For the given molecule, whether cis‑trans isomerism is possible has to be indicated. Concept Introduction: Alkenes are hydrocarbons that contain at least one double bond in it. There will not be any free rotation of the double bond in alkene. Hence, cis‑trans isomerism is possible. The first and foremost condition for the alkene to exhibit cis‑trans isomerism is that the carbon attached in either end of double bond must have different groups attached to it. A cis isomer is the one in which the same groups are present on same side of both the carbon atoms present in the double bond. A trans isomer is the one in which the same groups are present on opposite side of both the carbon atoms present in the double bond. Cis‑trans isomerism is not possible if any one of the carbon atom bonded to the double bond bears two identical groups. Cis‑trans isomers are not constitutional isomers but they are stereoisomers.

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Answer 1

Question

Chapter 13, Problem 13.53EP

(a)

Interpretation Introduction

Interpretation:

For the given molecule, whether cis‑trans isomerism is possible has to be indicated.

Concept Introduction:

Alkenes are hydrocarbons that contain at least one double bond in it. There will not be any free rotation of the double bond in alkene. Hence, cis‑trans isomerism is possible. The first and foremost condition for the alkene to exhibit cis‑trans isomerism is that the carbon attached in either end of double bond must have different groups attached to it.

A cis isomer is the one in which the same groups are present on same side of both the carbon atoms present in the double bond.

A trans isomer is the one in which the same groups are present on opposite side of both the carbon atoms present in the double bond.

Cis‑trans isomerism is not possible if any one of the carbon atom bonded to the double bond bears two identical groups.

Cis‑trans isomers are not constitutional isomers but they are stereoisomers.

(b)

Interpretation Introduction

Interpretation:

For the given molecule, whether cis‑trans isomerism is possible has to be indicated.

Concept Introduction:

Alkenes are hydrocarbons that contain at least one double bond in it. There will not be any free rotation of the double bond in alkene. Hence, cis‑trans isomerism is possible. The first and foremost condition for the alkene to exhibit cis‑trans isomerism is that the carbon attached in either end of double bond must have different groups attached to it.

A cis isomer is the one in which the same groups are present on same side of both the carbon atoms present in the double bond.

A trans isomer is the one in which the same groups are present on opposite side of both the carbon atoms present in the double bond.

Cis‑trans isomerism is not possible if any one of the carbon atom bonded to the double bond bears two identical groups.

Cis‑trans isomers are not constitutional isomers but they are stereoisomers.

(c)

Interpretation Introduction

Interpretation:

For the given molecule, whether cis‑trans isomerism is possible has to be indicated.

Concept Introduction:

Alkenes are hydrocarbons that contain at least one double bond in it. There will not be any free rotation of the double bond in alkene. Hence, cis‑trans isomerism is possible. The first and foremost condition for the alkene to exhibit cis‑trans isomerism is that the carbon attached in either end of double bond must have different groups attached to it.

A cis isomer is the one in which the same groups are present on same side of both the carbon atoms present in the double bond.

A trans isomer is the one in which the same groups are present on opposite side of both the carbon atoms present in the double bond.

Cis‑trans isomerism is not possible if any one of the carbon atom bonded to the double bond bears two identical groups.

Cis‑trans isomers are not constitutional isomers but they are stereoisomers.

(d)

Interpretation Introduction

Interpretation:

For the given molecule, whether cis‑trans isomerism is possible has to be indicated.

Concept Introduction:

Alkenes are hydrocarbons that contain at least one double bond in it. There will not be any free rotation of the double bond in alkene. Hence, cis‑trans isomerism is possible. The first and foremost condition for the alkene to exhibit cis‑trans isomerism is that the carbon attached in either end of double bond must have different groups attached to it.

A cis isomer is the one in which the same groups are present on same side of both the carbon atoms present in the double bond.

A trans isomer is the one in which the same groups are present on opposite side of both the carbon atoms present in the double bond.

Cis‑trans isomerism is not possible if any one of the carbon atom bonded to the double bond bears two identical groups.

Cis‑trans isomers are not constitutional isomers but they are stereoisomers.

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Answer 2

Question

Chapter 13, Problem 13.53EP

(a)

Interpretation Introduction

Interpretation:

For the given molecule, whether cis‑trans isomerism is possible has to be indicated.

Concept Introduction:

Alkenes are hydrocarbons that contain at least one double bond in it. There will not be any free rotation of the double bond in alkene. Hence, cis‑trans isomerism is possible. The first and foremost condition for the alkene to exhibit cis‑trans isomerism is that the carbon attached in either end of double bond must have different groups attached to it.

A cis isomer is the one in which the same groups are present on same side of both the carbon atoms present in the double bond.

A trans isomer is the one in which the same groups are present on opposite side of both the carbon atoms present in the double bond.

Cis‑trans isomerism is not possible if any one of the carbon atom bonded to the double bond bears two identical groups.

Cis‑trans isomers are not constitutional isomers but they are stereoisomers.

(b)

Interpretation Introduction

Interpretation:

For the given molecule, whether cis‑trans isomerism is possible has to be indicated.

Concept Introduction:

Alkenes are hydrocarbons that contain at least one double bond in it. There will not be any free rotation of the double bond in alkene. Hence, cis‑trans isomerism is possible. The first and foremost condition for the alkene to exhibit cis‑trans isomerism is that the carbon attached in either end of double bond must have different groups attached to it.

A cis isomer is the one in which the same groups are present on same side of both the carbon atoms present in the double bond.

A trans isomer is the one in which the same groups are present on opposite side of both the carbon atoms present in the double bond.

Cis‑trans isomerism is not possible if any one of the carbon atom bonded to the double bond bears two identical groups.

Cis‑trans isomers are not constitutional isomers but they are stereoisomers.

(c)

Interpretation Introduction

Interpretation:

For the given molecule, whether cis‑trans isomerism is possible has to be indicated.

Concept Introduction:

Alkenes are hydrocarbons that contain at least one double bond in it. There will not be any free rotation of the double bond in alkene. Hence, cis‑trans isomerism is possible. The first and foremost condition for the alkene to exhibit cis‑trans isomerism is that the carbon attached in either end of double bond must have different groups attached to it.

A cis isomer is the one in which the same groups are present on same side of both the carbon atoms present in the double bond.

A trans isomer is the one in which the same groups are present on opposite side of both the carbon atoms present in the double bond.

Cis‑trans isomerism is not possible if any one of the carbon atom bonded to the double bond bears two identical groups.

Cis‑trans isomers are not constitutional isomers but they are stereoisomers.

(d)

Interpretation Introduction

Interpretation:

For the given molecule, whether cis‑trans isomerism is possible has to be indicated.

Concept Introduction:

Alkenes are hydrocarbons that contain at least one double bond in it. There will not be any free rotation of the double bond in alkene. Hence, cis‑trans isomerism is possible. The first and foremost condition for the alkene to exhibit cis‑trans isomerism is that the carbon attached in either end of double bond must have different groups attached to it.

A cis isomer is the one in which the same groups are present on same side of both the carbon atoms present in the double bond.

A trans isomer is the one in which the same groups are present on opposite side of both the carbon atoms present in the double bond.

Cis‑trans isomerism is not possible if any one of the carbon atom bonded to the double bond bears two identical groups.

Cis‑trans isomers are not constitutional isomers but they are stereoisomers.

Expert Solution & Answer

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Answer 3

Question

Chapter 13, Problem 13.53EP

(a)

Interpretation Introduction

Interpretation:

For the given molecule, whether cis‑trans isomerism is possible has to be indicated.

Concept Introduction:

Alkenes are hydrocarbons that contain at least one double bond in it. There will not be any free rotation of the double bond in alkene. Hence, cis‑trans isomerism is possible. The first and foremost condition for the alkene to exhibit cis‑trans isomerism is that the carbon attached in either end of double bond must have different groups attached to it.

A cis isomer is the one in which the same groups are present on same side of both the carbon atoms present in the double bond.

A trans isomer is the one in which the same groups are present on opposite side of both the carbon atoms present in the double bond.

Cis‑trans isomerism is not possible if any one of the carbon atom bonded to the double bond bears two identical groups.

Cis‑trans isomers are not constitutional isomers but they are stereoisomers.

(b)

Interpretation Introduction

Interpretation:

For the given molecule, whether cis‑trans isomerism is possible has to be indicated.

Concept Introduction:

Alkenes are hydrocarbons that contain at least one double bond in it. There will not be any free rotation of the double bond in alkene. Hence, cis‑trans isomerism is possible. The first and foremost condition for the alkene to exhibit cis‑trans isomerism is that the carbon attached in either end of double bond must have different groups attached to it.

A cis isomer is the one in which the same groups are present on same side of both the carbon atoms present in the double bond.

A trans isomer is the one in which the same groups are present on opposite side of both the carbon atoms present in the double bond.

Cis‑trans isomerism is not possible if any one of the carbon atom bonded to the double bond bears two identical groups.

Cis‑trans isomers are not constitutional isomers but they are stereoisomers.

(c)

Interpretation Introduction

Interpretation:

For the given molecule, whether cis‑trans isomerism is possible has to be indicated.

Concept Introduction:

Alkenes are hydrocarbons that contain at least one double bond in it. There will not be any free rotation of the double bond in alkene. Hence, cis‑trans isomerism is possible. The first and foremost condition for the alkene to exhibit cis‑trans isomerism is that the carbon attached in either end of double bond must have different groups attached to it.

A cis isomer is the one in which the same groups are present on same side of both the carbon atoms present in the double bond.

A trans isomer is the one in which the same groups are present on opposite side of both the carbon atoms present in the double bond.

Cis‑trans isomerism is not possible if any one of the carbon atom bonded to the double bond bears two identical groups.

Cis‑trans isomers are not constitutional isomers but they are stereoisomers.

(d)

Interpretation Introduction

Interpretation:

For the given molecule, whether cis‑trans isomerism is possible has to be indicated.

Concept Introduction:

Alkenes are hydrocarbons that contain at least one double bond in it. There will not be any free rotation of the double bond in alkene. Hence, cis‑trans isomerism is possible. The first and foremost condition for the alkene to exhibit cis‑trans isomerism is that the carbon attached in either end of double bond must have different groups attached to it.

A cis isomer is the one in which the same groups are present on same side of both the carbon atoms present in the double bond.

A trans isomer is the one in which the same groups are present on opposite side of both the carbon atoms present in the double bond.

Cis‑trans isomerism is not possible if any one of the carbon atom bonded to the double bond bears two identical groups.

Cis‑trans isomers are not constitutional isomers but they are stereoisomers.

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Answer 4

Question

Chapter 13, Problem 13.53EP

(a)

Interpretation Introduction

Interpretation:

For the given molecule, whether cis‑trans isomerism is possible has to be indicated.

Concept Introduction:

Alkenes are hydrocarbons that contain at least one double bond in it. There will not be any free rotation of the double bond in alkene. Hence, cis‑trans isomerism is possible. The first and foremost condition for the alkene to exhibit cis‑trans isomerism is that the carbon attached in either end of double bond must have different groups attached to it.

A cis isomer is the one in which the same groups are present on same side of both the carbon atoms present in the double bond.

A trans isomer is the one in which the same groups are present on opposite side of both the carbon atoms present in the double bond.

Cis‑trans isomerism is not possible if any one of the carbon atom bonded to the double bond bears two identical groups.

Cis‑trans isomers are not constitutional isomers but they are stereoisomers.

(b)

Interpretation Introduction

Interpretation:

For the given molecule, whether cis‑trans isomerism is possible has to be indicated.

Concept Introduction:

Alkenes are hydrocarbons that contain at least one double bond in it. There will not be any free rotation of the double bond in alkene. Hence, cis‑trans isomerism is possible. The first and foremost condition for the alkene to exhibit cis‑trans isomerism is that the carbon attached in either end of double bond must have different groups attached to it.

A cis isomer is the one in which the same groups are present on same side of both the carbon atoms present in the double bond.

A trans isomer is the one in which the same groups are present on opposite side of both the carbon atoms present in the double bond.

Cis‑trans isomerism is not possible if any one of the carbon atom bonded to the double bond bears two identical groups.

Cis‑trans isomers are not constitutional isomers but they are stereoisomers.

(c)

Interpretation Introduction

Interpretation:

For the given molecule, whether cis‑trans isomerism is possible has to be indicated.

Concept Introduction:

Alkenes are hydrocarbons that contain at least one double bond in it. There will not be any free rotation of the double bond in alkene. Hence, cis‑trans isomerism is possible. The first and foremost condition for the alkene to exhibit cis‑trans isomerism is that the carbon attached in either end of double bond must have different groups attached to it.

A cis isomer is the one in which the same groups are present on same side of both the carbon atoms present in the double bond.

A trans isomer is the one in which the same groups are present on opposite side of both the carbon atoms present in the double bond.

Cis‑trans isomerism is not possible if any one of the carbon atom bonded to the double bond bears two identical groups.

Cis‑trans isomers are not constitutional isomers but they are stereoisomers.

(d)

Interpretation Introduction

Interpretation:

For the given molecule, whether cis‑trans isomerism is possible has to be indicated.

Concept Introduction:

Alkenes are hydrocarbons that contain at least one double bond in it. There will not be any free rotation of the double bond in alkene. Hence, cis‑trans isomerism is possible. The first and foremost condition for the alkene to exhibit cis‑trans isomerism is that the carbon attached in either end of double bond must have different groups attached to it.

A cis isomer is the one in which the same groups are present on same side of both the carbon atoms present in the double bond.

A trans isomer is the one in which the same groups are present on opposite side of both the carbon atoms present in the double bond.

Cis‑trans isomerism is not possible if any one of the carbon atom bonded to the double bond bears two identical groups.

Cis‑trans isomers are not constitutional isomers but they are stereoisomers.

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Answer 5

Chapter 13, Problem 13.53EP

(a)

Interpretation Introduction

Interpretation:

For the given molecule, whether cis‑trans isomerism is possible has to be indicated.

Concept Introduction:

Alkenes are hydrocarbons that contain at least one double bond in it. There will not be any free rotation of the double bond in alkene. Hence, cis‑trans isomerism is possible. The first and foremost condition for the alkene to exhibit cis‑trans isomerism is that the carbon attached in either end of double bond must have different groups attached to it.

A cis isomer is the one in which the same groups are present on same side of both the carbon atoms present in the double bond.

A trans isomer is the one in which the same groups are present on opposite side of both the carbon atoms present in the double bond.

Cis‑trans isomerism is not possible if any one of the carbon atom bonded to the double bond bears two identical groups.

Cis‑trans isomers are not constitutional isomers but they are stereoisomers.

(b)

Interpretation Introduction

Interpretation:

For the given molecule, whether cis‑trans isomerism is possible has to be indicated.

Concept Introduction:

Alkenes are hydrocarbons that contain at least one double bond in it. There will not be any free rotation of the double bond in alkene. Hence, cis‑trans isomerism is possible. The first and foremost condition for the alkene to exhibit cis‑trans isomerism is that the carbon attached in either end of double bond must have different groups attached to it.

A cis isomer is the one in which the same groups are present on same side of both the carbon atoms present in the double bond.

A trans isomer is the one in which the same groups are present on opposite side of both the carbon atoms present in the double bond.

Cis‑trans isomerism is not possible if any one of the carbon atom bonded to the double bond bears two identical groups.

Cis‑trans isomers are not constitutional isomers but they are stereoisomers.

(c)

Interpretation Introduction

Interpretation:

For the given molecule, whether cis‑trans isomerism is possible has to be indicated.

Concept Introduction:

Alkenes are hydrocarbons that contain at least one double bond in it. There will not be any free rotation of the double bond in alkene. Hence, cis‑trans isomerism is possible. The first and foremost condition for the alkene to exhibit cis‑trans isomerism is that the carbon attached in either end of double bond must have different groups attached to it.

A cis isomer is the one in which the same groups are present on same side of both the carbon atoms present in the double bond.

A trans isomer is the one in which the same groups are present on opposite side of both the carbon atoms present in the double bond.

Cis‑trans isomerism is not possible if any one of the carbon atom bonded to the double bond bears two identical groups.

Cis‑trans isomers are not constitutional isomers but they are stereoisomers.

(d)

Interpretation Introduction

Interpretation:

For the given molecule, whether cis‑trans isomerism is possible has to be indicated.

Concept Introduction:

Alkenes are hydrocarbons that contain at least one double bond in it. There will not be any free rotation of the double bond in alkene. Hence, cis‑trans isomerism is possible. The first and foremost condition for the alkene to exhibit cis‑trans isomerism is that the carbon attached in either end of double bond must have different groups attached to it.

A cis isomer is the one in which the same groups are present on same side of both the carbon atoms present in the double bond.

A trans isomer is the one in which the same groups are present on opposite side of both the carbon atoms present in the double bond.

Cis‑trans isomerism is not possible if any one of the carbon atom bonded to the double bond bears two identical groups.

Cis‑trans isomers are not constitutional isomers but they are stereoisomers.

Answer 6

Chapter 13, Problem 13.53EP

(a)

Interpretation Introduction

Interpretation:

For the given molecule, whether cis‑trans isomerism is possible has to be indicated.

Concept Introduction:

Alkenes are hydrocarbons that contain at least one double bond in it. There will not be any free rotation of the double bond in alkene. Hence, cis‑trans isomerism is possible. The first and foremost condition for the alkene to exhibit cis‑trans isomerism is that the carbon attached in either end of double bond must have different groups attached to it.

A cis isomer is the one in which the same groups are present on same side of both the carbon atoms present in the double bond.

A trans isomer is the one in which the same groups are present on opposite side of both the carbon atoms present in the double bond.

Cis‑trans isomerism is not possible if any one of the carbon atom bonded to the double bond bears two identical groups.

Cis‑trans isomers are not constitutional isomers but they are stereoisomers.

Answer 7

Chapter 13, Problem 13.53EP

(a)

Interpretation Introduction

Interpretation:

For the given molecule, whether cis‑trans isomerism is possible has to be indicated.

Concept Introduction:

Alkenes are hydrocarbons that contain at least one double bond in it. There will not be any free rotation of the double bond in alkene. Hence, cis‑trans isomerism is possible. The first and foremost condition for the alkene to exhibit cis‑trans isomerism is that the carbon attached in either end of double bond must have different groups attached to it.

A cis isomer is the one in which the same groups are present on same side of both the carbon atoms present in the double bond.

A trans isomer is the one in which the same groups are present on opposite side of both the carbon atoms present in the double bond.

Cis‑trans isomerism is not possible if any one of the carbon atom bonded to the double bond bears two identical groups.

Cis‑trans isomers are not constitutional isomers but they are stereoisomers.

Answer 8

(b)

Interpretation Introduction

Interpretation:

For the given molecule, whether cis‑trans isomerism is possible has to be indicated.

Concept Introduction:

Alkenes are hydrocarbons that contain at least one double bond in it. There will not be any free rotation of the double bond in alkene. Hence, cis‑trans isomerism is possible. The first and foremost condition for the alkene to exhibit cis‑trans isomerism is that the carbon attached in either end of double bond must have different groups attached to it.

A cis isomer is the one in which the same groups are present on same side of both the carbon atoms present in the double bond.

A trans isomer is the one in which the same groups are present on opposite side of both the carbon atoms present in the double bond.

Cis‑trans isomerism is not possible if any one of the carbon atom bonded to the double bond bears two identical groups.

Cis‑trans isomers are not constitutional isomers but they are stereoisomers.

Answer 9

(b)

Interpretation Introduction

Interpretation:

For the given molecule, whether cis‑trans isomerism is possible has to be indicated.

Concept Introduction:

Alkenes are hydrocarbons that contain at least one double bond in it. There will not be any free rotation of the double bond in alkene. Hence, cis‑trans isomerism is possible. The first and foremost condition for the alkene to exhibit cis‑trans isomerism is that the carbon attached in either end of double bond must have different groups attached to it.

A cis isomer is the one in which the same groups are present on same side of both the carbon atoms present in the double bond.

A trans isomer is the one in which the same groups are present on opposite side of both the carbon atoms present in the double bond.

Cis‑trans isomerism is not possible if any one of the carbon atom bonded to the double bond bears two identical groups.

Cis‑trans isomers are not constitutional isomers but they are stereoisomers.

Answer 10

(c)

Interpretation Introduction

Interpretation:

For the given molecule, whether cis‑trans isomerism is possible has to be indicated.

Concept Introduction:

Alkenes are hydrocarbons that contain at least one double bond in it. There will not be any free rotation of the double bond in alkene. Hence, cis‑trans isomerism is possible. The first and foremost condition for the alkene to exhibit cis‑trans isomerism is that the carbon attached in either end of double bond must have different groups attached to it.

A cis isomer is the one in which the same groups are present on same side of both the carbon atoms present in the double bond.

A trans isomer is the one in which the same groups are present on opposite side of both the carbon atoms present in the double bond.

Cis‑trans isomerism is not possible if any one of the carbon atom bonded to the double bond bears two identical groups.

Cis‑trans isomers are not constitutional isomers but they are stereoisomers.

Answer 11

(c)

Interpretation Introduction

Interpretation:

For the given molecule, whether cis‑trans isomerism is possible has to be indicated.

Concept Introduction:

Alkenes are hydrocarbons that contain at least one double bond in it. There will not be any free rotation of the double bond in alkene. Hence, cis‑trans isomerism is possible. The first and foremost condition for the alkene to exhibit cis‑trans isomerism is that the carbon attached in either end of double bond must have different groups attached to it.

A cis isomer is the one in which the same groups are present on same side of both the carbon atoms present in the double bond.

A trans isomer is the one in which the same groups are present on opposite side of both the carbon atoms present in the double bond.

Cis‑trans isomerism is not possible if any one of the carbon atom bonded to the double bond bears two identical groups.

Cis‑trans isomers are not constitutional isomers but they are stereoisomers.

Answer 12

(d)

Interpretation Introduction

Interpretation:

For the given molecule, whether cis‑trans isomerism is possible has to be indicated.

Concept Introduction:

Alkenes are hydrocarbons that contain at least one double bond in it. There will not be any free rotation of the double bond in alkene. Hence, cis‑trans isomerism is possible. The first and foremost condition for the alkene to exhibit cis‑trans isomerism is that the carbon attached in either end of double bond must have different groups attached to it.

A cis isomer is the one in which the same groups are present on same side of both the carbon atoms present in the double bond.

A trans isomer is the one in which the same groups are present on opposite side of both the carbon atoms present in the double bond.

Cis‑trans isomerism is not possible if any one of the carbon atom bonded to the double bond bears two identical groups.

Cis‑trans isomers are not constitutional isomers but they are stereoisomers.

Answer 13

(d)

Interpretation Introduction

Interpretation:

For the given molecule, whether cis‑trans isomerism is possible has to be indicated.

Concept Introduction:

Alkenes are hydrocarbons that contain at least one double bond in it. There will not be any free rotation of the double bond in alkene. Hence, cis‑trans isomerism is possible. The first and foremost condition for the alkene to exhibit cis‑trans isomerism is that the carbon attached in either end of double bond must have different groups attached to it.

A cis isomer is the one in which the same groups are present on same side of both the carbon atoms present in the double bond.

A trans isomer is the one in which the same groups are present on opposite side of both the carbon atoms present in the double bond.

Cis‑trans isomerism is not possible if any one of the carbon atom bonded to the double bond bears two identical groups.

Cis‑trans isomers are not constitutional isomers but they are stereoisomers.

Answer 14

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Answer 15

Expert Solution & Answer

Answer 16

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Answer 17

Ch. 13.1 - Prob. 1QQ Ch. 13.1 - Prob. 2QQ Ch. 13.1 - Prob. 3QQ Ch. 13.2 - Prob. 1QQ Ch. 13.2 - Prob. 2QQ Ch. 13.2 - Prob. 3QQ Ch. 13.2 - Prob. 4QQ Ch. 13.3 - Prob. 1QQ Ch. 13.3 - Prob. 2QQ Ch. 13.3 - Prob. 3QQ

Solution Summary: The author explains that cistrans isomerism is not possible for the given molecule.

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