Chemistry for Engineering Students
4th Edition
ISBN: 9781337398909
Author: Lawrence S. Brown, Tom Holme
Publisher: Cengage Learning
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Textbook Question
Chapter 13, Problem 13.53PAE
What product forms from the lead components of a lead storage battery? Why does mechanical shock (bumps) ultimately degrade the performance of the lead storage battery?
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(c) The following data have been obtained for the hydrolysis of sucrose, C12H22O11, to
glucose, C6H12O6, and fructose C6H12O6, in acidic solution:
C12H22O11 + H2O → C6H12O6 + C6H12O6
[sucrose]/mol dm³
t/min
0
0.316
14
0.300
39
0.274
60
0.256
80
0.238
110
0.211
(i) Graphically prove the order of the reaction and determine the rate constant of the
reaction.
(ii) Determine the half-life, t½ for the hydrolysis of sucrose.
(III) adsorbent
(b) Adsorption of the hexacyanoferrate (III) ion, [Fe(CN)6] ³, on y-Al2O3 from aqueous
solution was examined. The adsorption was modelled using a modified Langmuir
isotherm, yielding the following values of Kat pH = 6.5:
(ii)
T/K
10-10 K
280
2.505
295
1.819
310
1.364
325
1.050
Determine the enthalpy of adsorption, AadsHⓇ.
If the reported value of entropy of adsorption, Aads Se = 146 J K-1 mol-1 under the above
conditions, determine Aads Gº.
with full details solution please
Chapter 13 Solutions
Chemistry for Engineering Students
Ch. 13 - Prob. 1COCh. 13 - Prob. 2COCh. 13 - • write and balance half-reactions for simple...Ch. 13 - Prob. 4COCh. 13 - Prob. 5COCh. 13 - • use standard reduction potentials to predict the...Ch. 13 - • calculate the amount of metal plated, the amount...Ch. 13 - Prob. 8COCh. 13 - Prob. 9COCh. 13 - Prob. 10CO
Ch. 13 - Prob. 13.1PAECh. 13 - Prob. 13.2PAECh. 13 - Prob. 13.3PAECh. 13 - Prob. 13.4PAECh. 13 - For the following oxidationreduction reactions,...Ch. 13 - Which half-reaction takes place at the anode of an...Ch. 13 - If a salt bridge contains KNO3 as its electrolyte,...Ch. 13 - If a salt bridge contains KNO3 as its electrolyte,...Ch. 13 - The following oxidationreduction reactions are...Ch. 13 - Write a balanced chemical equation for the overall...Ch. 13 - For the reactions in parts (a) and (b) in the...Ch. 13 - Explain why the terms cell potential and...Ch. 13 - How does galvanic corrosion differ from uniform...Ch. 13 - Prob. 13.14PAECh. 13 - A student who has mercury amalgam fillings in some...Ch. 13 - Based on the cell potential measured for the cells...Ch. 13 - Prob. 13.17PAECh. 13 - Four voltaic cells are set up. In each, one...Ch. 13 - In tables of standard reduction potentials that...Ch. 13 - In the table of standard reduction potentials,...Ch. 13 - Using values from the table of standard reduction...Ch. 13 - Using values from the table of standard reduction...Ch. 13 - One half-cell in a voltaic cell is constructed...Ch. 13 - Four metals, A, B, C, and D, exhibit the following...Ch. 13 - Use the Nernst equation to calculate the cell...Ch. 13 - One half-cell in a voltaic cell is constructed...Ch. 13 - We noted that a tin-plated steel can corrodes more...Ch. 13 - The following half-cells are available: Ag(s);...Ch. 13 - Prob. 13.29PAECh. 13 - Prob. 13.30PAECh. 13 - In May 2000, a concrete pedestrian walkway...Ch. 13 - Prob. 13.32PAECh. 13 - Calculate the standard free energy change for the...Ch. 13 - Suppose that you cannot find a table of standard...Ch. 13 - Prob. 13.35PAECh. 13 - Which of the following reactions is (are)...Ch. 13 - Consult a table of standard reduction potentials...Ch. 13 - The equilibrium constant for a reaction is 31015...Ch. 13 - Some calculators cannot display results of an...Ch. 13 - Calculate the equilibrium constant for the...Ch. 13 - Use the standard reduction potentials for the...Ch. 13 - Hydrogen peroxide is often stored in the...Ch. 13 - Calculate the equilibrium constant for the redox...Ch. 13 - An engineer is assigned to design an...Ch. 13 - A magnesium bar with a mass of 6.0 kg is attached...Ch. 13 - Prob. 13.46PAECh. 13 - Prob. 13.47PAECh. 13 - Prob. 13.48PAECh. 13 - Prob. 13.49PAECh. 13 - If you put a 9-volt battery in a smoke detector in...Ch. 13 - If alkaline batteries were not alkaline but rather...Ch. 13 - What would happen to the voltage of an alkaline...Ch. 13 - What product forms from the lead components of a...Ch. 13 - Prob. 13.54PAECh. 13 - Prob. 13.55PAECh. 13 - Assume the specifications of a Ni-Cd voltaic cell...Ch. 13 - Prob. 13.57PAECh. 13 - What is the difference between active and passive...Ch. 13 - Prob. 13.59PAECh. 13 - Prob. 13.60PAECh. 13 - In an electroplating operation, the cell potential...Ch. 13 - Prob. 13.62PAECh. 13 - Prob. 13.63PAECh. 13 - Prob. 13.64PAECh. 13 - Use the Internet to find electroplating companies...Ch. 13 - Prob. 13.66PAECh. 13 - If a current of 15 A is run through an...Ch. 13 - Suppose somebody in a laboratory doesn't quite...Ch. 13 - If a barrel plating run uses 200.0 A for exactly 6...Ch. 13 - An electrical engineer is analyzing an...Ch. 13 - In a copper plating experiment in which copper...Ch. 13 - A metallurgist wants to gold-plate a thin sheet...Ch. 13 - Tin-plated steel is used for "tin" cans. Suppose...Ch. 13 - An electrolysis cell for aluminum production...Ch. 13 - If a plating line that deposits nickel (from NiCl2...Ch. 13 - Prob. 13.76PAECh. 13 - Prob. 13.77PAECh. 13 - A small part with a surface area of 2.62 cm2 is...Ch. 13 - An engineer is designing a mirror for an optical...Ch. 13 - Prob. 13.80PAECh. 13 - Prob. 13.81PAECh. 13 - What characteristic of lithium ions makes it...Ch. 13 - Looking at Figure 13.23, describe how the...Ch. 13 - Prob. 13.84PAECh. 13 - What is the role of a salt bridge in the...Ch. 13 - Prob. 13.86PAECh. 13 - If the SHE was assigned a value of 3.00 V rather...Ch. 13 - Prob. 13.88PAECh. 13 - Prob. 13.89PAECh. 13 - A chemical engineering student is studying the...Ch. 13 - Prob. 13.91PAECh. 13 - If a logarithmic scale had not been used for the...Ch. 13 - Battery manufacturers often assess batteries in...Ch. 13 - Prob. 13.94PAECh. 13 - Prob. 13.95PAECh. 13 - Prob. 13.96PAECh. 13 - As the voltaic cell shown here runs, the blue...Ch. 13 - Prob. 13.98PAECh. 13 - For a voltage-sensitive application, you are...Ch. 13 - Prob. 13.100PAECh. 13 - Prob. 13.101PAECh. 13 - Prob. 13.102PAECh. 13 - Prob. 13.103PAECh. 13 - 13.104 (a) What happens when a current is passed...Ch. 13 - A current is passed through a solution of...Ch. 13 - 13.106 Hydrazine, N2H4 , has been proposed as the...Ch. 13 - Prob. 13.107PAE
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- Zeroth Order Reaction In a certain experiment the decomposition of hydrogen iodide on finely divided gold is zeroth order with respect to HI. 2HI(g) Au H2(g) + 12(9) Rate = -d[HI]/dt k = 2.00x104 mol L-1 s-1 If the experiment has an initial HI concentration of 0.460 mol/L, what is the concentration of HI after 28.0 minutes? 1 pts Submit Answer Tries 0/5 How long will it take for all of the HI to decompose? 1 pts Submit Answer Tries 0/5 What is the rate of formation of H2 16.0 minutes after the reaction is initiated? 1 pts Submit Answer Tries 0/5arrow_forwardangelarodriguezmunoz149@gmail.com Hi i need help with this question i am not sure what the right answers are.arrow_forwardPlease correct answer and don't used hand raitingarrow_forward
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