Chemistry for Engineering Students
4th Edition
ISBN: 9781337398909
Author: Lawrence S. Brown, Tom Holme
Publisher: Cengage Learning
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Chapter 13, Problem 13.91PAE
Interpretation Introduction
Interpretation:
If nickel, make an acceptable sacrificial anode to protect steel should be explained.
Concept introduction:
Sacrificial anodes are those metals which are used as protective layers on metals. Sacrifice anode metals are corroded first in comparison to another metal due to the potential difference.
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81. a. Propose a mechanism for the following reaction:
OH
CH2=CHCHC=N
b. What is the product of the following reaction?
HO
H₂O
N=CCH2CH2CH
OH
HO
CH3CCH=CH2
H₂O
C=N
82. Unlike a phosphonium ylide that reacts with an aldehyde or a ketone to form an alkene a sulfonium ulia
For each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check
the appropriate box.
Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below.
Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions
- just focus on the first stable product you expect to form in solution.
?
NH2
MgBr
Will the first product that forms in this reaction
create a new CC bond?
○ Yes
○ No
MgBr
?
Will the first product that forms in this reaction
create a new CC bond?
O Yes
O No
Click and drag to start drawing a
structure.
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c
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Ar
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Predicting
As the lead product manager at OrganometALEKS Industries, you are trying to decide if the following reaction will make a molecule
with a new C - C bond as its major product:
H₂N
O
H
1.
?
2. H3O+
If this reaction will work, draw the major organic product or products you would expect in the drawing area below. If there's more
than one major product, you can draw them in any arrangement you like. Be sure you use wedge and dash bonds if necessary, for
example to distinguish between major products with different stereochemistry.
0
If the major products of this reaction won't have a new CC bond, just check the box under the drawing area and leave it blank.
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Explanation
Check
Click and drag to start drawing a
structure.
Chapter 13 Solutions
Chemistry for Engineering Students
Ch. 13 - Prob. 1COCh. 13 - Prob. 2COCh. 13 - • write and balance half-reactions for simple...Ch. 13 - Prob. 4COCh. 13 - Prob. 5COCh. 13 - • use standard reduction potentials to predict the...Ch. 13 - • calculate the amount of metal plated, the amount...Ch. 13 - Prob. 8COCh. 13 - Prob. 9COCh. 13 - Prob. 10CO
Ch. 13 - Prob. 13.1PAECh. 13 - Prob. 13.2PAECh. 13 - Prob. 13.3PAECh. 13 - Prob. 13.4PAECh. 13 - For the following oxidationreduction reactions,...Ch. 13 - Which half-reaction takes place at the anode of an...Ch. 13 - If a salt bridge contains KNO3 as its electrolyte,...Ch. 13 - If a salt bridge contains KNO3 as its electrolyte,...Ch. 13 - The following oxidationreduction reactions are...Ch. 13 - Write a balanced chemical equation for the overall...Ch. 13 - For the reactions in parts (a) and (b) in the...Ch. 13 - Explain why the terms cell potential and...Ch. 13 - How does galvanic corrosion differ from uniform...Ch. 13 - Prob. 13.14PAECh. 13 - A student who has mercury amalgam fillings in some...Ch. 13 - Based on the cell potential measured for the cells...Ch. 13 - Prob. 13.17PAECh. 13 - Four voltaic cells are set up. In each, one...Ch. 13 - In tables of standard reduction potentials that...Ch. 13 - In the table of standard reduction potentials,...Ch. 13 - Using values from the table of standard reduction...Ch. 13 - Using values from the table of standard reduction...Ch. 13 - One half-cell in a voltaic cell is constructed...Ch. 13 - Four metals, A, B, C, and D, exhibit the following...Ch. 13 - Use the Nernst equation to calculate the cell...Ch. 13 - One half-cell in a voltaic cell is constructed...Ch. 13 - We noted that a tin-plated steel can corrodes more...Ch. 13 - The following half-cells are available: Ag(s);...Ch. 13 - Prob. 13.29PAECh. 13 - Prob. 13.30PAECh. 13 - In May 2000, a concrete pedestrian walkway...Ch. 13 - Prob. 13.32PAECh. 13 - Calculate the standard free energy change for the...Ch. 13 - Suppose that you cannot find a table of standard...Ch. 13 - Prob. 13.35PAECh. 13 - Which of the following reactions is (are)...Ch. 13 - Consult a table of standard reduction potentials...Ch. 13 - The equilibrium constant for a reaction is 31015...Ch. 13 - Some calculators cannot display results of an...Ch. 13 - Calculate the equilibrium constant for the...Ch. 13 - Use the standard reduction potentials for the...Ch. 13 - Hydrogen peroxide is often stored in the...Ch. 13 - Calculate the equilibrium constant for the redox...Ch. 13 - An engineer is assigned to design an...Ch. 13 - A magnesium bar with a mass of 6.0 kg is attached...Ch. 13 - Prob. 13.46PAECh. 13 - Prob. 13.47PAECh. 13 - Prob. 13.48PAECh. 13 - Prob. 13.49PAECh. 13 - If you put a 9-volt battery in a smoke detector in...Ch. 13 - If alkaline batteries were not alkaline but rather...Ch. 13 - What would happen to the voltage of an alkaline...Ch. 13 - What product forms from the lead components of a...Ch. 13 - Prob. 13.54PAECh. 13 - Prob. 13.55PAECh. 13 - Assume the specifications of a Ni-Cd voltaic cell...Ch. 13 - Prob. 13.57PAECh. 13 - What is the difference between active and passive...Ch. 13 - Prob. 13.59PAECh. 13 - Prob. 13.60PAECh. 13 - In an electroplating operation, the cell potential...Ch. 13 - Prob. 13.62PAECh. 13 - Prob. 13.63PAECh. 13 - Prob. 13.64PAECh. 13 - Use the Internet to find electroplating companies...Ch. 13 - Prob. 13.66PAECh. 13 - If a current of 15 A is run through an...Ch. 13 - Suppose somebody in a laboratory doesn't quite...Ch. 13 - If a barrel plating run uses 200.0 A for exactly 6...Ch. 13 - An electrical engineer is analyzing an...Ch. 13 - In a copper plating experiment in which copper...Ch. 13 - A metallurgist wants to gold-plate a thin sheet...Ch. 13 - Tin-plated steel is used for "tin" cans. Suppose...Ch. 13 - An electrolysis cell for aluminum production...Ch. 13 - If a plating line that deposits nickel (from NiCl2...Ch. 13 - Prob. 13.76PAECh. 13 - Prob. 13.77PAECh. 13 - A small part with a surface area of 2.62 cm2 is...Ch. 13 - An engineer is designing a mirror for an optical...Ch. 13 - Prob. 13.80PAECh. 13 - Prob. 13.81PAECh. 13 - What characteristic of lithium ions makes it...Ch. 13 - Looking at Figure 13.23, describe how the...Ch. 13 - Prob. 13.84PAECh. 13 - What is the role of a salt bridge in the...Ch. 13 - Prob. 13.86PAECh. 13 - If the SHE was assigned a value of 3.00 V rather...Ch. 13 - Prob. 13.88PAECh. 13 - Prob. 13.89PAECh. 13 - A chemical engineering student is studying the...Ch. 13 - Prob. 13.91PAECh. 13 - If a logarithmic scale had not been used for the...Ch. 13 - Battery manufacturers often assess batteries in...Ch. 13 - Prob. 13.94PAECh. 13 - Prob. 13.95PAECh. 13 - Prob. 13.96PAECh. 13 - As the voltaic cell shown here runs, the blue...Ch. 13 - Prob. 13.98PAECh. 13 - For a voltage-sensitive application, you are...Ch. 13 - Prob. 13.100PAECh. 13 - Prob. 13.101PAECh. 13 - Prob. 13.102PAECh. 13 - Prob. 13.103PAECh. 13 - 13.104 (a) What happens when a current is passed...Ch. 13 - A current is passed through a solution of...Ch. 13 - 13.106 Hydrazine, N2H4 , has been proposed as the...Ch. 13 - Prob. 13.107PAE
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