Solution Process 13.3 Concentration Units 13.4 Factors That Affect Solubility 13.5 Colligative Properties 13.6 Calculations Using Colligative Properties 13.7 Colloids Chapter Questions expand_more
Problem 13.1QP Problem 13.2QP Problem 13.3QP Problem 13.4QP Problem 13.5QP Problem 13.6QP Problem 13.7QP: Explain why dissolving a solid almost always leads to an increase in disorder. Problem 13.8QP: Describe the factors that affect the solubility of a solid in a liquid. What does it mean to say... Problem 13.9QP Problem 13.10QP Problem 13.11QP: Arrange the following compounds in order of increasing solubility in water: O2, LiCl, Br2, methanol... Problem 13.12QP Problem 13.13QP Problem 13.14QP Problem 13.15QP Problem 13.16QP Problem 13.17QP Problem 13.18QP Problem 13.19QP Problem 13.20QP Problem 13.21QP Problem 13.22QP Problem 13.23QP Problem 13.24QP Problem 13.25QP: Fish breathe the dissolved air in water through their gills. Assuming the partial pressures of... Problem 13.26QP Problem 13.27QP: Discuss the factors that influence the solubility of a gas in a liquid. Problem 13.28QP: What is thermal pollution? Why is it harmful to aquatic life? Problem 13.29QP Problem 13.30QP: A student is observing two beakers of water. One beaker is heated to 30C, and the other is heated to... Problem 13.31QP: A man bought a goldfish in a pet shop. Upon returning home, he put the goldfish in a bowl of... Problem 13.32QP: A 3.20-g sample of a salt dissolves in 9.10 g of water to give a saturated solution at 25C. What is... Problem 13.33QP: The solubility of KNO3 is 155 g per 100 g of water at 75C and 38.0 g at 25C. What mass (in grams) of... Problem 13.34QP Problem 13.35QP: The solubility of CO2 in water at 25C and 1 atm is 0.034 mol/L. What is its solubility under... Problem 13.36QP: The solubility of N2 in blood at 37C and at a partial pressure of 0.80 atm is 5.6 104 mol/L. A... Problem 13.37QP: The difference between water-soluble and fat-soluble vitamins is their molecular structures.... Problem 13.38QP: Predict whether each vitamin will be water soluble or fat soluble. (Sec Problem 13.37.) Problem 13.39QP Problem 13.40QP: The first diagram represents an open system with two different gases dissolved in water. Which of... Problem 13.41QP: The diagrams represent an aqueous solution at two different temperatures. In both diagrams, the... Problem 13.42QP Problem 13.43QP Problem 13.44QP: Write the equation representing Raoults law, and express it in words. Problem 13.45QP Problem 13.46QP: Write the equations relating boiling-point elevation and freezing-point depression to the... Problem 13.47QP Problem 13.48QP Problem 13.49QP: What is osmosis? What is a semipermeable membrane? Problem 13.50QP Problem 13.51QP Problem 13.52QP Problem 13.53QP: What are ion pairs? What effect does ion-pair formation have on the colligative properties of a... Problem 13.54QP Problem 13.55QP Problem 13.56QP Problem 13.57QP Problem 13.58QP: The vapor pressure of benzene is 100.0 mmHg at 26.1C. Calculate the vapor pressure of a solution... Problem 13.59QP: The vapor pressures of ethanol (C2H5OH) and 1-propanol (C3H7OH) at 35C are 100 and 37.6 mmHg,... Problem 13.60QP: The vapor pressure of ethanol (C2H5OH) at 20C is 44 mmHg, and the vapor pressure of methanol (CH3OH)... Problem 13.61QP Problem 13.62QP: What arc the boiling point and freezing point of a 3.12-m solution of naphthalene in benzene? (The... Problem 13.63QP Problem 13.64QP: How many liters of the antifreeze ethylene glycol [CH2(OH)CH2(OH)] would you add to a car radiator... Problem 13.65QP Problem 13.66QP Problem 13.67QP: What are the normal freezing points and boiling points of the following solutions: (a) 21.2 g NaCl... Problem 13.68QP: At 25C, the vapor pressure of pure water is 23.76 mmHg and that of seawater is 22 .98 mmHg. Assuming... Problem 13.69QP: Both NaCl and CaCl2 are used to melt ice on roads and sidewalks m winter. What advantages do these... Problem 13.70QP: A 0.86 percent by mass solution of NaCl is called physiological saline because its osmotic pressure... Problem 13.71QP Problem 13.72QP: Calculate the osmotic pressure of a 0.0500 M MgSO4 solution at 25C. Problem 13.73QP: The tallest trees known are the redwoods in California. Assuming the height of a redwood to be 105 m... Problem 13.74QP: Calculate the difference in osmotic pressure (in atm) at die normal body temperature between the... Problem 13.75QP Problem 13.76QP: Consider two aqueous solutions, one of sucrose (C12H22O11) and the other of nitric acid (HNO3). Both... Problem 13.77QP: Arrange the following solutions in order of decreasing freezing point: 0.10 m Na3PO4, 0.35 m NaCl,... Problem 13.78QP Problem 13.79QP: Indicate which compound in each of the following pairs is more likely to form ion pairs in water:... Problem 13.80QP: Describe how you would use freezing-point depression and osmotic pressure measurements to determine... Problem 13.81QP Problem 13.82QP: The elemental analysis of an organic solid extracted from gum arabic (a gummy substance used in... Problem 13.83QP: A solution of 2.50 g of a compound having the empirical formula C6H5P m 25.0 g of benzene is... Problem 13.84QP: The molar mass of benzoic acid (C6H5COOH) determined by measuring the freezing-point depression in... Problem 13.85QP: A solution containing 0.8330 g of a polymer of unknown structure in 170.0 mL of an organic solvent... Problem 13.86QP Problem 13.87QP: A solution of 6.S5 g of a carbohydrate m 100.0 g of water has a density of 1.024 g/mL and an osmotic... Problem 13.88QP: A 0.036-M aqueous nitrous acid (HNO2) solution has an osmotic pressure of 0.93 atm at 25C. Calculate... Problem 13.89QP Problem 13.90QP Problem 13.91QP Problem 13.92QP Problem 13.93QP Problem 13.94QP: Lysozyme is an enzyme that cleaves bacterial cell walls. A sample of lysozyme extracted from egg... Problem 13.95QP: The blood sugar (glucose) level of a diabetic patient is approximately 0.140 g of glucose/100 mL of... Problem 13.96QP: Trees in cold climates may be subjected to temperatures as low as 60C. Estimate the concentration of... Problem 13.97QP Problem 13.98QP: Two liquids A and B have vapor pressures of 76 and 132 mmHg, respectively, at 25C. What is the total... Problem 13.99QP: Determine the van't Hoff factor of Na3PO4 in a 0.40-m solution whose freezing point is 2.6C. Problem 13.100QP Problem 13.101QP: Consider the three mercury manometers shown in the diagram. One of them has 1 mL of water on top of... Problem 13.102QP: A forensic chemist is given a white powder for analysis. She dissolves 0.50 g of the substance in... Problem 13.103QP Problem 13.104QP: A solution of 1.00 g of anhydrous aluminum chloride (AICl3) in 50.0 g of water freezes at 1.11C.... Problem 13.105QP: Explain why reverse osmosis is (theoretically) more desirable as a desalination method than... Problem 13.106QP: What masses of sodium chloride, magnesium chloride, sodium sulfate, calcium chloride, potassium... Problem 13.107QP: The osmotic pressure of blood plasma is approximately 7.5 atm at 37C. Estimate the total... Problem 13.108QP Problem 13.109QP: A protein has been isolated as a salt with the formula Na20P (this notation means that there are 20... Problem 13.110QP: A nonvolatile organic compound Z was used to make up two solutions. Solution A contains 5.00 g of Z... Problem 13.111QP Problem 13.112QP: State which of the alcohols listed in Problem 13.12 you would expect to be the best solvent for each... Problem 13.113QP: Before a carbonated beverage bottle is sealed, it is pressurized with a mixture of air and carbon... Problem 13.114QP: Iodine (I2) is only sparingly soluble in water (left photo). Yet upon the addition of iodide ions... Problem 13.115QP: (a) The root cells of plants contain a solution that is hypertonic in relation to water in the soil.... Problem 13.116QP: Hemoglobin, the oxygen-transport protein, binds about 1.35 mL of oxygen per gram of the protein. The... Problem 13.117QP Problem 13.118QP: In the apparatus shown, what will happen if the membrane is (a) permeable to both water and the Na+... Problem 13.119QP: Concentrated hydrochloric acid is usually available at a concentration of 37.7 percent by mass. What... Problem 13.120QP: Explain each of the following statements: (a) The boiling point of seawater is higher than that of... Problem 13.121QP Problem 13.122QP: A 1.32-g sample of a mixture of cyclohexane (C6H12) and naphthalene (C10H8) is dissolved in 18.9 g... Problem 13.123QP: How does each of the following affect the solubility of an ionic compound: (a) lattice energy, (b)... Problem 13.124QP: A solution contains two volatile liquids A and B. Complete the following table, in which the symbol ... Problem 13.125QP Problem 13.126QP: A mixture of ethanol and 1-propanol behaves ideally at 36C and is in equilibrium with its vapor. If... Problem 13.127QP: Ammonia (NH3) is very soluble in water, but nitrogen trichloride (NCl3) is not. Explain. Problem 13.128QP: For ideal solutions, the volumes are additive. This means that if 5 mL of A and 5 mL of B form an... Problem 13.129QP: Acetic acid is a weak acid that ionizes in solution as follows: If the freezing point of a 0.106 m... Problem 13.130QP: Which vitamins (sec the given structures) do you expect to be water soluble? (See Problem 13.37.) Problem 13.131QP: Calculate the percent by mass of the solute in each of the following aqueous solutions: (a) 5.75 g... Problem 13.132QP: Acetic acid is a polar molecule and can form hydrogen bonds with water molecules. Therefore, it has... Problem 13.133QP Problem 13.134QP: Fish in the Antarctic Ocean swim in water at about 2C. (a) To prevent their blood from freezing,... Problem 13.135QP: Why are ice cubes (e.g., those you see in the trays in the freezer of a refrigerator) cloudy inside? Problem 13.136QP Problem 13.137QP: Two beakers are placed in a closed container Beaker A initially contains 0.15 mole of naphthalene... Problem 13.138QP: (a) Derive the equation relating the molality (m) of a solution to its molarity (M) m=mdMM1000 where... Problem 13.139QP: At 27C, the vapor pressure of pure water is 23.76 mmHg and that of an aqueous solution of urea is... Problem 13.140QP: A very long pipe is capped at one end with a semipermeable membrane. How deep (in meters) must the... Problem 13.141QP: A mixture of liquids A and B exhibits ideal behavior At 84C, the total vapor pressure of a solution... Problem 13.142QP: Use Henrys law and the ideal gas equation to prove the statement that the volume of a gas that... Problem 13.143QP Problem 13.144QP Problem 13.145QP: The diagram here shows vapor pressure curves for pure benzene and a solution of a non-volatile... Problem 13.146QP: Valinomycin is an antibiotic. It functions by binding K+ ions and transporting them across the... Problem 13.147QP Problem 13.148QP Problem 13.149QP Problem 13.150QP: Explain why we cannot use osmotic pressure to determine both molar mass and percent ionization for... Problem 13.1KSP: Which of the following processes is accompanied by an increase in entropy? (Select all that apply.)... Problem 13.2KSP: For each of the processes depicted here, determine if it is endothermic or exothermic, or if there... Problem 13.3KSP: For each of the processes depicted here, determine if it is endothermic or exothermic, or if there... Problem 13.4KSP format_list_bulleted